IR study of the interaction of hydroxyl groups of silica gel with Cr species of Phillips' type catalysts

Spectroscopic evidence for the interaction of hydroxyl groups and chromium ions was obtained using a catalyst prepared from chromyl chloride. A new OH peak, observed at 3705 cm^–1 after pumping away CO gas, is attributed to the direct interaction of OH with the low-valent chromium. This peak shifts to 3590 cm^–1 on contact with O₂ at room temperature and it is assigned to a hydroxyl interacting with the oxidized chromium. New assignments are also proposed for IR bands of CO presorbed on the catalyst. The peak due to CO at 2188 cm^–1 decreases as the OH intensity at 3705 cm^–1 increases, suggesting that the former peak arises from adsorption on Cr(II) species to which two oxygen atoms are attached.     

Misidentification by wild rabbits,Oryctolagus cuniculus,of group members carrying the odor of foreign inguinal gland secretion

To demonstrate that the inguinal gland odor conveys information on the identity of individuals, 60 male, wild-type rabbits,Oryctolagus cuniculus, living in groups of three in outdoor pens, were used in 120 tests. Members of the groups smeared with the inguinal gland secretion from unfamiliar rabbits were attacked by their penmates. In contrast the odors of chin gland secretions and urine of strange rabbits and of a commercial perfume did not cause serious disruption to the social relationships within the groups.     

Light-sensitive elastomers modified by 4-(N-dimethylmaleimido)-benzenesulphenyl chloride

New light-sensitive polymers were prepared by modification of four different elastomers with 4-(N-dimethylmaleimido)-benzenesulphenyl chloride (DMI-BSCI). Polydienes modified by DMI-BSCI form block copolymers. These polymers show a strong increase of the glass transition temperature T_g whereby the T_g increase of modified poly(octenamer) is much smaller. Higher modified polydienes have two T_g. Modified poly(octenamers) show a melting temperature dependence T_m on the content of trans double bonds which is characteristic of statistical copolymers. The ratio of rate constants with which trans- and cis-structures in poly(octenamer) are occupied by DMI-BSCI, is

$\text{k}{}_{\mathrm{trans}}\text{k}{}_{\mathrm{cis}}\text{= 0.34}$

     

周期式冷轧管机的发展

叙述了周期式冷轧管机国内外开发、研制的历史和现状。介绍了典型型号的周期式冷轧管机的技术参数,结构特点及目前应用情况。     

Limit load and shakedown analysis of plastic structures under stochastic uncertainty

Problems from plastic analysis are based on the convex, linear or linearised yield/strength condition and the linear equilibrium equation for the stress (state) vector. In practice one has to take into account stochastic variations of several model parameters. Hence, in order to get robust maximum load factors, the structural analysis problem with random parameters must be replaced by an appropriate deterministic substitute problem. A direct approach is proposed based on the primary costs for missing carrying capacity and the recourse costs (e.g. costs for repair, compensation for weakness within the structure, damage, failure, etc.). Based on the mechanical survival conditions of plasticity theory, a quadratic error/loss criterion is developed. The minimum recourse costs can be determined then by solving an optimisation problem having a quadratic objective function and linear constraints. For each vector a(·) of model parameters and each design vector x, one obtains then an explicit representation of the “best” internal load distribution F^∗. Moreover, also the expected recourse costs can be determined explicitly. Consequently, an explicit stochastic nonlinear program results for finding a robust maximal load factor μ^∗. The analytical properties and possible solution procedures are discussed.     

基于复杂网络的非正式团体知识交互网络分析

针对知识在非正式团体中的传播特征,结合复杂网络理论,为了企业知识不断创新,提出了一种非正式团体知识交互网络模型.通过仿真得出,在小世界网络模型下知识的传播速度和平均知识水平比其他网络模型有明显优势,进而在非正式团体知识交互网络的描述与分析中提出利用"小世界"的平均路径长度和聚类系数来表征IFG知识交互网络中的交互频繁度和交互聚集度的思想,为进一步研究IFG组织及管理与其内部知识创新的内在联系提供了数量分析基础.     

