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271.
Substituted uracils were tested as corrosion inhibitors of copper in 3% NaCl medium using electrochemical polarisation, impedance measurements and non-electrochemical techniques (weight loss, IR and UV-visible). This study permitted to follow the evolution of the inhibitory effect of the uracil derivatives, according to their substituents, on copper in 3% NaCl medium. Comparison of results showed that dithiouracil (DTUr) was the best inhibitor. The maximum inhibition efficiency reached 98% at 10−3 M. DTUr adsorbs on the copper surface according to the Frumkin isotherm model. 相似文献
272.
Further evidence was delivered that certain impurities, which could be contained in MgO samples, might be responsible for observed variability in MgO basicity and catalytic performance in oxidative coupling of methane. The surface basicity/base strength distribution of a series of MgO samples containing or not containing Ca and Na impurities was determined by a temperature-programmed desorption of CO2. It was revealed that samples containing Ca and Na impurities have much more medium, strong and very strong basic sites. The surface basicity of MgO samples containing added alkali or alkaline earth compounds or water was characterized by a test reaction of transformation of 2-butanol. It was confirmed that the introduction of these compounds to a pure MgO enhanced both its basicity and activity in oxidative coupling of methane. 相似文献
273.
274.
En-Hai Sun Yong-Ho Choa Tohru Sekino Tomohiko Adachi Koichi Niihara 《Materials Research Innovations》2002,6(3):105-111
Cordierite/ZrO2 composites with 5 to 25 wt% ZrO2 were fabricated by conventional powder mixing and pressureless sintering method. Their densification behavior, microstructure,
mechanical and thermal properties were studied. By dispersing 25 wt% (9.57 vol%) ZrO2, densified cordierite/ZrO2 composite with a relative density of 98.5% was obtained at an optimum sintering condition of 1440 °C and 2 h. ZrO2 particles were homogenously dispersed within matrix grains and at the grain boundaries. The intragranular particles were
finer than 100 nm and the intergranular particles were coarser. Both fracture strength and toughness could be enhanced more
than two times higher, compare to those of monolithic cordierite, by dispersing 25 wt% ZrO2 into the cordierite matrix. The toughening mechanism in the present composites was mainly attributed to martensitic transformation
due to ZrO2 dispersion.
Electronic Publication 相似文献
275.
276.
A type of CO2 sensor based on oxygen concentration cell was designed as following: Cell I: Pt | Au, O2,CO2|Na2CO3(Au)|NKBA(Au)|YSZ|O2, CO2|Pt or Cell Ⅱ: Pt|Au, O2, CO2|K2CO3(Au)|NKBA(Au)|YSZ|O2, CO2|Pt.(Na,K-β/β″-Al2O3 is named by NKBA). The sensor signal is consistent with the Nernstian slope within the region ofphase equilibrium for Na, K-β/β"-Al2O3 material. The relationship between CO2 sensor voltage response and phaseequilibrium of solid electrolyte Na, K-β/β-Al2O3 is discussed in this paper. 相似文献
277.
做为一种耐磨性能很好的材料 ,SiC颗粒增强铝基复合材料切削加工表面具有分形特征。实际研究表明SiC颗粒增强铝基复合材料切削加工表面分形维数与抗磨损性能有密切关系 ,本文还分析了表面分形维数越大其抗磨损性能越强的机理。 相似文献
278.
279.
280.
含H_2S井完井液对井下金属管串具有腐蚀性。采用锌基或铁基螯合物除硫剂及咪唑啉缓蚀剂可有效地防止这种腐蚀的发生。本文对H_2S的腐蚀、除硫剂和缓蚀剂产品及其对产层的损害作了介绍与探讨。 相似文献