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101.
Nayereh Soltani Elias Saion Mohd Zobir Hussein Maryam Erfani Alam Abedini Ghazaleh Bahmanrokh Manizheh Navasery Parisa Vaziri 《International journal of molecular sciences》2012,13(10):12242-12258
ZnS and CdS nanoparticles were prepared by a simple microwave irradiation method under mild conditions. The obtained nanoparticles were characterized by XRD, TEM and EDX. The results indicated that high purity of nanosized ZnS and CdS was successfully obtained with cubic and hexagonal crystalline structures, respectively. The band gap energies of ZnS and CdS nanoparticles were estimated using UV-visible absorption spectra to be about 4.22 and 2.64 eV, respectively. Photocatalytic degradation of methylene blue was carried out using physical mixtures of ZnS and CdS nanoparticles under a 500-W halogen lamp of visible light irradiation. The residual concentration of methylene blue solution was monitored using UV-visible absorption spectrometry. From the study of the variation in composition of ZnS:CdS, a composition of 1:4 (by weight) was found to be very efficient for degradation of methylene blue. In this case the degradation efficiency of the photocatalyst nanoparticles after 6 h irradiation time was about 73% with a reaction rate of 3.61 × 10−3 min−1. Higher degradation efficiency and reaction rate were achieved by increasing the amount of photocatalyst and initial pH of the solution. 相似文献
102.
103.
《分离科学与技术》2012,47(8):1675-1703
Abstract A mass balance model of total soluble sulfide and free zinc with a second-order reaction term is theoretically able to reconstruct the zinc effluent concentration and the kinetic parameter (k). However, under real conditions this model predicts the zinc effluent concentration four orders of magnitude higher than the measured ones. The applied error analysis, based on linearization of the model followed by first-order variance propagation, showed that the accuracy of several of the input variables (flows and influent concentrations) jeopardized the estimation of the Zn concentration in the effluent, which is a phenomenon expected for every fast reaction with low product concentration. In order to overcome the inaccuracy issue, an “apparent solubility product” as a function of pS (11-20) was calculated from the experimental data, allowing for the subsequent determination of an “apparent kinetic parameter” (k A ), that excluding parallel reactions was between 1.7 × 1023 – 6.2 × 1024 L/(mol·h). This allowed for further tuning of the model such that the estimates of the Zn effluent concentration became of the same order of magnitude as the measured ones (10?7 M Zn). 相似文献
104.
105.
Biocompatible chitosan-coated ZnS quantum dots [CS-ZnS QDs] and chitosan-coated ZnS:Mn2+ quantum dots [CS-ZnS:Mn2+ QDs] were successfully fabricated via a convenient one-step γ-radiation route. The as-obtained QDs were around 5 nm in diameter with excellent water-solubility. These QDs emitting strong visible blue or orange light under UV excitation were successfully used as labels for PANC-1 cells. The cell experiments revealed that CS-ZnS and CS-ZnS:Mn2+ QDs showed low cytotoxicity and good biocompatibility, which offered possibilities for further biomedical applications. Moreover, this convenient synthesis strategy could be extended to fabricate other nanoparticles coated with chitosan.PACS: 81.07.Ta; 78.67.Hc; 82.35.Np; 87.85.Rs. 相似文献
106.
采用CTAB辅助溶剂热法合成出花簇状结构的ZnS:Mn微球,并研究了反应温度,时间,溶剂,CTAB用量对样品形貌的影响.结果表明在170℃时加入0.8g CTAB溶剂热反应12h,所获得样品形貌规整,尺寸较均一;此外在反应体系中加入油酸获得尺寸更小的花簇状ZnS:Mn.并对花簇状结构的生长机制进行了阐述. 相似文献
107.
