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81.
Cl~-浓度对316L不锈钢点蚀行为的影响 总被引:1,自引:0,他引:1
运用电化学动电位扫描、电化学交流阻抗技术、金相显微以及电子扫描显微技术,对常温常压下,不同浓度的Cl-对316 L不锈钢的CO2腐蚀作用进行了一系列实验。经过实验结果发现,316 L不锈钢呈现出整体腐蚀速率不高而局部腐蚀严重的态势,当氯离子的浓度升高时,316 L的腐蚀表现出整体腐蚀速率有很小的上升,而点蚀电位随着氯离子浓度的上升而降低,导致严重的点蚀。说明氯离子浓度的升高使点蚀电位严重下降,在该环境下316 L不锈钢的腐蚀主要为点蚀特征。 相似文献
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83.
Qifeng Zhang Zhengbo Zhou Tian Fang Han Gu Yanglong Guo Wangcheng Zhan Yun Guo Li Wang 《中国稀土学报(英文版)》2022,40(9):1462-1470
Spherical CeO2 synthesized by the hydrothermal process was used as support to prepare Pt/WO3/CeO2,and the effects of tungsten(W) contents on activity,stability and polychlorinated by-products were investigated to understand the role of W for vinyl chloride(VC) catalytic oxidation.The introduction of12 wt% W to Pt/CeO2(P12 WC) exhibits the highest catalytic activity with 90% conversion of VC at 250℃,meanwhile the stability improves and the polychlorinat... 相似文献
84.
85.
This paper presents the chloride penetration and the effect of chloride ingress on the serviceability of reinforced concrete (RC) beams. A series of experimental studies were carried out on beams with various corroded ages up to 28 years. The chloride content in different locations were tested during various periods. Different states influencing the serviceability of the corroded beams were investigated, including the maximum width of the corrosion-induced cracks of the concrete cover, the mid-span deflection of the beams under the service load and their load-bearing capacity. Based on the results available from this programme, the service life of corroded beams was predicted by the corrosion process of the reinforcement. The results showed that the chloride corrosion could significantly deteriorate the serviceability of the beams. The current criteria concerning the chloride content at the level of the reinforcement of the concrete beams and the maximum width of the corrosion-induced cracks appear to be very conservative. 相似文献
86.
The degradation of 4-chlorophenol (4-CP) contaminated water by Fenton process with or without solar irradiation assistance were investigated. It was found that the COD degradation and mineralization efficiency of 4-CP were more than 90% when a 30 min treatment of solar photo-Fenton oxidation process was applied and under an optimum [H2O2]0/[Fe2+]0 ratio of 40, the COD degradation and mineralization efficiency increased 65% as compared to Fenton oxidation. Meanwhile, the AOS values increased from −0.33 to 2.13 in solar photo-Fenton process while no significant improvement for AOS values was found in Fenton process, implying a higher degree of oxidation for 4-CP in solar photo-Fenton process. In addition, increasing the intensity of solar irradiation seemed to be beneficial for treatment of 4-CP contaminated water. Formation of chloride ion as a result of mineralization of organically bounded chlorine was identified during the treatment of 4-CP solution. Near-stoichiometric accumulation of chlorine was observed during the degradation of 4-CP in both Fenton and solar photo-Fenton processes. However, accumulation rate of chloride ions were much faster in solar photo-Fenton process. The degradation of 4-CP was found to obey a pseudo-first-order reaction kinetics. As compared to Fenton process, the presence of solar light in photo-Fenton process increases the reaction rate by a factor of 6.5 and 15.8 for COD and TOC degradation, respectively. In other words, during the treatment of 4-CP contaminated water, solar photo-Fenton process possesses notably higher mineralization efficiency in a relatively short radiation time as compared to Fenton process, and could enhance the degradation treatment of refractory organic wastewater such as 4-CP in a cost-effective approach. 相似文献
87.
Non-saturated ion diffusion properties of cementitious materials were evaluated in an experimental study. To assess these properties, resistivity measurements have been performed on mortars with different binders (ordinary Portland cement – OPC, OPC with 5% silica fume, 40% slag and 70% slag, respectively) and different water-to-binder ratios (w/b, 0.38 and 0.53). Specimens have been conditioned to eight different climates with relative humidity (RH) from 100% to 33% RH in order to assess an effective diffusion coefficient. The results from the resistivity measurements have been corrected for changes of the conductivity of the pore solution when drying to different degrees of saturation.The diffusion coefficients for Portland cement binders within the range 100–59% RH are presented. They showed that the diffusion coefficient of the mortar with high w/b ratio was higher at high RH, but at low RH the opposite trend was found. By comparing these results with the corresponding desorption isotherms, it is shown that the diffusion coefficient for the two w/b ratios have the same dependency on the degree of saturation. 相似文献
88.
Michael Horst Andrea L. Welker Robert G. Traver 《Canadian Metallurgical Quarterly》2011,137(6):352-358
The use of infiltration storm-water best management practices (BMPs) has become a more commonly used approach as a means of reducing postdevelopment runoff volumes in many areas throughout the United States. Although studies regarding the performance of infiltration BMPs are emerging, much remains to be learned about their design, construction, and operation. The increase in knowledge will improve the performance and longevity of these BMPs. The performance of one such infiltration basin over a 2-year cycle is presented in this paper. The study site is a pervious concrete infiltration basin BMP built in 2002 in a courtyard common area at Villanova University. The system consists of three linked infiltration beds lined with geotextile filter fabric, filled with coarse aggregate, and overlaid with pervious concrete. The natural soil beneath the infiltration BMP is a silty sand. The BMP is extensively instrumented to facilitate water quantity and quality research. Both water-quantity and -quality results are presented. The water-quantity analysis showed that the performance of the basin was directly related to its infiltration characteristics. The infiltration rate of the silty sand is cyclic, with higher rates during warmer periods and lower rates during colder periods. The water quality analysis investigated the pollutant reduction for chloride, copper, nitrogen, and phosphorus from the inlet to the surface-water outlet of the structure, as well as differences in pollutant concentration levels between the basin, surrounding ground, and varying soil layer elevations beneath the basin. In general, the pollutant reduction to the surface waters was greater than 90% from inlet to outlet, primarily influenced by the infiltration of the storm water into the natural soils below the BMP. The pollutant concentration of the infiltrating runoff was found to be higher than expected in the area adjacent to the bed when compared to concentration levels found at a similar depth beneath the infiltration bed. Comparison of pollutant concentration levels, as the water moved from within the storage bed to the soil beneath the bed, were shown to vary, with statistical differences found for mean concentration levels of both pH and copper levels; and no statistical differences were found for conductivity, total phosphorous, and chloride at each elevation. 相似文献
89.
本文围绕提高氯化锌电池放电容量,将本厂工艺实验和生产实践进行了总结和分析,论述了影响放分的诸因素,提出了提高电池容量的一些措施。 相似文献
90.
本文探讨了提高R6P高功率电池间歇放电时间的一种新途径,提出了电解二氧化锰的合理配比及合理锰碳比的新思路,使该电池10Ω 60min/d间歇放电时间突破400min大关。 相似文献