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981.
982.
《International Journal of Hydrogen Energy》2019,44(45):24342-24352
To achieve high activity and stability for both hydrogen and oxygen evolution reactions through the non-precious-metal based electrocatalysts is still facing the great challenge. Herein, we demonstrate a facile strategy to prepare CoP nanoparticles (NPs) loaded on N, P dual-doped carbon (NPC) electrocatalysts with high concentration N and P dopants through a pyrolysis-deposition-phosphidation process. The great bifunctional electrocatalytic activity for both HER (the overpotential of 98 mV and 86 mV at 10 mA cm−2 in both 0.5 M H2SO4 and 1 M KOH electrolytes, respectively) and OER (the overpotential of 300 mV at 10 mA cm−2 in 1 M KOH electrolyte) were achieved. When CoP@NPC hybrid was used as two electrodes in the 1 M KOH electrolyte system for overall water splitting, the needed cell potential for achieving the current density of 10 mA cm−2 is 1.6 V, and it also showed superior stability for HER and OER after 10 h’ test with almost negligible decay. Experimental results revealed that the P atoms in CoP were the active sites for HER and the CoP@NPC hybrid showed excellent bifunctional electrocatalytic properties due to the synergistic effects between the high catalytic activity of CoP NPs and NPC, in which the doping of N and P in carbon led to a stronger polarization between Co and P in CoP, promoting the charge transfer from Co to P in CoP, enhancing the catalytic activity of P sites and Co sites in CoP for HER and OER, respectively. Specifically, the improvements could result from the changed charge state, the increased active specific surface area, and the facilitated reaction kinetics by N, P co-doping and admixture. This work provides a high-efficient, low-cost and stable electrocatalyst for overall water splitting, and throws light on rational designing high performance electrocatalysts. 相似文献
983.
《International Journal of Hydrogen Energy》2019,44(47):25652-25661
Surface decoration of photoanodes with oxygen evolution cocatalysts is an efficient approach to improve the photoelectrochemical water splitting performance. Herein, ultrafine CoOx was selectively immobilized on the surface of BiVO4/WO3 photoanode by using the photogenerated holes to in-situ oxidize Co4O4 cubane. The composited photoanode (CoOx/BiVO4/WO3) displayed an enhanced photoelectrochemical (PEC) water oxidation performance, with a photocurrent density of 2.3 mA/cm2 at 1.23 VRHE under the simulated sunlight irradiation, which was 2 times higher than that of bare BiVO4/WO3. The characterization results for the morphological, optical and electrochemical properties of the photoelectrodes revealed that, the enhanced PEC performances could be attributed to the improved charge carrier separation/transport behaviors and the promoted water oxidation kinetics when the photoelectrodes were loaded with CoOx. 相似文献
984.
《International Journal of Hydrogen Energy》2019,44(48):26373-26386
Production of hydrogen and oxygen from water splitting reaction under visible light is a simple method for conversion of solar-to-hydrogen energy and it is a hopeful clean and renewable method for H2 fuel generation. However, there is still a lack of potential materials with significant activity under visible light. Because of safety, chemical inertness, low cost, stability and other characteristics, transition metal oxide semiconductors have been widely applied as photocatalysts for hydrogen generation. Albeit, wide usage of semiconductor photocatalysts were prevented by its inability to exploit solar energy of visible region. Here we show synthesis of a nano-sized mixed metal oxide (MMO) Ca3MnO6 through wet-chemistry methods such as co-precipitation, ultrasonic, microwave, reflux, and hydrothermal methods. The nano-sized Ca3MnO6 has initially selected based on morphology and respective particle diameters. The selected sample shows a well-defined single crystal, free from any impurities, complete structural formation, and a band gap energy (Eg) of around 5.3 eV. The best product synthesized in ultrasonic method which shows the best morphology, purity and the highest efficiency for splitting of water to hydrogen and oxygen. Irrespective of preparation methods and morphologies, all samples split water into hydrogen and oxygen, as confirmed from their respective photocatalytic analysis. When the selected sample combined with (NH4)2Ce(NO3)6, the single-crystal Ca3MnO6 nanoparticles split water into hydrogen and oxygen more efficiently under visible light. Our findings demonstrate the importance of nanostructured Ca3MnO6 single-crystal photocatalysts in solar water splitting. 相似文献
985.
《International Journal of Hydrogen Energy》2019,44(36):19650-19657
To split water and produce hydrogen by white light is an excellent solution for the storage and supply of clean and sustainable energy. Efficiency and stability are the key challenges for a successful exploitation. InGaN, evaluated against other semiconductors, metal oxides, carbon based - and organic materials has most suited intrinsic materials properties. Based on this optimum materials choice we report photoelectrochemical (PEC) hydrogen generation under white light illumination by an InGaN-based quantum nanostructure photoelectrode. No degradation occurs for operation over 10 h. Our novel concept, combining quantum nanostructure physics with electrochemistry and catalysis leads to almost 10% efficiency at zero external voltage. The efficiency rises above 25% at 0.2 V. This is unmatched for a single photoelectrode, representing the most advanced technology of low complexity. 相似文献
986.
