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991.
992.
尖晶石锰酸锂的组成对其结构和性能的影响 总被引:3,自引:0,他引:3
以电解二氧化锰和碳酸锂为原料用高温固相法合成了尖晶石锰酸锂,在锂与锰的原子比从0.95:2到1.1:2范围内,其结构为单一尖晶石相,晶格常数和比容量随着锂锰比的增加呈现出先增大后降低的变化规律.在锂锰比为1.0:2和1.02:2附近,晶格常数和比容量分别达到最大.这种变化规律与锂离子在晶格中的位置有关.在锂锰比从1.0:2到1.1:2的范围内,随着锂锰比的增加,尖晶石锰酸锂嵌脱锂反应过程的动力学极化逐渐降低,大电流性能逐渐提高.以尖晶石锰酸锂为正极,MCMB为负极组装了423048型电池,锂锰比从1.0:2到1.1:2,电池循环稳定性随锰酸锂的锂锰比的增大而提高. 相似文献
994.
Phase transition of LaCrO3 and doped-LaCrO3 was studied by DSC, TG and XRD, and thermal expansion during the transition was analyzed. It is found that phase transition of LaCrO3 begins at about 240℃ and ends at about 265 ℃. Temperatures of phase transition rise obviously with increasing Ca^2+ content. The transition of LaCrO3 and Ca-doped LaCrO3 from orthorhombic to rhombohedral is accompanied with endothermic reaction. No obvious change occurs in mass, but remarkable shrinkage occurs during phase transition. 相似文献
995.
Preparation of Neodymium-Doped Yttrium Aluminum Garnet Transparent Ceramics by Homogeneous Precipitation Method 总被引:3,自引:0,他引:3
Neodymium-doped yttriumaluminumgarnet(Nd∶YAG)transparent polycrystalline ceramics,laser ce-ramic matrix materials,are gradually becomingsubsti-tutes for single crystals because they are provided withpredominantly chemical stability,highly doped ionconcentration,excellent optical performance and hightemperature stability[1,2].Presently,the conventionallyused methods to produce Nd∶YAG powders are solid-state processes[3],chemical precipitation methods[4,5]andlowtemperature combustiontechniqu… 相似文献
996.
通过测量样品的M T曲线、M H曲线、ESR曲线、红外光谱、拉曼光谱、ρ -T曲线和MR T曲线 ,研究了双掺杂La0 .6 7+ 1 .33xSr0 .33- 1 .33xMn1 -xMgxO3(0.0 0≤x≤ 0 .2 5 )体系的磁电性质和输运行为。对x =0 .10和 0 .15 ,在温度高于TConset时出现相分离 ;对x =0 .2 0和 0 .2 5 ,在低温区出现了反铁磁 (AFM )行为。x =0 .0 5的 ρ-T关系存在金属 绝缘体 (MI)转变 ;x≥ 0 .15的所有样品在测量温区内显示绝缘体行为。这些奇异现象用M H关系、ESR曲线和拉曼光谱给予了很好的解释 相似文献
997.
Coating of SiC Powder with Nano YAG Phase 总被引:5,自引:0,他引:5
SiCceramiccompositeshavefoundextensiveap plicationsinmodernindustryduetotheirexcellentchemicalstabilityandwear resistance .Rodeghieroetal.[1~ 3 ] investigatedthefabricationofSiC Al2 O3 ce ramiccompositematerialsviaco precipitationcoatingandsol gelmethods… 相似文献
998.
Evaluating Acceleration Ability of Electrons of SiO_2 and ZnS in ZnS∶Er Electroluminescence 总被引:1,自引:0,他引:1
SinceCoeyandSun[1]discoveredtheinterstitial compoundSm2Fe17Nx,ithasattractedmanyresearch ers′attention.Asakindofpermanentmagneticmate rial,Sm2Fe17Nxexhibitsfairlyhighsaturationmagneti zation(1.54T)[2],highanisotropyfield(14T)under roomtemperatureandhighC… 相似文献
999.
The free vibration of the laminated composite anticlastic doubly curved stiffened shells is investigated using the finite element method. The stiffened shell element is obtained by appropriate combination of the nine-node doubly curved isoparametric thin shallow shell element with the three-node curved isoparametric beam element. The shell forms include the hyperbolic paraboloid, hypar, and conoidal shells. The accuracy of the formulation is validated by comparing the authors’ results of specific problems with those available in the literature. The additional problems are taken up for parametric studies to include the effects of fiber orientation and lamina stacking sequence of shells and stiffeners. Moreover, the effects of number, types, and orientations of stiffeners, and stiffener depth to shell thickness ratio on the fundamental frequency are also included in the present study. Further, mode shapes corresponding to the fundamental frequency for typical cases are obtained to verify the parametric trend of the results of the fundamental frequency. 相似文献
1000.
This paper discusses the capabilities of two homogenization techniques to accurately represent the elastic behavior of granular materials considered as assemblies of randomly distributed particles. The stress-strain relationship for the assembly is determined by integrating the behavior of the interparticle contacts in all orientations, using two different homogenization methods, namely the kinematic method and the static method. The numerical predictions obtained by these two homogenization techniques are compared to results obtained during experimental studies on different granular materials. Relations between elastic constants of the assembly, interparticle properties, and fabric parameters are discussed, as well as the capabilities of the models to take into account inherent and stress-induced anisotropy for different stress conditions. 相似文献