全文获取类型
收费全文 | 14221篇 |
免费 | 2173篇 |
国内免费 | 1184篇 |
专业分类
电工技术 | 1481篇 |
综合类 | 1421篇 |
化学工业 | 2851篇 |
金属工艺 | 702篇 |
机械仪表 | 1556篇 |
建筑科学 | 1054篇 |
矿业工程 | 669篇 |
能源动力 | 547篇 |
轻工业 | 219篇 |
水利工程 | 522篇 |
石油天然气 | 623篇 |
武器工业 | 230篇 |
无线电 | 2117篇 |
一般工业技术 | 1959篇 |
冶金工业 | 318篇 |
原子能技术 | 194篇 |
自动化技术 | 1115篇 |
出版年
2024年 | 160篇 |
2023年 | 358篇 |
2022年 | 547篇 |
2021年 | 647篇 |
2020年 | 702篇 |
2019年 | 573篇 |
2018年 | 563篇 |
2017年 | 644篇 |
2016年 | 643篇 |
2015年 | 728篇 |
2014年 | 887篇 |
2013年 | 945篇 |
2012年 | 1169篇 |
2011年 | 1168篇 |
2010年 | 808篇 |
2009年 | 792篇 |
2008年 | 737篇 |
2007年 | 851篇 |
2006年 | 759篇 |
2005年 | 638篇 |
2004年 | 553篇 |
2003年 | 438篇 |
2002年 | 394篇 |
2001年 | 303篇 |
2000年 | 256篇 |
1999年 | 242篇 |
1998年 | 187篇 |
1997年 | 157篇 |
1996年 | 142篇 |
1995年 | 128篇 |
1994年 | 109篇 |
1993年 | 75篇 |
1992年 | 73篇 |
1991年 | 48篇 |
1990年 | 43篇 |
1989年 | 33篇 |
1988年 | 26篇 |
1987年 | 8篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1980年 | 4篇 |
1979年 | 7篇 |
1978年 | 2篇 |
1973年 | 1篇 |
1965年 | 1篇 |
1959年 | 2篇 |
1951年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
The nature of pairing mechanism as well as transition temperature of yttrium cuprates is discussed using the strong coupling
theory. An interaction potential has been developed for the layered structure with two conducting CuO2(a–b) layers in a unit cell. The interaction potential properly takes care of electron-electron, electron-phonon and electron-plasmon
interactions. Furthermore, the electron-phonon coupling parameter (λ), the modified Coulomb repulsive parameter (μ*) and the 2D acoustic phonon (plasmon) energy as a function of oxygen deficiency is worked out. Finally, the superconducting
transition temperature (T
c) is then evaluated by using these coupling parameters and obtainedT
c = 95(92)K for Y(Yb)Ba2Cu3O7−δ
superconductors withδ = 0·0. The model parameters estimated from the layered structure approach are consistent with the strong coupling theory.
The result deduced on the variation ofT
c withδ are in fair agreement with the earlier reported data on yttrium cuprates. The analysis of the above results are discussed. 相似文献
2.
M.E. Enyiegbulam 《International Journal of Adhesion and Adhesives》1985,5(4):207-210
Increased wetting of the coupling agent/epoxy resin interface was observed when γ-glycidoxypropyltrimethoxysilane, polyfunctional aminosilane and γ-aminopropyltriethoxysilane were applied respectively from methyllethylketone, dimethylformamide and water on woven glass cloths which had been cleaned at 300°C. However, when factory-applied coupling agents were burnt off the woven cloths and fresh coupling agents re-applied, it was found that the nature of the factory-applied coupling agent influenced subsequent wetting. Thinner glass fibres showed a greater improvement in wetting rate than thicker fibres in those solvents identified to be good for improved wettability, irrespective of the heat-cleaning temperature. 相似文献
3.
Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry 相似文献
4.
本文评价了塑料闪烁片用作软β核素探测器时的计数效率、β谱、本底谱和康普顿电子谱的特征。文中强调:采用胶合光导剂构成的系统是一种新型探测器(软β核素内部样品塑料闪烁探测器)。本文提出内部样品固体探测器、胶合光导剂和胶合闪烁光导剂的新概念。 相似文献
5.
Qingzhao Yao Yuming Zhou Yanqing Sun Xiaoyun Ye 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(4):477-484
TiO2 hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane
coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation
method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as
testified by UV spectrometric method. KH570 modified TiO2 nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the
reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron
microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed
for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting
cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive
adsorption capacity were achieved, which made it promising in chemical sensor applications. 相似文献
6.
Compared to other fields of engineering, in mechanical engineering, the Discrete Element Method (DEM) is not yet a well known
method. Nevertheless, there is a variety of simulation problems where the method has obvious advantages due to its meshless
nature. For problems where several free bodies can collide and break after having been largely deformed, the DEM is the method
of choice. Neighborhood search and collision detection between bodies as well as the separation of large solids into smaller
particles are naturally incorporated in the method. The main DEM algorithm consists of a relatively simple loop that basically
contains the three substeps contact detection, force computation and integration. However, there exists a large variety of
different algorithms to choose the substeps to compose the optimal method for a given problem. In this contribution, we describe
the dynamics of particle systems together with appropriate numerical integration schemes and give an overview over different
types of particle interactions that can be composed to adapt the method to fit to a given simulation problem. Surface triangulations
are used to model complicated, non-convex bodies in contact with particle systems. The capabilities of the method are finally
demonstrated by means of application examples.
Commemorative Contribution. 相似文献
7.
对弹性杆与水下壳体接触冲击问题进行了研究,用有限元法模拟壳体,边界无法模拟无限域流体,通过温面上的耦合条件进行联立求解,文中给出了典型算例,并进行了有关讨论。 相似文献
8.
一种协调的科技文献分类方法 总被引:1,自引:0,他引:1
科技文献之间的相互引证关系反映了一种科学交流活动,显示了科学文献之间(甚至是学科之间)的内在联系,而通过追溯文献之间的这种关系,可以改善和提高传统的基于内容的科技文献的分类的方法。论文利用有相互引证关系,有同引关系,以及有耦合关系的两篇文献一般是属于同一类的这一特点,提出了文献之间的引用相似度,同引相似度,耦合相似度这三个概念,再利用这三个概念生成了文献之间的“结构相似度”,并将它用于K-NN分类法中得出一种基于结构的分类法。最后,论文将这种基于结构的分类法和基于内容的NaveBayes分类法结合起来提出了一种新的协调分类法。 相似文献
9.
10.
偶联剂处理硅灰石填充不饱和聚酯树脂的研究 总被引:2,自引:0,他引:2
对针状硅灰石 (L∶D≥ 10∶32 5目 )提纯后 ,采用偶联剂进行表面处理 ,将硅灰石按不同比例填充于不饱和聚酯树脂体系中 ,研究了材料的性能。结果表明 ,改性后的硅灰石可显著改善不饱和聚酯的性能。 相似文献