Cd-ZSM-5沸石催化剂的制备、表征和芳构化催化性能

采用离子交换、浸渍和混合三种方法制备镉改性ZSM-5沸石催化剂,考察了改性方法和镉含量对催化剂的表面酸性和Cd状态以及芳构化性能的影响。结果表明,加入镉降低了B酸性,Cd~(2+)与沸石结合形成了L_(1612)酸中心,其生成量取决于改性方法和Cd含量,并与芳构化活性提高有直接关系。     

广东核电站ATWS事故分析研究

针对广东核电站给出了具有包络意义的三类ＡＴＷＳ分析结果，它们是：失去主给水ＡＴＷＳ（ＬＯＦＷ－ＡＴＷＳ）、失去非应急交流电源ＡＴＷＳ（ＬＯＮＥＰ－ＡＴＷＳ）、控制棒失控提升ＡＴＷＳ（ＵＣＲＷ－ＡＴＷＳ），并与广东最终安全分析报告所提供的ＡＴＷＳ分析做了比较，最后对其中后果较为严重的ＬＯＦＷ－ＡＴＷＳ作了部分参数的敏感性分析，并对低于３０％功率下的ＬＯＦＷ－ＡＴＷＳ作了讨论。     

Critical-point drying versus freeze drying for scanning electron microscopy: a quantitative and qualitative study on isolated hepatocytes

Critical-point drying and freeze drying were compared both quantitatively and qualitatively as preparative procedures for scanning electron microscopy. Isolated hepatocytes were used as model cells. Nomarski differential interference contrast microscopy was used for light microscopic measurements of the hepatocytes in the unfixed, the glutaraldehyde fixed, the glutaraldehyde + OsO₄ fixed, the critical-point dried and the freeze dried states. Critical-point dried hepatocytes were found to shrink to 38% of glutaraldehyde + OsO₄ fixed volume, whereas optimal freeze dried hepatocytes (frozen in water saturated with chloroform and freeze dried at 183 K for 84 h) were found to shrink to 51% of glutaraldehyde + OsO₄ fixed volume. Transmission and scanning electron micrographs of the critical-point dried cells showed well-preserved ultrastructure and surface structure. Micrographs of the freeze dried cells showed ultrastructure destroyed by internal ice crystals and surface structure destroyed by external ice crystals. Double-fixed isolated hepatocytes were shown to swell during storage in buffer and to shrink during storage after critical-point drying. For low magnification scanning electron microscopy (up to about 3000 times) both critical-point drying and freeze drying can be used. However, for high magnification scanning electron microscopy, critical-point drying is superior to freeze drying.     

渣油中硫化物类型分布与化学转化性能

用X射线光电子能谱（XPS）定量研究了Athabasca渣油及其加氢裂化渣油，流化焦化渣油中的硫化物类型，用超临界流体萃取分馏将3种渣油分别分离成9－14个窄馏分及残渣，测定其中的硫醚，噻吩，亚砜和砜类硫原子的分布，讨论了加氢裂化和热裂化反应脱除硫化物的反应性能。     

Novel application of radiotracer techniques for corrosion studies of zinc and aluminium in acidic medium

The adsorption of sulphate ions on Zn and Al was studied in 0.5 M NaClO₄ supporting electrolyte at various pH values in the range of pH=2-7 by radiotracer techniques. It was found in both cases that the adsorption of sulphate passes over maximum in the pH range studied.The phenomena observed are interpreted by the assumption that the main component of the overall process is anion adsorption on the protonated oxides/hydroxides formed as a result of corrosion. At low pH values the steady state coverage with respect to these products should be very low owing to their dissolution; consequently the extent of anion adsorption induced must also be very low. At higher pH values where no protonation occurs the adsorption of anions decreases significantly.     

松辽流域水利规划及战略研究总体思路

在总结水利规划工作经验教训的基础上,结合松辽流域现在水利工作实际,进行了水利规划及战略研究工作,提出切实可行的解决途径,并着重阐述了松辽流域水利规划和战略研究的总体思路.     

企业滋生腐败与防范中的问题研究

分析了产生腐败的内在因素和外在环境;提出了企业在反腐败工作中存在的自律方面的问题、权利作用问题和监督部门的设置问题,并提出建立“分离分立不分家,制约制衡不掣肘”的防范机制。     

跋山水库抛石挤淤压重的试验研究

通过对水库坝前沉积的淤泥进行详细的试验分析,摸清淤泥的物理性质、状态指标,找出一条适宜的施工工艺,进行淤泥清淤,既能保证工程质量,又能加快进度,节省投资,为山区丘陵地区的水库加固提供新的经验。     

对国际岩石力学委员会J_V公式的质疑

通过对国际岩石力学委员会JV 公式的论证 ,指出了该公式不符合数理逻辑。结合工程勘察实践 ,拟建了Ky新公式 ,提高了工程岩体完整程度评价方法的科学性。     

钢纤维喷射混凝土作为面板材料的可行性研究

钢纤维混凝土作为一种新型增强材料，以其较好的受力变形特性在水利水电，交通，海岸防护，港口及军事等诸多工程中得到了广泛的应用。针对混凝土面板堆石坝面板的受力变形特点，为改善水布垭面板堆石坝面板的受力条件，提高其防渗能力，同时方便施工，现提出采用钢纤维喷射混凝土作为水布垭面板堆石坝面板材料的新构想，并通过对钢纤维喷射混凝土的物理力学特性及堆石坝面板受力变形进行分析，为钢纤维喷射混凝土在水布垭面板堆石坝面板中的实际应用提出了建议方案。