Complete oxidation of methane at low temperature over Pt and Pd catalysts for the abatement of lean-burn natural gas fuelled vehicles emissions: influence of water and sulphur containing compounds

The catalytic activity of fresh Pd and Pt catalysts supported on γ-alumina in the complete oxidation of CH₄ traces under lean-burn conditions was studied in the presence or the absence of water or H₂S. Steam-aged catalysts were also studied in order to simulate long-term ageing in real lean-burn natural gas fuelled vehicles (NGVs) exhaust conditions. Without water or H₂S added to the feed, Pd catalysts exhibit a superior catalytic activity in methane oxidation compared to Pt ones, whatever the catalysts were fresh or aged. The addition of 10 vol.% water vapour to the feed strongly affects the activity of the fresh Pd catalyst, thus being only slightly more efficient than the fresh Pt one. H₂S has a strong poisoning effect on the catalytic activity of Pd catalysts, while Pt catalysts are more resistant. The fresh H₂S-poisoned Pd/Al₂O₃ catalyst was studied by TPD in O₂/He. Poisoning species decompose above 873 K as SO₂ and O₂ in relative concentrations consistent with the decomposition of surface sulphate species. However, a treatment in O₂/He at temperatures as high as 923 K does not allow the complete regeneration of the catalytic activity of H₂S-poisoned Pd/Al₂O₃. A mechanism involving the poisoning of PdO by sulphate species is proposed. Different diffusion processes by which these sulphate species can migrate back and forth between PdO and the support, depending on the experimental conditions, are suggested.     

分析再热器超温爆漏与水冷壁结焦控制量的关系

文章介绍了宝钢自备电厂在改善锅炉燃烧工况，控制锅炉水冷壁结焦所采取的技术措施，分析了锅炉水冷壁结焦量与锅炉二次再热器烟气出口平均温度的关系，为解决锅炉水冷壁结焦所引发的二次再热器超温爆漏问题提供了依据。     

测井岩性类比解释法及应用

利用理想的地质体积模型和电阻率测井的供电电流流过模型的导电机理,推导出一种不需要含水饱和度参数即能定量计算含水饱和度的方法,即岩性类比解释法。经过初步实践,该方法应用于砂泥岩地层的测井分析,效果良好。     

岩心PI值试验研究及应用

主要论述了在多功能采油化学用剂评价仪上进行的岩心ＰＩ值试验的步骤，现象及结论。重点考察了岩心ＰＩ值与渗透率、流量及注入截面面积的关系；平行管岩心复合ＰＩ值和其中单管岩心ＰＩ值的关系。     

三维定量储层地质模型与参数动态预测方法

提出了三维定量储层地质模型及其参数动态预测方法，用该方法可预测储层开采状态，水淹区及剩余油区分布和各剩余油区的可采储量，三维定量储层地质模型的预测图件可为合理开采提供依据。     

东营深层盐膏层钻井液工艺

胜利油田东营深层盐膏地层发育,盐膏段厚度大,分布范围广,地层岩性十分复杂,钻井中经常发生喷、漏、塌、卡,遇阻、划眼、电测遇阻等井下复杂事故。郝科1井是在该区设计的一口重点深探井,宅钻井深5807.81m,井底最高温度230℃。介绍了深层盐膏层钻井液体系的转化工艺、性能控制、维护处理、防漏、堵漏、固相控制、抗污染和钻具缓蚀等技术,以及MMH聚合物饱和盐水钻井液在郝科1井的成功应用。结果表明,该钻井液在高密度下对盐膏层具有较强的抑制性、悬浮携砂性和抗污染性,抗温220—230℃。MMH聚合物饱和盐水钻井液体系及其配套技术满足了深层盐膏层钻井施工需要。     

工业用水中硅酸根离子分析技术的现状与发展

综述了工业用水中硅酸根离子的基本分析方法以及分析仪器的开发应用现状；论述了流动注射分析技术（ＦＩＡ）在工业用水中硅酸根离子分析上的应用并预示了水质分析中在线预富集技术与多组分联合测定技术的发展。     

离子色谱技术在钻井现场的应用研究

将离子色谱技术(IC)应用于钻井现场的钻井液滤液分析,从而获取所钻井钻遇地层的可溶性矿物的性质、地层水的类型等资料信息。离子色谱技术在这一领域的应用尚属探索阶段,但通过现场两口井的试用已见到较好的应用效果,文章简介了该技术的应用前景及价值,如:确定油水界面的位置及指导钻井液的调配、确保井下安全等。这方面的论述,对分析化验仪器向井场转移实现多手段综合分析具有一定的促进作用。