Si_3N_4的结构状态对放电等离子烧结制备Sialon陶瓷的影响

以纳米非晶-Si3N4、微米α-Si3N4、微米AlN、纳米Al2O3和纳米Y2O3为初始原料,采用放电等离子烧结工艺制备了Sialon陶瓷。通过调整配方中Si3N4对应原料的种类,研究了不同结构的Si3N4对合成Sialon陶瓷的影响。通过XRD和SEM对试样的物相和显微结构进行了表征,同时测试了试样的体积密度、抗弯强度、断裂韧性和维氏硬度。实验结果表明,配方中的Si3N4全部采用α-Si3N4,经SPS烧结后可获得α/β-Sialon陶瓷,当用纳米非晶-Si3N4逐步替换α-Si3N4时,所合成的Sialon陶瓷中的α-Sialon晶相的相对含量减少;当全部采用纳米非晶-Si3N4时,则试样中仅含有β-Sialon相。     

Low-temperature sintering and microwave dielectric properties of Li2MgTi3O8 ceramics doped with BaCu（B2O5）

The influences of BaCu(B₂O₅) (BCB) addition on sintering, microstructure and microwave dielectric properties of Li₂MgTi₃O₈ ceramics were investigated using X-ray diffractometry, scanning electron microscopy and microwave dielectric measurements. The experimental results show that a small amount of BaCu(B₂O₅) addition can effectively reduce the sintering temperature to 900 °C, and induce only a limited degradation of the microwave dielectric properties. Typically, the best microwave dielectric properties of ɛ _r=24.5, Q×f =24 622 GHz, τ _f=4.2×10⁻⁶ °C⁻¹ are obtained for 1.0% BCB-doped Li₂MgTi₃O₈ ceramics sintered at 900 °C for 3 h. The BCB-doped Li₂MgTi₃O₈ ceramics can be compatible with Ag electrode, which may be a strong candidate for low temperature co-fired ceramics applications.     

自悬浮线性空气轴承的理论分析和轴承设计

挤压膜的承载能力已经在理论与实验方面得到了验证,设计了一种新型的挤压膜空气轴承,可应用在直线型导轨系统中;轴承材料为航空铝型材,压电激励和弹性铰链用来引起轴承振动和产生轴承挤压膜的压力,激振频率的选择由轴承的模态主振型确定。通过ANSYS对电．固耦合结构进行的模态分析和谐响应分析,确定了所设计轴承的模态振型和压电激振时的谐响应振型。通过对理论计算和实验结果的比较,证实了此轴承应用于线型导轨的可行性。     

基于连续损伤力学理论的陶瓷材料蠕变寿命预测模型

基于连续介质损伤理论,在Mises增量本构关系中引入了拉压蠕变变形不对称因子,从耦合演化方程推出了稳态蠕变状态下陶瓷材料为的临界累积应变失效准则和修正型的M－G蠕变寿命表达式,并用蠕变实验数据对寿命模型进行了验证。     

陶瓷与石墨化铸铁副乳化液润滑滑动磨损研究

在室温下,以乳化液为润滑剂,使用环－块磨损试验机进行了Al2O3、ZrO2及Si3N4三种工程陶瓷与球墨铸铁、灰铸铁配副的滑动磨损试验。结果表明陶瓷磨损体积依次增加的顺序为Al2O3→ZrO2→Si3N4,且陶瓷的磨损体积与铸铁的硬度成正比;而铸铁无论与何种陶瓷配副,灰铸铁的磨损体积大于球墨铸铁,马氏体基体铸铁的磨损体积反而大于珠光体基体铸铁。     

Composite Eshelby model and domain band geometries of ferroelectric ceramics

A method of composite Eshelby inclusion is proposed for a ferroelectric grain with domain switching embedded in a polycrystalline ferroelectric matrix. The method quantifies the twinning structure due to spontaneous polarization, as well as the conventional and non-conventional domain structures after poling induced domain reorientation of 90 degree. The predicted parameters include the volume fraction, the thickness, and the surface inclination angle of switched domain plates. The domain wall energy for non-conventional domain structures is derived in terms of the arrays of misfit dislocations. The domain geometries predicted by the present work agree with the measured domain morphology near an indentation crack tip when subjected to lateral electric field.     

Effect of doped Mn on piezoelectric properties of （Na0.5Bi0.5 ）0.92 Ba0.08 TiO3 lead-free ceramics

Piezoelectric ceramics (Na0.5Bi0.5)0.92Ba0.05TiO3 x%MnCO3(BNBT-Mn, x=0-1.6,mass fraction)were synthesized by conventional solid state reaction. The results show that when the addition of MnCO3 is 0-1.4%, BNBT-Mn ceramics exhibit a single-phase perovskite structure. With the increase of content of MnCO3, piezoelectric constant and electromechanical coupling factor increase rapidly when x is lower than 0.3. Then they both decrease when x is in the range of 0.3 and 1.6. When x=0.3, piezoelectric constant and electromechanical coupling factor reach the maximum value of 160 pC/N and 58.5% respectively, which can improve the temperature stability of BNBT-Mn.     

振片式超声波马达的研究

超声波马达是一种由超声振动而获得驱动力的新型马达。它利用作为定子的压电陶瓷振子,通过压电效应产生高频振动并依靠摩擦力来驱动压置在其上的转子运动。     

Strengthening steel joint of architectural structure under loading condition

Through the comparative analysis of steel plate reinforced,ceramics reinforced and non-reinforced joints under loading condition,the feasibility of strengthening steel joint of architectural structure was studied.By using element birth and death technology simulation of the fi nite element software ANSYS,it is found that when the reinforced structure is 10 mm in thickness and using steel structure to reinforce the concerned areas,the equivalent stress in concerned regionals reduces by 31.1% compared with that when the structure is not reinforced.When reinforced with ceramics,the equivalent stress in concerned regionals reduces by 24.1% compared with that reinforced with steels;when the reinforced structure is 20 mm in thickness using steels to reinforce the concerned area,the equivalent stress in concerned regionals reduces by 39.4% compared with that when the structure is not reinforced.When using ceramics to reinforce the concerned areas,the equivalent stress only decreases by 3.7% compared with that reinforced with steels.     

BCB对CSLLT陶瓷的烧结及介电性能的影响

在CaO-SrO-Li2O-Sm2O3-Nd2O3-TiO2(简称CSLLT)陶瓷中加入BaCu(B2O5)(简称BCB),研究了BCB对CSLLT陶瓷的烧结特性和介电性能的影响。结果表明:随BCB的添加,CSLLT陶瓷的烧结温度逐渐下降,并且具有高介电常数。其中,添加10?B后的CSLLT陶瓷其烧结温度从1 300℃显著下降到1 050℃,且在微波频率下具有如下介电性能:ε=77.3、Qf=4 735 GHz;τf=-48.1×10-6/℃(1 MHz)。