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21.
从测得的竞聚率计算了单体链节在聚[苯乙烯-甲基丙烯酸β(甲基亚硫酰基)乙酯](PSM)中的序列分布。苯乙烯(S)或甲基丙烯酸β(甲基亚硫酰基)乙酯(M)的长序列的概率随着PSM中相应单体含量的增加而增加。对于S和M摩尔分数大致相等的PSM,单体链节的长序列分布函数值相接近。用与此结构相近的PSM合成的稀土金属络合物,其催化活性不佳。在M短序列分布和S长序列分布较高的情况下,络合物的催化活性最好。所得聚丁二烯的微观结构与PSM中单体单元的分布无关。 相似文献
22.
23.
叙述了运用磁性法或超声法对核电和化工容器中不锈钢及镍基堆焊层厚度进行测量的原理、方法及主要影响因素 ,比较了这两种方法的测量结果 相似文献
24.
Electroinitiated cationic copolymerisation of indene and styrene was investigated by constant potential electrolysis. Effects of copolymerisation potential and temperature on the copolymer composition and the reactivity ratios are discussed. The reactivity ratios of the monomers were calculated according to the integrated Lewis-Mayo equation. 相似文献
25.
A new and efficient method for preparation of optically active poly(styrene–divinylbenzene) copolymers (PS-DVB) is presented here. This is carried out by Friedel–Crafts acylation reaction of chiral N-phthaloyl
-leucine acid chloride with PS-DVB beads in the presence of aluminum chloride as Lewis acid catalyst and 1,2-dichloroethane as the solvent at ambient temperature. Reagents’ amounts and reaction conditions are mentioned and four samples with different amounts of functionality have been prepared. Final products were characterized by FT-IR and elemental analysis. The results obtained confirm that the above modification in preparation of chiral supported PS-DVB has been achieved well and in moderate yield. 相似文献
26.
通过比较电镀硬铬和化学镀镍在液压支柱表面处理上的应用 ,探讨了化学镀镍在配方、工艺、设备、镀层性能、环保等方面的优越性。 相似文献
27.
循环风与瓦斯浓度的关系 总被引:1,自引:0,他引:1
通过循环风时对瓦斯污染数学模型的建立 ,详细阐述了在各种情况下 ,瓦斯浓度的变化情况及治理措施。 相似文献
28.
A new class of bifunctional periodic mesoporous organosilicas (PMOs) composed of organosilicate building blocks with two different silicon sites have been synthesized from the single‐source bifunctional organosilica precursors tris(triethoxysilylethyl)ethoxysilane and bis(triethoxysilylethyl)diethoxysilane, respectively denoted MT3‐PMO and DT2‐PMO. The synthesis of these PMOs is achieved by the co‐assembly of a triblock‐copolymer Pluronic P123 template with the bifunctional organosilica precursor under acid‐catalyzed and inorganic‐salt‐assisted conditions. After template removal through solvent extraction, the MT3‐PMO and DT2‐PMO so obtained show well‐ordered mesopores and display large pore diameters (6–7 nm) and pore volumes (0.6–0.8 cm3 g–1) with a narrow pore‐size distribution and high surface areas (700–800 m3 g–1). 相似文献
29.
The bulk copolymerization of styrene–acrylonitrile monomers using styrene‐N+–montmorillonite complex as a comonomer in the polymerization was studied. The X‐ray diffraction (XRD) analysis showed that part of the styrene‐N+–montmorillonite complex remained non‐dispersed (immiscible) and the copolymer was excluded from the interlayer of the immiscible part of the clay. The successive chemical extraction process revealed that a reasonable amount of the styrene–acrylonitrile copolymer was directly attached to the styrene‐N+–montmorillonite complex and enveloped the clay. Highly exfoliated clay lamella and nanospheres (3–5 nm) were observed by transmission electron microscopy (TEM). The montmorillonite clay assume two different morphologies, immiscible and exfoliated, on the basis of the XRD and TEM data. A simple method of calculation of the ratio of the exfoliated/immiscible amounts of the clay indicated that the amount of the styrene‐N+–montmorillonite complex exfoliated into separate lamella was 40 % (w/w) of the amount of the clay samples containing 2 % of the (styrene‐N+–montmorillonite complex) clay. This amount of exfoliated clay decreases with the increase of the concentration of the clay. The presence of the styrene‐N+–montmorillonite clay in the copolymerization reaction had a minor effect on both the copolymer composition and the molecular weight. Modification of the clay with the derivatized styrene monomer can achieve a nanocomposite using a percentage no more than 4 % (w/w) of complex in the copolymer. Copyright © 2004 Society of Chemical Industry 相似文献
30.
Biodegradable multiblock poloxamers (BMPs) with gel duration of 8 h to several weeks were prepared by varying their molecular weights from 4000 to 40 000 g mol?1. The molecular weight of the BMP was controlled by changing the poloxamer to coupling agent ratio. Assuming a micelle packing model of the BMP gel, as in the case of a poloxamer gel, the micelle properties and critical gel concentration of BMPs were investigated on the basis of the scaling concept. The findings suggest that the control of molecular weight by hydrolyzable groups can be a facile approach to optimize the gel properties for biomedical applications. Copyright © 2005 Society of Chemical Industry 相似文献