全文获取类型
收费全文 | 8999篇 |
免费 | 928篇 |
国内免费 | 719篇 |
专业分类
电工技术 | 384篇 |
综合类 | 691篇 |
化学工业 | 1761篇 |
金属工艺 | 590篇 |
机械仪表 | 301篇 |
建筑科学 | 245篇 |
矿业工程 | 110篇 |
能源动力 | 254篇 |
轻工业 | 426篇 |
水利工程 | 86篇 |
石油天然气 | 188篇 |
武器工业 | 42篇 |
无线电 | 1172篇 |
一般工业技术 | 669篇 |
冶金工业 | 484篇 |
原子能技术 | 257篇 |
自动化技术 | 2986篇 |
出版年
2024年 | 19篇 |
2023年 | 110篇 |
2022年 | 213篇 |
2021年 | 233篇 |
2020年 | 200篇 |
2019年 | 158篇 |
2018年 | 153篇 |
2017年 | 202篇 |
2016年 | 241篇 |
2015年 | 251篇 |
2014年 | 425篇 |
2013年 | 466篇 |
2012年 | 611篇 |
2011年 | 735篇 |
2010年 | 747篇 |
2009年 | 897篇 |
2008年 | 791篇 |
2007年 | 835篇 |
2006年 | 736篇 |
2005年 | 435篇 |
2004年 | 356篇 |
2003年 | 287篇 |
2002年 | 320篇 |
2001年 | 218篇 |
2000年 | 200篇 |
1999年 | 162篇 |
1998年 | 96篇 |
1997年 | 89篇 |
1996年 | 62篇 |
1995年 | 61篇 |
1994年 | 41篇 |
1993年 | 49篇 |
1992年 | 34篇 |
1991年 | 32篇 |
1990年 | 32篇 |
1989年 | 22篇 |
1988年 | 15篇 |
1987年 | 14篇 |
1986年 | 4篇 |
1985年 | 13篇 |
1984年 | 12篇 |
1983年 | 10篇 |
1982年 | 12篇 |
1981年 | 15篇 |
1980年 | 12篇 |
1979年 | 5篇 |
1978年 | 5篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
Natural amorphous polymer poly(3‐hydroxybutyrate‐co‐4‐hydroxybutyrate) (P3HB4HB) containing 41 mol % of 4HB was blended with poly(3‐hydroxybutyrate) (PHB) with an aim to improve the properties of PHB. The influence of P3HB4HB contents on thermal and mechanical properties of the blends was evaluated with differential scanning calorimetry (DSC), Fourier transform infrared (FTIR) spectroscopy, stress–strain measurement and thermo gravimetric analyzer. Miscibility of PHB/P3HB4HB blends was mainly decided by the contents of P3HB4HB. When P3HB4HB exceeded 50 wt %, the two polymer phases separated and showed immiscibility. The addition of P3HB4HB did not alter the crystallinity of PHB, yet it diluted the PHB crystalline phase as revealed by DSC studies. DSC and FTIR results showed that the overall crystallinity of the blends decreased remarkably with increasing of P3HB4HB contents. Decreased glass transition temperature and crystallinity imparted desired flexibility for the blends. The ductility of the blends increased progressively with increasing of P3HB4HB content. Thus, the PHB mechanical properties can be modulated by changing the blend composition. P3HB4HB did not significantly improve the thermal stability of PHB, yet it is possible to melt process PHB without much molecular weights loss via blending it with suitable amounts of P3HB4HB. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
62.
63.
Granados M. López Galisteo F. Cabello Lambrou P. S. Alifanti M. Mariscal R. Gurbani A. Sanz J. Sobrados I. Efstathiou A. M. Fierro J. L. G. 《Topics in Catalysis》2007,42(1-4):443-447
The chemical nature of P-containing species of varying concentration present in CeO2 after impregnation with (NH4)2HPO4 and calcination at 1273 K, and their effects on the oxygen storage and release (OSR) properties of ceria are reported for
the first time. The samples were characterized by different techniques and the results were compared with those recently reported
on the same samples but calcined at 873 K. When P-containing ceria solids were calcined at 1273 K, CePO4 (monazite) was the predominant P-containing species on the surface of ceria, confirming previous studies that showed that
monazite exists for those samples in which the surface P loading (P atoms per nm−2) is larger than 5.5. For lower surface P concentrations, isolated orthophosphate units are present at the surface and within
the subsurface region of the solid. Severe sintering of CeO2 after calcination at 1273 K resulted in P concentrations >5.5 P atoms·nm−2 in all samples. Isolated PO4 units that could initially be present in the samples calcined at 873 K nucleated and CePO4 was formed when samples were calcined at 1273 K. OSR properties of CeO2 deteriorated progressively when P loading increased due to the presence of larger crystals of the very stable Ce(III) phase
of CePO4 at the surface of the P-containing ceria solids. 相似文献
64.
