The Fabrication and Characterization of Single‐Component Polymeric White‐Light‐Emitting Diodes

By using Ni⁰‐mediated polymerization, we have systematically synthesized a series of fluorene‐based copolymers composed of blue‐, green‐, and red‐light‐emitting comonomers with a view to producing polymers with white‐light emission. 2,7‐Dibromo‐9,9‐dihexylfluorene, {4‐(2‐[2,5‐dibromo‐4‐{2‐(4‐diphenylamino‐phenyl)‐vinyl}‐phenyl]‐vinyl)‐phenyl}‐diphenylamine (DTPA), and 2‐{2‐(2‐[4‐{bis(4‐bromo‐phenyl)amino}‐phenyl]‐vinyl)‐6‐tert‐butyl‐pyran‐4‐ylidene}‐malononitrile (TPDCM) were used as the blue‐, green‐, and red‐light‐emitting comonomers, respectively. It was found that the emission spectra of the resulting copolymers could easily be tuned by varying their DTPA and TPDCM content. Thus with the appropriate red/green/blue (RGB) unit ratio, we were able to obtain white‐light emission from these copolymers. A white‐light‐emitting diode using the polyfluorene copolymer containing 3 % green‐emitting DTPA and 2 % red‐emitting TPDCM (PG3R2) with a structure of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonic acid)/PG3R2/Ca/Al was found to exhibit a maximum brightness of 820 cd m^–2 at 11 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33,0.35), which are close to the standard CIE coordinates for white‐light emission (0.33,0.33).     

An Investigation of the Reduction and Reoxidation of Isolated Vanadate Sites Supported on MCM-48

The reduction and subsequent reoxidation of isolated vanadate species supported on silica was investigated using temperature-programmed reduction and oxidation, along with in-situ XANES and Raman spectroscopy. Approximately 70–80% of the vanadium was reduced to V³⁺ after reduction in H₂ at temperatures up to 923 K. Upon reduction, the vanadyl oxygen was removed and the three remaining V–O bonds are lengthened by 0.2 Å. The vanadate species are rapidly reoxidized when exposed to O₂, with the amount of oxygen uptake matching well with the amount removed during reduction. In-situ Raman spectroscopy during reoxidation in ¹⁸O₂ showed that significant scrambling occurs between gas phase oxygen and surface oxygen species during the reoxidation of the vanadate species.     

水溶液中硅酸溶解和胶结的实验研究

本研究了几种不酸ＰＨ值对硅酸胶结的影响。结果表明，草酸浓度增大时，硅酸胶结速度变缓，至ＰＨ３－４时，硅酸不再胶结；而ＨＣＬ浓度增大，虽然胶结速度变缓，但最终仍胶结。     

Leaching kinetics of Cs and Co radionuclides fixed in cement and cement-based materials

Leach characteristics of ¹³⁷Cs and ⁶⁰Co radionuclides from both ordinary Portland cement and cement mixed with two different ratios of silica fume and ilmenite have been studied using International Atomic Energy's (IAEA) standard leach method. A mathematical model has been simulated to predict the release rate of each nuclide from cubic geometry waste matrix and the predicted values are discussed in relation to experimentally observed leach rates to confirm the validity of the proposed mechanism in the model. The effect of temperature on the radionuclides leaching rates was also studied and the effective diffusion coefficients were obtained at different temperatures. The net fractional release of the two radionuclides from different waste forms showed a decreasing pattern as ¹³⁷Cs>⁶⁰Co, indicating the largest diffusion coefficient for cesium in all waste matrices.     

A basic program for calculating subsurface water temperatures using chemical geothermometers-implication to geothermal reservoir estimation

GEOTHERM is a computer program written in BASIC language to estimate geothermal reservoir temperature using the well-known chemical gèothermometers. The empirical equations used in the program were obtained from the literature. Three different chemical geothermometers are included in the program: Na-K, Na-K-Ca, and silica geothermometers; this gives the user the opportunity not only to select the most reliable geothermometer in estimating subsurface temperature, but also to select the type of geothermometer according to available data. A sample input file of geothermal waters obtained from Iceland has been tested, so as to show the applicability and usefulness of the program.     

国画“留白”在包装设计中的运用

"留白"是中国绘画艺术中的一个非常重要的术语,被广泛的应用在中国传统的书画创作中。"留白"是艺术达成审美交流的中介机制,它深刻的展开了艺术的创作过程与接受过程的视野融合,具有极高的设计与文化价值,是现代包装设计师在设计思维和设计手法上可供学习和借鉴的宝库。本文从国画"留白"艺术的构成方法、风格、布置等角度进行了论述。总结了其设计特点和艺术手段,以通过对国画"留白"艺术设计理念的探讨对现代包装设计给予启发与引导。     

基于纹理分类的极化SAR图像滤波方法

关于雷达图像优化,提高分辨率的问题,场景较为复杂的图像,固有噪声图像效果不够理想,对具有不同统计特性的像素点缺乏精确的区分。由于传统参数估计方法降噪效果不足,为解决上述问题,提出了一种基于纹理特征分类的参数估计方法。首先计算极化总功率图像的灰度共生矩阵,并提取纹理特征矢量,用K均值聚类的方法进行分类。然后根据分类结果,在滑动邻域窗内选取与中心像素同类别的像素用于参数估计。实验结果表明,改进的纹理分类的滤波方法具有更好的降噪效果,对于复杂场景的极化SAR图像表现了较大的优越性。     

离心铸造汽缸套白斑产生机理

针对离心铸造汽缸套的白斑特征，以模拟试验手段探寻原因。用金属凝固理论解释白斑形成机理。经过装车试用，验证了白斑对摩擦性能的影响。     

Surface integrity in finish hard turning of case-hardened steels

Highly stressed steel components, e.g., gears and bearing parts, are appropriate applications for hard turning. Therefore, the process effects on significant engineering properties of work materials have to be carefully analyzed. Roughness, residual stresses, and white layers as parts of surface integrity, are functions of the machining parameters and of the cuttability of the cutting edge, i.e. of the tool wear.The aim of this work was to study the influence of feed rate, cutting speed, and tool wear on the effects induced by hard turning on case-hardened 27MnCr5 gear conebrakes and to point out the technical limitations in mass production.