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91.
The UV‐curable urethane‐acrylates based on 2‐hydroxyethyl methacrylate (HEMA)‐terminated polyurethane (PU) for lithographic and coating applications are investigated in this study. Series of PU prepolymers were made from 4,4‐diphenyl methane diisocyanate (MDI), poly(propylene oxide) glycol (PPG 400), poly(butylene adipate)glycol (PBA 500), or poly(tetramethylene oxide) glycol (PTMO 1000) and are terminated with HEMA. The 2,2‐azobisisobutyronitrile (AIBN) was used as a UV‐initiator under air atmosphere. The curing kinetics of HEMA‐terminated PU film were studied. The curing analysis, using FTIR and reaction kinetics, indicate the reaction rate equation correlates well with the film thickness [T], initiator concentration [I], unreacted double bond concentration [C?C], and exposed energy [E] of the reaction system. The kinetic rate equation for the UV‐curable reaction can be written as © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3162–3166, 2004 相似文献
92.
Temperature measurements have been performed in the process of electron‐beam curing of EB‐I and EB‐II epoxy resin systems. The influence of initiator content, resin type, and dose rate on the temperature of the systems was studied. Transverse and longitudinal temperatures of samples in the glass vessel were also analyzed. The nature of temperature curves varied with the different epoxy resin systems in the steel mold, but did not change with different contents of the initiator. At the same time, the heat had no effect on the gel fraction of epoxy resin systems. The temperature curve was greatly affected by the dose rate, and its peak value, peak width, and plateau value also increased with it. The transverse temperature of EB‐II glass vessel samples increased as the radiation dose increased and, in the same sample, the temperature reduced as the distance between the radiation center and the test point increased. The longitudinal temperature of EB‐I and EB‐II resin systems in a glass vessel decreased as the radiation depth increased. As the radiation dose increased, the temperature of the EB‐I resin system increased simultaneously, while that of the EB‐II resin system initially increased and then kept constant when the dose reached a certain value. The temperatures of these two resin systems decreased rapidly when the radiation process stopped. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2217–2222, 2004 相似文献
93.
94.
用动态DSC研究了笼型γ-氨丙基倍半硅氧烷/环氧树脂纳米杂化复合体系的固化过程、最佳配比与热稳定性能,并用Ozawa和Kissinger—Akahira—Sunose等转化率法研究了固化反应动力学。结果表明,该体系固化峰值温度为85℃,终了温度为118℃,最佳NH2与环氧基摩尔比为0.75,热分解最高起始温度为336-356℃。Ozawa法更适合本体系的动力学分析,固化反应表观活化能为71.0765kJ/mol,反应级数为0.9855级。 相似文献
95.
研究试验温度和停放时间对胶料加工性能的影响。结果表明,试验温度对胶料的门尼粘度、门尼焦烧时间和硫化特性均有一定影响。门尼粘度测定的试验温度选择100℃;门尼焦烧时间测定的试验温度一般选120℃,SBR胶料可提高至130℃左右,以缩短试验时间;硫化特性测定的试验温度一般选185℃。试验前模腔达到规定温度后再保持15min,以使转子与模腔温度一致。胶料停放时间应控制在2h左右。 相似文献
96.
The present study investigates the decomposition of N-Methyl-2-Pyrolidone (NMP) using conventional ozonation (O3), ozonation in the presence of UV light (UV/O3), hydrogen peroxide (O3/H2O2), and UV/H2O2 processes under various experimental conditions. The influence of solution pH, ozone gas flow dosage, and H2O2 dosage on the degradation of NMP was studied. All ozone-based advanced oxidation processes (AOPs) were efficient in alkaline medium, whereas the UV/H2O2 process was efficient in acidic medium. Increasing ozone gas flow dosage would accelerate the degradation of NMP up to certain level beyond which no positive effect was observed in ozonation as well as UV light enhanced ozonation processes. Hydrogen peroxide dosage strongly influenced the degradation of NMP and a hydrogen peroxide dosage of 0.75 g/L and 0.5 g/L was found to be the optimum dosage in UV/H2O2 and O3/H2O2 processes, respectively. The UV/O3 process was most efficient in TOC removal. Overall it can be concluded that ozonation and ozone-based AOPs are promising processes for an efficient removal of NMP in wastewater. 相似文献
97.
积层多层板用UV油墨的合成研究 总被引:1,自引:0,他引:1
采用丙烯酸改性环氧树脂E-44的方法,合成了环氧丙烯酸酯预聚物,并将其用在UV光固化油墨的配方中。在树脂合成过程中,研究了反应温度,催化剂,阻聚剂等因素对合 产品的影响。通过L9(3^4)正交试验,得到了优化的工艺参数:反应温度为90℃,催化剂为N,N-二甲苯胺,用量1%;阻聚剂对苯二酚,用量0.5%,投料环氧树脂和丙烯酸的摩尔比为1:1.08。 相似文献
98.
Advanced oxidation processes are defined as those which involve the generation of hydroxyl radicals in sufficient quantity to affect water purification. The theoretical and (practical yield of OH from O3 at high pH, 03/H202, O3/UV and H2O2/UV systems is reviewed. New data is presented which illustrates the importance of direct photolysis in the O3/UV process, the effect of the H202:03 ratio in the O3/H2O2 process, and the impact of the low extinction coefficient of H2O2 in the H202/UV process. 相似文献
99.
The effect of TiO2 nanoparticles for sun-weathering protection of UV-cured coatings is investigated. TiO2 is either introduced in the form of nanoparticles in the photocurable formulations or generated in situ via sol–gel process. Cured films containing comparable amounts of TiO2 were weathered for 800 h under UV irradiation and compared with free-TiO2 coating. The TiO2 presence induces a clear lower mass loss decrease during weathering as well as a lower gel content decrease. The TiO2 screen effect is also confirmed by a lower alkyl-band reduction monitored by FT-IR during weathering. The TiO2 generated in situ via sol–gel gives rise to transparent coatings without interfering with photopolymerization process and therefore without compromising UV-cured film properties. 相似文献
100.
Emulsion polymer isocyanate (
), polyvinyl acetate (
) and resorcinol-formaldehyde (
) adhesives were used to produce single lap shear specimens using resinous and non-resinous apitong (Dipterocarpus spp.) timbers. Tests showed that joints made with highly resinous apitong were about 40% weaker than similar joints made with non-resinous apitong. The resinous apitong was treated with different solvents to yield five different extractives which were characterized by infra-red analysis. Apitong extractives were then added to
and
adhesives and joints made with buna (Fagus crenata), a timber known to be low in extractives and easy to bond. Joints prepared using extractive-containing adhesives were generally weaker than those made with the unmodified adhesives. RF adhesives containing extractives cured more slowly than unmodified
. It is thought that the acidic nature of the extractives changes the pH of the system sufficiently to affect the curing mechanism 相似文献