Dong Hyeop Shin Ji Hye Kim Young Min Shin Kyung Hoon Yoon Essam A. Al‐Ammar Byung Tae Ahn 《Progress in Photovoltaics: Research and Applications》2013,21(2):217-225
ZnS is a candidate to replace CdS as the buffer layer in Cu(In,Ga)Se2 (CIGS) solar cells for Cd‐free commercial product. However, the resistance of ZnS is too large, and the photoconductivity is too small. Therefore, the thickness of the ZnS should be as thin as possible. However, a CIGS solar cell with a very thin ZnS buffer layer is vulnerable to the sputtering power of the ZnO : Al window layer deposition because of plasma damage. To improve the efficiency of CIGS solar cells with a chemical‐bath‐deposited ZnS buffer layer, the effect of the plasma damage by the sputter deposition of the ZnO : Al window layer should be understood. We have found that the efficiency of a CIGS solar cell consistently decreases with an increase in the sputtering power for the ZnO : Al window layer deposition onto the ZnS buffer layer because of plasma damage. To protect the ZnS/CIGS interface, a bilayer ZnO : Al film was developed. It consists of a 50‐nm‐thick ZnO : Al plasma protection layer deposited at a sputtering power of 50 W and a 100‐nm‐thick ZnO : Al conducting layer deposited at a sputtering power of 200 W. The introduction of a 50‐nm‐thick ZnO : Al layer deposited at 50 W prevented plasma damage by sputtering, resulting in a high open‐circuit voltage, a large fill factor, and shunt resistance. The ZnS/CIGS solar cell with the bilayer ZnO : Al film yielded a cell efficiency of 14.68%. Therefore, the application of bilayer ZnO : Al film to the window layer is suitable for CIGS solar cells with a ZnS buffer layer. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
108.
沉淀法制备ZnS∶Cr纳米晶及其光学性能研究 总被引:1,自引:0,他引:1
以十二烷基苯磺酸钠和六偏磷酸钠作为分散剂,采用沉淀法制备了ZnS及不同掺杂浓度的ZnS∶Cr纳米晶。利用XRD和TEM对纳米晶物相和形貌进行了分析。结果表明,ZnS和ZnS∶Cr纳米晶均为立方闪锌矿结构,利用谢乐公式估算ZnS和ZnS∶Cr纳米晶平均粒径分别为2.1和2.2nm。TEM观察到纳米晶近似为球形,平均粒度为3nm左右,具有较好的单分散性且分布均匀。荧光光谱(PL)表明,纳米晶在420、440和495nm处有发射谱带,前两者被认为是S空位深陷阱发光,后者被认为是表面态或中心辐射复合发光。 相似文献
109.
以醋酸锌和硫脲为原料,采用溶剂热法分别以有机小分子的一元胺(甲胺、乙胺、正丁胺)和多元胺(乙胺、二乙胺、三乙胺)为介质合成ZnS纳米粉体,通过XRD和SEM对所得ZnS粉体进行了表征,研究了不同介质对所得ZnS粉体的晶相组成、颗粒尺寸及形貌的影响.结果表明,在单胺体系中,随着碳链的增长,ZnS粉体六方相的生长趋势渐弱;在伯仲叔胺中,随着与氨基相连的碳原子上氢原子的减少,六方相的生长趋势渐弱,在三乙胺中甚至出现了立方ZnS的特征峰.荧光光谱的研究表明,从伯胺到叔胺,其发射峰发生少量的红移,从乙胺溶液中的450nm附近红移到三乙胺溶液中的500nm附近. 相似文献
110.
The aim of this study is to reveal the underlying cause of the gradual turn-on characteristic of low Te containing ZnSTe Schottky
barrier photodiodes. The results of photoresponse studies on ZnS, ZnSSe and ZnSTe diodes indicate that the Te isoelectronic
trapping effect is responsible for the gradual turn-on characteristic of low Te containing ZnSTe Schottky barrier photodiodes.
The results also reveal that the ZnSSe diode, having the advantage of being free of isoelectronic centers, is a more suitable
choice for applications requiring high visible rejection power. It is demonstrated that highly UV sensitive responsivity with
an abrupt long wavelength cutoff tailored to lie between 340–400 nm can be achieved in the ZnSSe diode system. 相似文献