SISAK快速化学分离装置的建立

SISAK(Short-lived Isotopes Studies by the AKUFVE technique)技术是目前使用最广泛的快速化学分离方法之一,主要应用在短寿命核素的分离和鉴别、超重元素的人工合成以及化学性质研究等方面的工作中.本文简单地叙述了SISAK技术的流程、原理和发展现状,介绍了自行建立的国内第一套基于SISAK技术的快速化学分离装置,并通过从裂变产物中分离短寿命核素这一实例验证了SISAK技术在快速化学分离中的优越性.     

溶剂对溶胶-凝胶法制备LaMnFe2Al9O19催化剂的影响

摘要 用溶胶凝胶法制备六铝酸盐催化剂LaMnFe2Al9O19，通过BET、XPS、XRD等技术，对催化剂的结构和性质进行了研究，主要考察了在制备过程中不同的醇做溶剂对催化剂结构及其甲烷催化燃烧活性的影响。结果表明：不同醇做溶剂所制备的催化剂LaMnFe2Al9O19 在1200℃焙烧后都可以形成完整的六铝酸盐晶型，且具有较高高温稳定性。同时对于催化剂的的催化性能也有较大的影响，用异丙醇做溶剂所得催化剂的催化活性最高，并保持了较大的比表面积。     

GC/MS characterization of mate tea leaves extracts obtained from high-pressure CO2 extraction

This work presents a study concerning the chemical characteristics and analytical separation process of the essential oil obtained from high-pressure carbon dioxide extraction of Ilex paraguariensis. The experiments were performed in a laboratory-scale unit in the temperature range of 20–40 °C, from 100 to 250 bar. A blend of the I. paraguariensis extracts was percolated through a preparative chromatographic column, containing silica gel, and successively eluted with 150 mL of each of the following solvents: hexane, toluene, dichloromethane, ethyl acetate, acetone and methanol. The raw extract and its fractions were analyzed by gas chromatography coupled to mass spectrometry detection (GC/MS). The fractionation procedure showed to be a good clean up technique due to the isolation of different classes of compounds in each fraction. Chromatographic analyses allowed the identification of caffeine, fatty acids and esters, phytol, squalene, Vitamin E, stigmasterol derivatives and saturated hydrocarbons.     

溶剂萃取分离锂同位素研究Ⅱ.苏丹Ⅰ-中性配位体协萃体系萃取分离锂同位素效应探讨

文章讨论了苏丹I-中性配位体协萃体系萃取分离锂同位素中螯合剂和协萃剂的结构效应。为了获得高的同位素分离效应,螯合剂必须是弱酸性的(PK_α>11),具有强的分子内氢键及易于形成六元螯合环。协萃剂结构不仅要求无空间位阻,而且具有强的配位基。α随配位基的碱性增大而相应提高。萃取络合物中螯合环的增多亦有利于体系α的提高。此外本文还讨论了一些萃取体系的同位素富集方向和萃锂体系用于分离同位素的前景。     

Optimal Locations of Groundwater Extractions in Coastal Aquifers

A regional water supply management model for coastal aquifers was developed. One of its outcomes is the definition of the optimized locations for groundwater withdrawal. Such a tool permits the analysis of alternative plans for groundwater extraction and the sustainable use of water resources in a coastal aquifer subject to saltwater intrusion. The principal components are the evolutionary optimization and the analytical/numerical simulation models. The optimization technique looks for the best well locations taking into consideration the economic results and the satisfaction of the societal water demand. However these two concerns are conditioned by trying to control the saltwater intrusion, i.e., preserving the environmental equilibrium. The simulation model uses the governing mathematical equations for groundwater movement to find the interface between freshwater and saltwater. Because of the non-linearity in the system and the possibility of a jumping interface, a security distance was defined. This is a controlling variable which can be set by the decision makers. The model was applied to a typical case with interesting results. For example, diagrams showing the relationship between the location of the wells and the security distance(s) are of importance to the managers. It was also crucial to have an understanding of the tradeoffs between groundwater withdrawals, positions of the wells from the coast line, and the security distance. The model was also applied to a real case in order to relate the extractions, distances and artificial recharge (not presented in this paper).     

Two-tier architecture for unconstrained handwritten character recognition

In this paper, we propose an approach that combines the unsupervised and supervised learning techniques for unconstrained handwritten numeral recognition. This approach uses the Kohonen self-organizing neural network for data classification in the first stage and the learning vector quantization (LVQ) model in the second stage to improve classification accuracy. The combined architecture performs better than the Kohonen self-organizing map alone. In the proposed approach, the collection of centroids at different phases of training plays a vital role in the performance of the recognition system. Four experiments have been conducted and experimental results show that the collection of centroids in the middle of the training gives high performance in terms of speed and accuracy. The systems developed also resolve the confusion between handwritten numerals.     

铜萃取剂BK992和LIX984的性能研究

研究羟肟类铜萃取剂的结构与性能的关系。试验研究了铜萃取剂BK992和LIX984的对比萃取及混合萃取性能指标 ,试验表明BK992与LIX984的使用性能相当 ,两种铜萃取剂相互混合不影响使用性能指标。     

检测骨架图形特征点的新方法

端点、折点、歧点和交点是骨架图形的重要特点是，提出用快速查表法检测侯选特征点，再进行侯选特征点聚集，用局部结构分析，去除假特征点，判别真特征点的类型，并对折点给以大致的定量描述。实验结果表明，该方法能快速有效地找出骨架图形的特征点，在目标识别、字符识别等应用中起着关键作用。     

从催化裂化柴油中分离高纯度2,6-二甲基萘

以大庆石油化工总厂炼油厂催化柴油为原料 ,通过精馏分离得到二甲基萘 (DMN)窄馏分 (2 5 8～ 2 70℃ ) ,经糠醛溶剂抽提 ,减压蒸馏后 ,在 -10～ -2 5℃冷冻 2～ 5h ,离心分离制得纯度约 80 %的粗 2 ,6 DMN ,再经无水乙醇在 -10～ -2 5℃重结晶 ,得到纯度大于等于 98%的 2 ,6 DMN。     

Facile optical resolution of amino acid esters via hydrolysis by an industrial enzyme in organic solvents

Racemic amino acid esters were optically resolved via hydrolysis in organic solvents by the catalysis of an industrial alkaline protease, “Alcalase”. The products which were composed mainly of L-amino acids were insoluble and easily separated by filtration. The activity of the enzyme and enantiomeric excess of the products were significantly dependent on the nature of solvent and the water content in the reaction media. Generally, high values of enantiomeric excess were obtained at low water contents. Many natural and unnatural amino acids were resolved by this method.