Ruan Ke-He; Milfeld Kent; Kulmacz Richard J.; Wu Kenneth K. 《Protein engineering, design & selection : PEDS》1994,7(11):1345-1351
A 3-D model of human thromboxane A2 synthase (TXAS) was constructedusing a homology modeling approach based on information fromthe 2.0 crystal structure of the hemoprotein domains of cytochromeP450BM-3 and P450cam. P450BM-3 is a bacterial fatty acid monooxygenaseresembling eukaryotic microsomal cytochrome P450s in primarystructure and function. TXAS shares 26.4% residue identity and48.4% residue similarity with the P450BM-3 hemoprotein domain.The homology score between TXAS and P450BM-3 is much higherthan that between TXAS and P450cam. Alignment between TXAS andthe P450BM-3 hemoprotein domain or P450cam was determined throughsequence searches. The P450BM-3 or P450cam main-chain coordinateswere spplied to the TXAS main chain in those sements where thetwo sequences were well aligned. These segments were linkedto one another using a fragment search method, and the sidechains were added to produce a 3-D model for TXAS. A TXAS substrate,prostaglandin H2 (PGH2) was docked into the TXAS cavity correspondingto the arachidonic acid binding pocket in P450BM-3 or camphorbinding site in P450cam. Regions of the heme and putative PGH2binding cavities in the TXAS model were identified and analyzed.The segments and residues involved in the active-site pocketof the TXAS model provide reasonable candidates for TXAS proteinengineering and inhibitor design. Comparison of the TXAS modelbased on P450BM-3 with another TXAS model based on the P450BM-3with another TXAS model based on the P450cam structure indicatedthat P450BM-3 is a more suitable template for homology modelingof TXAS. 相似文献
65.
A. El Ghazali S. Belcadi J. J. Rameau F. Dalard 《Journal of Applied Electrochemistry》1998,28(7):725-735
Electrosynthesis of peroxodiphosphate ions (P2O84–) was performed in 2m K3PO4, 1m K2HPO4 medium, using a platinum anode. The results showed that under conditions of potentiostatic polarization at constant potential, the reaction rate reaches a maximum value of 125mAcm–2 and a faradaic yield of 30%. From about 1.9V, the reaction kinetics are increasingly inhibited as the potential shifts positively. Rapid scanning potential voltammetry was used to characterize the oxidation state of the electrode surface. This method shows that the growth of (PtO) and (PtO2 or PtO3) oxides depend on the applied potential. It also establishes a correlation between the inhibition of P2O84– ion electrosynthesis and the oxide coating surface. When 2×10–3m KSCN is added to the solution, some oxygen evolution sites are selectively blocked and oxide occurs at more positive potential values. Consequently, the rate of peroxodiphosphate ion formation and the faradaic efficiency are increased to 380mAcm–2 and 75%, respectively. Under pulsed potential conditions it was possible to reach 1200mAcm–2 for P2O84– ion electrosynthesis with a faradaic yield of 82%. 相似文献
66.
The availability to plants of fertilizer phosphorus (P) applied to soil, as measured by chemical extraction, is used to estimate P fertilizer needs. We studied the availability of P, applied as monocalcium phosphate (MCP) powder, ordinary superphosphate (OSP) granules and diammonium phosphate (DAP) granules in 24 calcareous Vertisols and Inceptisols of Andalusia, Spain, by using laboratory incubation techniques. The soils differed widely in their P adsorption- and Ca-phosphate precipitation-related properties. For MCP, availability (defined as the proportion of added P that is recovered by extraction with NaHCO3 or is isotopically exchangeable) decreased markedly with incubation time and increasing addition rate. The mean recoveries after 180 d of incubation at field capacity at a rate of 246 mg P kg–1 soil were 17% for Olsen P, 38% for Colwell P, and 16% for isotopically exchangeable P (IEP). Increasing the application rate to 2460 mg kg–1 resulted in recoveries of 6% for Olsen P, 25% for Colwell P, and 4% for IEP. While IEP-based recovery was not significantly correlated to any soil property, that based on Olsen P (and, to a lesser extent, Colwell P) decreased sharply with increase in the ratio of clay (or Fe oxides) to total (or active) calcium carbonate equivalent. Accordingly, Olsen P might overestimate P availability in those soils relatively rich in carbonate and poor in clay and Fe oxides. On the other hand, recovery of applied P from soils containing more clay and Fe oxides, by a sequential extraction (with H2O, two 0.5M NaHCO3 treatments, 0.5M HCl), was lower than 100%, thereby suggesting phosphate occlusion by Fe oxides or clay.Availability of the fertilizers tested 90 d after application was found to decrease in the following order: MCP powder (rate, 246 mg kg–1) > DAP granules (rate, 547 mg kg–1) > MCP powder (rate, 738 mg kg–1) > OSP granules (rate, 308 mg kg–1). Differences between fertilizers tended to increase with increasing carbonate content in the soil. This may have been due to precipitation of Ca phosphates caused by the presence of Ca in the fertilizer and the high Ca- supplying capacity of the more calcareous soils. 相似文献
67.
