分散因素对氯乙烯微悬浮聚合的影响及对策

本文对氯乙烯微悬浮聚合中影响氯乙烯分散的诸因素:乳化剂及其助剂,氯乙烯以及分散系统自聚等进行了分析,并针对目前生产中出现的问题提出相应对策。     

磁场作用下铁在盐酸和氯化钠溶液中自腐蚀状态的变化

采用自腐蚀电位测量及恒电位极化法研究了磁场对铁在酸性与中性氯化的溶液中自腐蚀状态的作用。外加磁场使自腐蚀电位正移，撤去磁场使自腐蚀电位负移，没有磁场时在自腐蚀电位下极化然后外加磁场会导致磁致阴极电流；有磁场时自腐蚀电位下极化然后撤去磁场会导致磁致阳极电流。酸性溶液体系的磁致阴极电流值明显大于中性溶液体系，表现出磁场主要通过作用于析氢反应而影响自腐蚀状态。     

用失效的C－Pd催化剂生产氯化钯

介绍了用锌镁粉直接还原与处理失效废弃的Ｃ－Ｐｄ催化剂，并用自制混酸直接生产氯化钯的工艺。该工艺比传统的铝粉置换法更快捷，钯收率更高。     

氧化还原引发乳液聚合单体水溶性与动力学之间的关系

本文研究了以过硫酸钾／焦亚硫酸钠为氧化还原引发体系，在苯乙烯、醋酸乙烯酯为具体单体的乳液聚合中，单体水溶性与动力学之间的关系。通过实验考察了聚合温度、搅拌速率、电解质浓度对聚合反应转化率～时间关系的影响，并讨论了单体水溶性、自由基水相反应和聚合速率等之间的内在联系。同时得出该氧化还原引发下苯乙烯和醋酸乙烯酯体系的表观活化能分别为４７．０６ｋｊ／ｍｏｌ和约７０ｋＪ／ｍｏｌ。     

VAc／MMA半连续乳液共聚合的研究：Ⅰ种子乳液共聚合

以过硫酸铵为引发剂，十二烷基硫酸钠为乳化剂，于７０℃下进行了ＶＡｃ＝ＭＭＡ种子乳液共聚合。试验考察了组分和操作条件对体系稳定性，聚合速度及组成分布等的影响，同时，从理论上给出了加料速率与体系稳定性因子间的关系。     

Round-Robin Test on methods for determining chloride transport parameters in concrete

This paper presents the results of a Round-Robin Test on methods for determining chloride transport parameters in concrete, carried out by the Technical Committee TC 178-TMC: “Testing and Modelling Chloride Penetration in Concrete” in which 27 different laboratories around the world have participated, using 13 different methods, in triplicate specimens, for 4 different mixes of concrete cast with different binders. Four different groups of methods have been tested: Natural diffusion methods (D), Migration methods (M), Resistivity methods (R) and Colourimetric methods (C). The statistical treatment of the data has been carried out according to the International Standard ISO 5725-2:1994 for the determination of the accuracy (trueness and precision) of measurement methods and results. Part 2: Basic method for the determination of the repeatability and reproducibility of a standard measurement method. In order to make an evaluation of these methods, four indicators have been identified and within each of them, several sub-indicators have been assigned. According to this system of classification, the methods have been classified following each indicator (trueness, precision, relevance and convenience), and also globally, by assigning different factors of importance, F.I., to the different indicators.     

Electrochemical corrosion behavior of carbon-based thin films in chloride ions containing electrolytes

Commercially available carbon-based thin films consisting of single layers of amorphous diamond-like carbon or multilayers of crystalline TiAlN or CrN with diamond-like carbon top coatings were evaluated in relation to their electrochemical corrosion behavior in chloride ions containing electrolytes. The hardened working steel (an alloy of 0.9% C, 4.1% Cr, 4.9% Mo, 1.8% V, 6.4% W) was used as a substrate material.The potentiodynamic corrosion behavior of coated samples was tested in 3.5 wt.% NaCl solution and Hank's balanced body solution, HBBS (0.89 wt.% NaCl, further chlorides, sulfates, carbonates and phosphates). The multi-layers TiAlN + a-C:H:W and CrN + a-C:H:W exhibited only a minor improvement in corrosion resistance. Single layers of amorphous diamond-like carbon coating without hydrogen (a-C) spall off during the corrosion tests in chloride containing media. A minor improvement of the corrosion resistance is possible. The a-C:H and the a-C:H:Si, which contain hydrogen, showed the best corrosion resistance with a 100 times lower corrosion current density.     

聚醋酸乙烯酯共聚胶液的改性研究

聚醋酸乙烯酯作为常用的胶粘剂之一,有明显的优点,但随着环保和绿色生活的要求,其有毒和耐水性等缺陷影响了其更好发展.本研究利用醋酸乙烯酯与其它烯类单体的共聚,制备出了无毒、快干、胶接强度高、耐水性好的高性能聚醋酸乙烯酯共聚改性胶液,并对其相关影响因素及工艺条件的确定进行了讨论.     

阴离子交换树脂吸附镉的动力学研究

研究了强碱性阴离子交换树脂吸附镉的主要动力学因素。通过实验找出了过程的限制环节，推算出交换反应的活化能、反应级数及动力学方程。     

钴白合金湿法冶金工艺研究

本文研究了钴白合金湿法冶炼工艺流程,详细进行了氯气浸出－电溶脱铜－ＴＢＰ萃取除铁试验研究。试验条件下,钴、铜、铁浸出率均达到９９％,且分离效果良好。文章给出了钴白合金冶炼原则工艺流程。