Prediction of the effects on dynamic response due to distributed structural modification with additional degrees of freedom

The aim of this study is to investigate means of efficiently assessing the effects of distributed structural modification on the dynamic properties of a complex structure. The dynamic properties of the modified structure can be determined by experimental testing or numerical simulation, both of which are complex, expensive and time-consuming. Assuming that the original dynamic characteristics are already established and that the modification is a relatively simple attachment, the modified dynamic properties may be determined numerically without solving the equations of motion of the full-modified structure. The frequency response functions (FRFs) of the modified structure can be computed by coupling the original FRFs and a delta dynamic stiffness matrix for the modification introduced. The validity of this approach is investigated by applying it to a cantilever beam to which a smaller beam is attached as modification. The original FRFs were obtained experimentally as well as numerically. The delta dynamic stiffness matrix was determined numerically by modeling the attachment and part of the original structure including the attachment points. The FRFs of the modified beam were then computed. Good agreement is obtained by comparing the results to the FRFs of the modified beam determined experimentally as well as by numerical modeling of the complete modified structure.     

Influence of washing and of heat-treatment conditions on the thermal stability of VPI-5

Thorough washing of a VPI-5 synthesized with n-dipropylamine as template improves greatly its thermal stability while no major change is observed in the template content. A detailed study of the influence of the pretreatment conditions shows that in order to obtain a high thermal stability (up to at least 960 °C) two parameters are of importance. The removal of both the template and the adsorbed water requires either a low heating rate at atmospheric pressure or a low pressure (less than 3 Torr) when the heating rate is 300 ° per hour.     

专家系统在化工中的应用进展

本文综述了近年来专家系统在化工领域的应用状况，并指出今后的发展趋势。     

有关H－Ⅱ运载火箭的动力学课题研究

重点介绍有关Ｈ—Ⅱ运载火箭（以下简称Ｈ—Ⅱ）的一些动力学课题的研究状况。其中，重要的动力学课题有全箭振动、ＰＯＧＯ、防液体晃动、分离动力学试验、动力学环境试验等。针对这些动力学课题，日本有关部门已研究多年，既作了充分的地面试验，又进行了有效的工程应用研究，最终保证了Ｈ—Ⅱ的首次飞行成功。     

一种新的位错运动理论及对材料动态力学行为的描述

通过对位错在晶格内运动的动力学过程的全面分析。本文提出了一种考虑到粘性阻尼效应和热激活的位错集体运动统一理论。其特点是可用一简单的方程对从低速到高速运动的大量位错的平均行为进行统一描述。对ＫＣｌ晶体的典型实验怕拟合发现理论描述与实验结果相当一致。     

不同活化剂对石油焦基活性炭孔结构的影响

以石油焦为原料 ,Na OH,KOH和 Na2 CO3 为活化剂制备活性炭 ,采用氮气吸附考察了不同活化剂对活性炭的比表面积、中孔和微孔孔径分布、孔容积及平均孔径等孔结构的影响 .结果表明 :KOH活化制备的活性炭包含 1 nm的微孔和 4nm的中孔 ,总孔容 0 .648cm3 /g,比表面积大 ;Na OH制备的活性炭以 1 nm的微孔为主 ,占总孔容 ( 0 .1 65 cm3 /g)的 98% ,平均孔径 1 .83nm;Na2 CO3 制备的活性炭以 4nm的中孔为主 ,占总孔容 ( 0 .1 43cm3 /g)的 68.5 % ,平均孔径 3.42 nm,比表面积小 .3种样品的孔径都呈现出多峰分布特征 .KOH和 Na2 CO3 活化制备的活性炭的 N2 吸附脱附曲线属于 型 ,Na OH活化制备的活性炭吸附脱附曲线属于 型 .     

Simulation of nitrogen dynamics and biomass production in winter wheat using the Danish simulation model DAISY

A dynamic simulation model for the soil plant system is described. The model includes a number of main modules, viz., a hydrological model including a submodel for soil water dynamics, a soil temperature model, a soil nitrogen model including a submodel for soil organic matter dynamics, and a crop model including a submodel for nitrogen uptake. The soil part of the model has a one-dimensional vertical structure. The soil profile is divided into layers on the basis of physical and chemical soil characteristics. The simulation model was used to simulate soil nitrogen dynamics and biomass production in winter wheat grown at two locations at various levels of nitrogen fertilization. The simulated results were compared to experimental data including concentration of inorganic nitrogen in soil, crop yield, and nitrogen accumulated in the aboveground part of the crop. Based on this validation it is concluded that the overall performance of the model is satisfactory although some minor adjustments of the model may prove to be necessary.     

Transitions of saturated monoacid triglycerides: Modeling conformational change at glycerol during α→β′→β transformation

The glycerol region geometry of modeled saturated monoacid triglycerides was altered by bond rotations and minor angle distortions to convert theoretical α-forms into bent β′- and β-forms. Direct α to β conversion involves lateral disruption of fatty chain packing to generate side-chain character typical of the β-form. Such disruption, which could contribute to fat bloom, allows additional molecular movement and shifts in molecular mechanics energy (MME) that may approximate thermal changes observed by differential scanning calorimetry during α to β transformations. Energy calculations at 100 points throughout each transformation identified plausible conversion routes. A two-stage conversion, α to either of two stereospecific β′-forms bent at glycerol followed by subsequent conversion to β, showed less chain movement and more favorable MME than direct α to β conversion. The preferred path, based on energy profiles of each conversion, involves a β′-D form and rotation of carbonyl to α-carbon bonds in chain #2 and a side chain (chain #3).     

A comparison of the performance of N simulation models in the prediction of Nmin on farmers' fields in the spring

The performance of three different models, which simulate changes in the inorganic N content of the soil, was evaluated in respect of their ability to predict N_min content in the spring under cereal crops. The models of British, Dutch and German origin, were tested using data from farmers' fields supplied by 70 farmers over two growing seasons in FRG. The models were run between harvest of the previous crop and spring of the following year, and predictions of N_min in the spring compared to soil measurements. The performance of the models was assessed by counting the number of cases in which predictions agreed within 10 or 20 kg (N) ha^–1 of the measurements. Predictions were less than ± 10 kg (N) ha^–1 of measured values in only 30–44% and 28–55% of cases in 1988 and 1989, respectively. Predictions were less than ± 20 kg (N) ha^–1 of measured values in 62–70% and 68–82% of cases in 1988 and 1989, respectively. Predictions in 1989 were better because the initial N_min content in the autumn was included in the model input. None of the models tested had been designed to use input data of the type available to farmers. It is concluded that, at present, the results are too variable for any of the models to be used with confidence as tools to aid in N fertilizer recommendations.     

等离子体技术在化学合成中的应用

从等离子体的基本特性出发,综述了等离子体技术在氨气合成、有机物合成、高分子合成以及纳米碳管的合成等方面的应用和最新进展,并展望了等离子体技术在化学合成方面的应用前景.