Kinetics of oxygen absorption in aqueous sodium dithionite solutions

The absorption and reaction of oxygen in aqueous alkaline solutions of sodium dithionite has been experimentally investigated in a novel gas-liquid contactor. The novel gas-lift bubble column contactor was used to study the kinetics over wide ranges of reactant concentrations, temperature, and pH. The oxygen-sodium dithionite reaction was found to be first-order with respect to dithionite in the range of dithionite concentration < 0.1 M, and second-order in the range of dithionite concentration > 0.1 M. The reaction with respect to oxygen was found to be zero-order for all dithionite concentrations. These results and experimental investigations of the effect of solution alkalinity and temperature on the reaction rate are consistent with previous findings obtained in different gas-liquid contactors. The results thus confirm the feasibility of using the gas-lift bubble column for the kinetics of gas-liquid reactions.     

异丁醛氧化制丙酮热导气相色谱分析

本工作用２米４０１有机担体填充柱，在带四臂热导检测器的国产１０３型气相色谱仪上，仅８分钟将原料异丁醛、产物丙酮及水进行良好分离，并采用内标法定量，其最大平均偏差在±２％以内。方法简单、快速、准确     

Erosion-corrosion of a stainless steel distillation column in food industry

Unusual extended corrosion phenomena were detected in a distillation column made in AISI type 316 stainless steel (UNS S31600) of a plant for natural pectins extraction from citrus. The column was the first of a series of two distillation columns representing the unit core. Corrosion problems were observed only in that column and mainly along the surface of the trays located in the lower section of the column. The phenomenon was observed subsequently to a modification of the original plant layout that caused an increase of the operating temperatures and turbulence of the process stream inside the column.     

应用列对象的Tag属性实现多表数据动态查询

探讨在PB开发的应用程序中利用数据窗口列对象的Tag属性,结合自行设计的一个更改SELECT语句中的Where子句的全局函数,实现应用程序多表数据的动态查询。该种方法是PB开发的应用程序中实现数据查询的一种高效、简洁且行之有效的方法。     

堆石混凝土单轴受压应力-应变全曲线试验方法研究

为了研究堆石混凝土应力-应变全曲线,采用碟形弹簧与钢柱组合成附加刚性元件增强压力机的刚性,研究了碟形弹簧并联与串联联结装置的变形量和刚度以及实现单轴受压端部减摩措施,提出了一种堆石混凝土单轴受压应力-应变全曲线的试验方法。在混凝土压力试验机上进行了堆石混凝土立方体试件单轴受压试验,测得了堆石混凝土受压应力-应变全曲线。试件破坏形态表明,采用的端部减摩措施有效,测得的应力-应变曲线下降段验证了碟形弹簧与钢柱组合装置能够吸收试件破坏时混凝土压力试验机存储的变形能。研究结果为在混凝土压力试验机上进行堆石混凝土单轴受压应力-应变全曲线提供了可行、简便、经济的测试方法。     

多目标优化策略在精馏过程中的应用研究

针对精馏塔自由度多,能耗大,扰动复杂多变,控制和优化要求高等特点,提出了一种基于动态矩阵控制(DMC)的二层多目标优化控制策略。在实现精馏过程控制目标的前提下,设计了二层优化指标,可在有多余自由度的情况下,进行二层控制和优化,实现精馏过程质量控制目标和经济运行优化。通过对Shell多侧线精馏过程的仿真研究,验证了二层多目标优化控制策略的有效性。与DMC控制相比,二层多目标优化控制策略可以明显改善精馏塔运行的经济性,实现增加收益的目标。     

再生砖混骨料混凝土柱的小偏心受压性能

通过小偏心受压性能试验对比研究3根的天然骨料混凝土柱和3根同强度全再生砖混骨料混凝土柱,强度分别为C25、C30和C35. 对6根柱进行加载试验,分析再生砖混骨料混凝土柱相比于同强度天然骨料混凝土柱在受力过程、破坏特征、变形能力与承载力等方面的差异. 试验发现,再生砖混骨料混凝土柱在小偏心加载至破坏的过程中,具有与天然骨料混凝土柱相似的3个受力阶段,且符合平截面假定. 与同强度的天然骨料混凝土柱相比,变形较大,但再生砖混骨料混凝土柱的极限承载力略高,原因可能在于两者轴心抗压强度的差异.     

不用压边成形圆锥形零件过程中内皱发生时刻确定及其影响因素分析

利用内皱模型，结合圆锥形零件在成形过程中的几何条件及应力分析推导了圆锥形零件不用压边时也不发生内皱的l临界条件；进而利用VB语言编程绘制了圆锥形零件在成形过程中不同参数情况下拉深时刻与相对厚度的变化曲线，据此得到内皱发生的具体时刻，并分析了不同参数对内皱发生时刻的影响。此临界条件可作为圆锥形零件拉深过程中不用压边时也不发生内皱的判据。所得曲线组具有通用性，可供生产实践或理论研究参考。     

Review on the effect of heat exchanger tubes on flow behavior and heat/mass transfer of the bubble/slurry reactors

Bubble/Slurry bubble column reactors(BCR/SBCR) are intensively used as multiphase reactors for a wide range of application in the chemical, biochemical and petrochemical industries. Most of these applications involve complicate gas–liquid/gas–liquid–solid flow behavior and exothermic process, thus it is necessary to equip the BCR/SBCR with heat exchanger tubes to remove the heat and govern the performance of the reactor. Amounts of experimental and numerical studies have been carried out to describe the phenomena taking place in BCR/SBCRs with heat exchanger tubes. Unfortunately, little effort has been put on reviewing the experiments and simulations for examining the effect of internals on the performance and hydrodynamics of BCR/SBCR. The objective of this work is to give a state-of-the-art review of the literature on the effects of heat exchanger tubes with different types and configurations on flow behavior and heat/mass transfer, then provide adequate information and scientific basis for the design and the development of heat exchanger tubes in BCR/SBCR, ultimately provide reasonable suggestions for better comprehend the performance of different heat exchanger tubes on hydrodynamics.     

浅谈气力提升系统的设计

阐述了气力提升系统的组成、原理、选择原则和设计过程。并对气力提升系统与传统提升装置进行了分析、比较,指出气力提升系统具有设备性能稳定、耗能小等优点,有着很好的应用前景,值得推广。