Ying‐Pei Shen Jhen‐Jhan Wong Chi‐Ching Yang Ta‐Chen Lin 《International Journal of Food Science & Technology》2012,47(8):1720-1727
Roasted sweet potato is a popular food because of the attractive aroma produced by the Maillard reaction. However, the roasting process may lead to charred skin. Cooking with superheated (saturated) steam provides a solution to this problem. As the results show, when comparing sweet potatoes cooked by superheated steam, and those roasted for 40 min, respectively, the degree of gelatinisation could reach as high as 95% with only 140 °C superheated steam, while roasting required temperatures up to 240 °C. Moreover, in appearance, the skins of the sweet potatoes cooked using superheated steam were not charred like the roasted ones. However, sweet potatoes roasted at 240 °C for 60 min had the highest overall sensory score. When comparing the antioxidant activity, the sweet potatoes cooked by superheated steam had the highest content of total phenol and flavonoids, the best scavenging ability of 1,1‐diphenyl‐2‐picrylhydrazyl (DPPH) and the highest ferric‐reducing ability of plasma (FRAP). 相似文献
987.
Jitendra Sharma Prabhakaran Ponnusamy Pazhaniandi Vinay Kumar Tanwar Sudip Kumar Das Meena Goswami 《International Journal of Food Science & Technology》2012,47(1):61-66
This investigation was carried out to evaluate the antioxidant effect of turmeric (turmeric 1000 ppm, turmeric 5000 ppm), nitrite (nitrite 200 ppm) and ascorbic acid (ascorbic acid 500 ppm) on raw minced chicken stored at 4 ± 1 °C. Physicochemical properties [pH, water activity, cooking loss, thiobarbituric acid (TBA) value, peroxide value (PV), free fatty acid (FFA)] were evaluated on 0, 2, 4 and 6th day of storage. Highly significant differences (P < 0.01) in pH, TBA value, PV and FFA value were noticed between treatments and between storage periods. TBA values were observed to be lowest for nitrite 200 ppm and then turmeric 5000 ppm, and there was no significant difference between nitrite 200 ppm and turmeric 5000 ppm, and both were superior to ascorbic acid 500 ppm and turmeric 1000 ppm. Among different treatments, PV was found to be lowest in turmeric 5000 ppm and highest in nitrite 200 ppm. FFA value was found to be lowest in turmeric 5000 ppm and highest in ascorbic acid 500 ppm among all treated samples. It can be concluded that turmeric has potential to replace synthetic antioxidants presently used in meat processing with many added advantages. 相似文献
988.
M. Valcuende C. ParraE. Marco A. GarridoE. Martínez J. Cánoves 《Construction and Building Materials》2012,28(1):122-128
The objective of this experimental work is to study porosity in self-compacting concrete (SCC) made without adding limestone filler, comparing the results with other SCC and with normally-vibrated concrete (NVC). Several types of concrete were made, keeping the w/c ratio constant. The results show that the air content in SCC depends on the flowability and viscosity of the material, putting a forward an expression to estimate the air content in accordance with these two parameters. SCC shows a finer and more tortuous porous structure than NVC, leading to lower permeability to water under pressure. Nevertheless, in the absence of pressure, when water penetrates by capillary action, the results obtained from the different types of concrete were very similar, with differences below 3.5%. This is due to the fact that the content of pores over 0.5 μm is practically the same in SCC and NVC, but for smaller pore sizes, which are therefore only accessed when water under pressure is applied, the differences in porosity between the different samples is more pronounced. On the other hand, it was observed that the use of more fluid mixtures permitted more impermeable concrete to be obtained. The use of viscosity-modifying admixture on SCC as a replacement for limestone filler does not affect the total volume of pores, but generates a slightly more coarse porous microstructure, thereby leading to concretes in which water penetration depth under pressure is a little higher (around 4 mm). 相似文献
989.
Hong Van Le Van Viet Man Le 《International Journal of Food Science & Technology》2012,47(6):1206-1214
This article describes a comparative study of enzyme and ultrasound techniques for the simultaneous extraction of vitamin C and phenolic compounds from acerola fruit. Ultrasound‐assisted extraction (UAE) took only 6 min to achieve the highest level of vitamin C and phenolic compounds as well as antioxidant activity of acerola juice, while enzyme‐assisted extraction (EAE) took up to 120 min to obtain the maximal values. On the basis of kinetic model of second‐order extraction, the extraction rate constant of vitamin C and phenolics in UAE increased approximately 3.1 and 2.7 times, respectively, in comparison with that in EAE. In addition, the maximal level of vitamin C, phenolics and the antioxidant activity evaluated by 1,1‐diphenyl‐2‐picrylhydrazyl (DPPH), and 2,2′‐azinobis‐(3‐ethylbenzothiazoline‐6‐sulphonic acid) (ABTS) methods in UAE was 4.6%, 3.5%, 4.6% and 3.3%, respectively, higher than those in EAE. Obviously, UAE is a useful method for the extraction of antioxidants from plant materials. 相似文献
990.