基于Haar小波变换高频特征的图像质量评价算法

在分析人类视觉系统(HVS)特性的基础上,提出一种基于Haar小波变换高频特征的图像质量评价算法(CSSIM)。此方法首先将图像进行小波变换得到不同方向和不同频率的4个频带划分,在3个高频频带比较边缘结构信息上根据人类视觉系统特性,赋予3个频带比较结果相应视觉权重值,最终得到归一化的图像质量评价指标CSSIM。通过非线性回归拟合分析,证明了提出的算法(CSSIM)相对图像结构相似度评价算法(MSSIM)及其改进算法(MGSSIM)更符合人类的主观视觉感受。     

Computing presentations for subgroups of polycyclic groups and of context-free groups

Algorithms for solving uniform decision problems for algebraic structures crucially depend on the chosen finite presentations for the structures under consideration. Rewriting techniques have been used very successfully to solve uniform decision problems, when the presentations considered involve finite, noetherian, and ()-confluent rewriting systems. Whenever the class of algebraic structures considered is closed under the operation of taking finitely generated substructures, then the algorithms for solving the uniform decision problems can be applied to the substructures as well. However, since these algorithms depend on the form of the presentations, this involves the task of constructing a presentation of a certain form for a substructure given a presentation of this form for the structure itself and a finite set of generating elements for the substructure.This problem, which has received a lot of attention in algebra, is here investigated from an algorithmic point of view. The structures considered are the following two classes of groups, which have been studied extensively before: the polycyclic groups and the context-free groups.Finitely generated context-free groups can be presented by finite, monadic, and -confluent string-rewriting systems. Due to their nice algorithmic properties these systems provide a way to effectively solve many decision problems for context-free groups. Since finitely generated subgroups of context-free groups are again contextfree, they can be presented in the same way. Here we describe a process that, from a finite, monadic, and -confluent string-rewriting system presenting a context-free groupG and a finite subsetU ofG, determines a presentation of this form for the subgroup U ofG that is generated byU. For finitely presented polycyclic groups we obtain an analogous result, when we use finite confluent PCP2-presentations to describe these groups.This work was performed while this author was visiting at the Fachbereich Informatik, Universität Kaiserslautern, during his sabbatical 1991/92     

Monte Carlo and variance reduction methods for structural reliability analysis: A comprehensive review

Monte Carlo methods have attracted constant and even increasing attention in structural reliability analysis with a wide variety of developments seamlessly presented over decades. Along the way, a number of specialized reviews and benchmark studies have been provided from time to time, aiming at summarizing and comparing selected few approaches in detail, mainly from an implementation point of view. In contrast, the aim of the present survey is to play a comprehensive role as a methodological guidebook on Monte Carlo simulation and its related, especially variance reduction, techniques through a covering of 444 references in the relevant literature. To achieve this goal, we present an extensive review of formulations and techniques along with insightful summaries of developments of existing numerical methods, ranging from the general formulation, sub-categories and variants, to their combined uses with other simulation techniques and surrogate models, as well as the key advantages and assumptions.     

Wave Groups in Uni-Directional Surface-Wave Models

Uni-directional wave models are used to study wave groups that appear in wave tanks of hydrodynamic laboratories; characteristic for waves in such tanks is that the wave length is rather small, comparable to the depth of the layer. In second-order theory, the resulting Nonlinear Schrödinger (NLS) equation for the envelope of the wave group contains the dispersion of the group velocity multiplying the linear term and a gen-coefficient that results from mode generation multiplying the nonlinear term. The signs of these coefficients determine whether experimentally relevant wave groups are possible or not. If the dispersion is modelled in such a way that it is correct for all wave lengths for infinitesimal waves, relevant wave groups are obtained consisting of constituent waves with a certain maximal wave length; other models for the dispersion (such as in the KdV-equation) lead to different results.