Study on bioleaching of primary chalcopyrite ore with thermoacidophilic archae

A high temperature-tolerating thermoacidophilic archae （TA） was isolated from water samples collected from a hot sulfur-containing spring in the Yunnan Province, China, and was used in bioleaching experiments of a low-grade chalcopyrite ore. The TA grow at temperatures ranging from 40 to 80℃, with 65℃ being the optimum temperature, and at pH values of l.5 to 4.0, with an optimum pH value of 2.0. The bioleaching experiments of the chalcvpyrite ore were conducted in both laboratory batch bioreactors and leaching columns. The results obtained from the bioreactor experiments showed that the TA bioleaching rate of copper reached 97% for a 12-day leaching period, while the bioleaching rate was 32.43% for thiobacillus ferrooxidans （Tf） leaching for the same leaching time. In the case of column leaching, tests of a two-phase leaching （196 days）, that is, a two-month （56 days） Tf leaching in the first phase, followed by a 140-day TA leaching in the second phase were performed. The average leaching rate of copper achieved for the 140-day TA leaching was 195mg/（L.d）, while for the control experiments, it was as low as 78mg/（L .d） for the Tf leaching, indicating that the TA possesses a more powerful oxidizing ability to the chalcopyrite than Tf Therefore, it is suggested that the two-phase leaching process be applied to .for the heap leaching operations, whereas, the TA can be used in the second phase when the temperature inside the heap has increased, and the primary copper sulfide minerals have already been partially oxidized with Tf beforehand in the first phase.     

COMPARISON BETWEEN THEORETICAL FORMULA AND EXPERIMENTAL RESULTS ON BUBBLE ELECTROPHORESIS

ＣＯＭＰＡＲＩＳＯＮＢＥＴＷＥＥＮＴＨＥＯＲＥＴＩＣＡＬＦＯＲＭＵＬＡＡＮＤＥＸＰＥＲＩＭＥＮＴＡＬＲＥＳＵＬＴＳＯＮＢＵＢＢＬＥＥＬＥＣＴＲＯＰＨＯＲＥＳＩＳ￥ＸｕＪｉｒｕｎ；ＫｅｌｓａｌｌＧＨ（Ｐ．Ｏ．Ｂｏｘ１３９，ＮｏｒｔｈｅａｓｔｅｒｎＵｎｉ...     

大豆中异黄酮类化学成分的研究

用w(C2H5OH)=70%的工业乙醇从脱脂大豆饼中提取大豆异黄酮,并依次用乙酸乙酯、正丁醇萃取,乙酸乙酯萃取部分经硅胶柱和SephadexLH-20柱层析,用V(CHCl3)∶V(CH3OH)=(12～4)∶1梯度洗脱。分离得到4种化合物,通过理化常数和光谱分析鉴定其化学结构,分别为大豆甙元(daidzein)、染料木素(genistein)、大豆甙(daidzin)、染料木甙(genistin)。     

用人工神经网络方法预测鼓泡塔气含率

A new correlation for the prediction of gas hod up in bubble columns was proposed based on an extensive experimental database set up from the literature published over last 30 years .The updated estimation method relying on artificial neural network,dimensional analysis and phenomenological approaches was used and the model prediction agreed with the experimental data with average relative error less than 10%.     

多元复杂精馏过程模拟和优化

采用非平衡级METSH方程组，对丙烯精馏过程进行了模拟计算和优化，提出了一种全新的、实用的塔板组成的圆整归一方法，摸索出了一套行之有效的计算程式，大大提高了模型方程组迭代计算的收敛性，求解更加稳定。本文还以精馏塔利润为目标，建立了优化目标函数，进行了优化计算，计算结果对丙烯塔生产具有一定意义。     

An improved light attenuation technique for measuring large interfacial areas

A laser-based light attenuation technique was successfully used to measure interfacial areas as high as 5832 m²/m³ and Sauter mean bubble diameter varying between 50 and 5600 μm. Good agreement between this approach and the photographic technique was obtained particularly at low gas holdups.     

Current problems in the modelling of chemical reactors

Modelling of chemical reactors is reviewed with an emphasis on process development and scale-up. A distinction is made between modelling of chemical kinetics, of rate processes in volume elements and of whole reactors. Examples are mainly taken from papers presented at the Sixth International Symposium on Chemical Reaction Engineering. Special attention is given to the modelling of single phase reactors, fixed beds, trickle beds, fluid beds, and gas bubble reactors.     

Monodisperse‐porous poly(styrene‐co‐divinylbenzene) beads providing high column efficiency in reversed phase HPLC

A multistage polymerization protocol, the so‐called “modified seeded polymerization,” was developed for the production of monodisperse‐porous poly(styrene‐co‐divinylbenzene) providing high column efficiency as a packing material in reversed phase high performance liquid chromatography (RPLC). In the first stage of the multistage production, uniform polystyrene seed particles, produced by dispersion polymerization, were swollen by an organic agent (i.e., the diluent) and then by a monomer mixture containing styrene and divinylbenzene. The final porous particles were obtained in the monodisperse form by the polymerization of monomer mixture in the seed particles. By the use of a small size seed latex with low molecular weight and by the selection of the appropriate diluent, relatively small monodisperse‐porous particles with suitable pore structure could be achieved. In the reversed phase separation of alkylbenzenes, under isocratic conditions, theoretical plate numbers up to 40,000 plates/m were achieved by using 5.2 μm porous particles, obtained by a toluene‐dibutyl phthalate mixture as the diluent. No significant decrease in the resolution power was observed by the fourfold increase in the mobile phase flow rate. The column efficiency and the resolution observed with 5.2 μm monodisperse‐porous particles were significantly higher with respect to the currently available polymer based packing materials used in the reversed phase HPLC. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1430–1438, 2005     

凉水塔技术研究与探讨

通过对我厂引进的大型进口设备———Marley—600型冷却塔进行技术改造情况的介绍,具体分析了进口材料与国产材料的本质区别,并具体介绍了我厂的使用情况。此次技术改造在大化肥行业是首次进行,并取得了成功。论证了进口设备走国产化道路的必然性及可行性,从而为我国的其他大型Marley—600型冷却塔设备走国产化道路作了较好的铺垫。     

塔板布置的计算机辅助设计

提供了一种简单而有效的利用计算机辅助进行塔板布置的方法。给出了相应的计算内容和程序。有较好的通用性。适用于浮阀塔板和筛孔塔板。