The performance of a venturi scrubber in the removal of tar from gas in updraft gasification has been studied. The gasifier has been operated with a husk feed rate of 1.6 × 10?4 kg/s. The venturi scrubber has been operated at a superficial gas velocity of 56.4 m/s at the throat. A wide variety of scrubbing liquids having surface tensions ranging from 0.026 to 0.072 N/m have been used. The Qg/Ql, has been varied in the range of 1000–8000. The tar separation efficiency η has been found to vary from 51 to 98.5%. A mathematical model, assuming steady-state operation, has been developed considering very high pseudosolubility of tar in the scrubbing liquids. The predicted values of η have been compared with experimental results. The model satisfactorily explains the tar removal efficiency of the venturi for Qg/Ql values ranging from 4000 to 8000 for all scrubbing liquids. The following correlation has been developed for predicting venturi scrubber efficiency: . 相似文献
SO2 and NO emitted from coal-fired power plants have caused serious air pollution in China. In this study, a test system for NO oxidation using O3 is established. The basic characteristics of NO oxidation and products forms are studied. A separate test system for the combined removal of SO2 and NOx is also established, and the absorption characteristics of NOx are studied. The characteristics of NO oxidation and NOx absorption were verified in a 35 t·h-1 industrial boiler wet combined desulfurization and denitrification project. The operating economy of ozone oxidation wet denitrification technology is analyzed. The results show that O3 has a high rate and strong selectivity for NO oxidation. When O3 is insufficient, the primary oxidation product is NO2. When O3 is present in excess, NO2 continues to get oxidized to N2O5 or NO3. The removal efficiency of NO2 in alkaline absorption system is low (only about 15%). NOx removal efficiency can be improved by oxidizing NOx to N2O5 or NO3 by increasing ozone ratio. When the molar ratio of O3/NO is 1.77, the NOx removal efficiency reaches 90.3%, while the operating cost of removing NOx per kilogram is 6.06 USD (NO2). 相似文献
A wet air oxidation reaction was carried out in a gas/liquid catalytic membrane reactor of the contactor type. The oxidation of formic acid was used as a model reaction. The mesoporous top-layer of a ceramic tubular membrane was used as catalyst (Pt) support, and was placed at the interface of the gas (air) and liquid (HCOOH solution) phases.
A similar reaction was carried out in a conventional batch reactor, using a steering rate high enough to avoid gas-diffusion limitations, and exactly identical conditions than for the CMR (amount of catalyst, pressure, etc.). At room temperature, the CMR showed an initial activity three to six times higher than the conventional reactor. This activity increase was attributed to an easier oxygen access to the catalytic sites. Nevertheless, the catalytic membrane gradually deactivated after a few hours of operation. Different deactivation mechanisms are presented. 相似文献
Pd catalysts supported on TiO2, ZrO2, ZSM-5, MCM-41 and activated carbon were used in catalytic wet oxidation of hydrocarbons such as phenol, m-cresol and m-xylene.
It was found that the Pd/TiO2 catalyst was highly effective in the wet oxidation of hydrocarbon. The activities of catalysts with various hydrocarbon species,
catalyst support, oxidation state of catalyst performed in a 3-phase slurry reactor show that reaction on Pd surface is more
favorable than that in aqueous phase and that the active site is oxidized Pd in catalytic wet air oxidation of hydrocarbons.
Based on the experimental results, a plausible reaction mechanism of wet oxidation of hydrocarbons catalyzed over Pd/TiO2 catalyst was proposed. This catalyst is superior to other oxide catalysts because it suppressed the formation of hardly-degradable
organic intermediates and polymer. 相似文献
Acrylic acid is a refractory compound for the non-catalytic wet oxidation (WO) process and can seriously damage the environment when released in industrial effluents. Oxidation of acrylic acid by catalytic wet oxidation (CWO) was studied in slurry conditions in a high-pressure batch reactor at 200 °C and 15 bar of oxygen partial pressure. Several solid cerium-based catalysts prepared in our laboratory were used (Ag/Ce, Co/Ce, Mn/Ce, CeO, MnO) and evaluated in terms of activity, selectivity and stability. Mn/Ce shows the higher activity in 2 h with 97.7% reduction of total organic carbon (TOC) followed by: MnO(95.5%)>Ag/Ce(85.0%)>Co/Ce(65.1%)>CeO(61.2%). Attempts were also carried out to analyze the influence of different Mn/Ce molar ratios. High percentages of Mn lead to practically total organic carbon concentration (TOC) abatements while low ratios lead to the formation of non-oxidizable compounds. Acrylic acid was readily degraded by all the catalysts pointing out the high importance of using a catalytic process. pH was an indicator of the reaction pathway and acetic acid was found as the major reaction intermediate compound; however it is completely oxidized after 2 h with exception for Co/Ce, CeO and MnO. Carbon adsorption and leaching of metals were poorly found for Mn/Ce indicating high stability. The catalyst microstructure after the reaction was analyzed and formation of whiskers of β-MnO2 (or less probably MnOOH) were observed at the catalyst surface. Therefore, Mn/Ce revealed to be a promising catalyst for the treatment of effluents containing acrylic acid; nevertheless, its commercialization depends on further research. 相似文献