Five field experiments involving P application rates from 0 to 66 kg P ha–1 were conducted on irrigated wheat at Tandojam, Pakistan. The soils belonged to two great soil groups, Torrifluvent and Camborthid. All soils were calcareous. Olsen-P contents ranged from 3.5 to 6.3 mg P kg–1. Phosphate sorption curves were developed for soils from control (no P) plots at each site. Concentrations of P in solution established by fertilization in the field as estimated from the sorption curves ranged from 0.008 to 0.16mg P L–1. Actual grain yields were converted to relative grain yields and plotted against corresponding concentrations of P in solution. Yield response to P application was obtained in each experiment. Control plot yields ranged from 57 to 89% of maximum yield of respective experiments. Phosphorus requirements of wheat were 0.032 mg L–1 for 95% yield as determined from a composite yield response curve. Predicted quantities of P required to attain 0.032 mg P L–1 ranged from 18 to 29 kg P ha–1. The results of the study suggest that the P sorption approach can be used as a rational basis for making P fertilizer recommendations for various soil-crop combinations. 相似文献
68.
69.
Phosphorus (P) inputs are required for sustainable agricultural production in most acid soils of the tropics and subtropics. Phosphate rocks (PR) and organic materials have been suggested as alternative P sources in these soils. Quantitative information on the P availability from sewage sludge (SL) is scanty. Methods to improve the effectiveness of PR such as partial acidulation and compaction with water-soluble P sources have been recommended. The objective of this greenhouse study was to evaluate the relative agronomic effectiveness (RAE) of Florida PR and sewage sludges (irradiated and non-irradiated) applied alone and in mixture with a water-soluble source (triple superphosphate, TSP) at two rates (50 and 150 mg P kg–1 soil). The 32P isotope dilution technique was utilised to determine the proportion of P in the plant taken up from the P fertilizer treatments. Wheat was grown on an acid loamy sand Dystric Eutrocrepts and harvested 6 weeks after planting. Results on total P uptake and the RAE of the P fertilizer sources tested indicated that the addition of 50 mg P kg–1 soil as TSP was adequate in supplying P to the 6-week-old wheat plants as compared to PR and sewage sludge. Intermediate values were obtained for the mixtures. Similar responses were observed for the high P rate. For a given P rate, phosphorus uptake from PR and SL in presence of TSP was higher than P uptake from these sources alone, indicating an enhancement effect of TSP on the effectiveness of these non-readily available sources. With respect to P uptake from PR applied alone, the relative increases in P uptake from PR due to TSP influence were 52 and 67% for the low and high P rates, respectively. The relative increases in P uptake from SL due to TSP when compared to P uptake from SL alone were 102 and 59% for the low and high P rates of application. Application of a water-soluble P fertilizer together with a non-readily available P source shows an enhancement on the P uptake from the non-readily available P source by the wheat plants. In this experiment the estimated enhancement effects are very likely underestimated. 相似文献
70.
以酸性多孔ZSM-5沸石(HZSM-5-M)和高比表面积的氧化硅(SiO2)为载体,采用等体积浸渍法制备了负载Ni2P催化剂(Ni2P/HZSM-5-M和Ni2P/SiO2),对比研究了它们在苯乙炔选择性加氢反应中的催化性能。采用XRD、N2吸附-脱附、NH3-TPD、H2-TPR、SEM和TEM对载体及其负载的Ni2P催化剂进行了表征。催化剂活性结果为:当反应时间为2 h,苯乙炔在Ni2P/HZSM-5-M催化剂的转化率为98.5%,而在Ni2P/SiO2催化剂上仅为45.6%。说明Ni2P/HZSM-5-M催化剂的加氢活性显著高于Ni2P/SiO2催化剂。这是因为,与Ni2P/SiO2催化剂相比,在Ni2P/HZSM-5-M催化剂上形成了小颗粒的Ni2P活性相。同时,Ni2P/HZSM-5-M催化剂的活性具有良好的重复性。 相似文献