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951.
银的形貌、银表面的润滑剂、树脂基体的成分、固化过程等都会影响导电胶的性能。其中,银的形貌是一个关键的因素。论文研究了在相同条件不同形貌的银对导电胶性能的影响。将银片、银球和银线用戊二酸处理以消除其他因素的影响,然后这些银粒子被用作导电填料与环氧树脂混合制备导电胶。研究了不同形貌银粉制备的导电胶热降解性能、导电性能、机械性能及贮存稳定性。结果表明在相同条件下银线制备的导电胶具有最低电阻率和渗流阈值、最好的机械性能、以及较好的贮存稳定性,银片制备的导电胶导电性能和贮存稳定性比用银球制备的导电胶好,但机械性能比用银球制备的导电胶差。 相似文献
952.
Polymer-Solid Interface Connectivity and Adhesion: Design of a Bio-Based Pressure Sensitive Adhesive
Adhesion at polymer-solid interfaces was explored for a new bio-based pressure sensitive adhesive (PSA) in terms of sticker groups, φX, on the polymer phase, receptor groups, φY, on the solid surface, and the bond strength of the sticker-receptor X-Y acid-base interaction, χ. The polymer-solid interface restructuring models of Gong and Lee et al. were extended with new percolation models of entanglements and interface strength to determine the optimal sticker group concentration, φ?X. For the general case where φY and χ are constant, it is predicted that when φX < φ?X, that the critical peel energy behaves as G1c ~ φX/φ?X and the locus of failure is adhesive between the polymer and the solid. However, when φX > φ?X, failure occurs cohesively in a polymer-polymer interface adjacent to the solid and the strength decreases as G1c ~ φ?X/φX. The switch from adhesive to cohesive failure can be understood in terms of the changes in the chain conformations of the adhered chains and their decreasing interpenetration, Xi, with the bulk chains, via Xi ~ 1/r, where r = χφXφY. The optimal value of φX which maximizes the adhesion and determines the mode of failure is given by φ?X ≈ 0.129/C∝, and for typical values of the characteristic ratio C∝ in the range 7–20, φ?X ≈ 1% mole fraction, corresponding to about 2 sticker groups per entanglement molecular weight, Me. This result was verified for a bio-based PSA synthesized from an acrylated high oleic fatty acid, which was copolymerized with maleic anhydride as the sticker group. The observed behavior is counterintuitive to the current wisdom for the effect of acid-based interactions on adhesion, where the strength is expected to increase with the number of X-Y contacts. The surprisingly low value of φ?X ≈ 1% sticker groups which maximizes the adhesion strength can now be readily calculated using the percolation model of entanglements and fracture. 相似文献
953.
Guohua Li Yanmei Yao Qingxin Zhang Nongyue Wang 《Journal of Adhesion Science and Technology》2013,27(13):1441-1453
Latex particles with the same core composition of poly(MMA-co-ALMA) and different shell compositions of poly(BA-co-AA) were prepared by semibatch emulsion polymerization using ‘power feed’ monomer and chain transfer agent addition methods in the shell layers. The seed stage involved formation of seed particles of 111 nm in diameter with a batch process. After that, two growth stages formed the final particle diameter, dz = 300 nm measured by dynamic light scattering. The gel content and the molecular parameters of the polymer were determined. The adhesive properties including loop tack, peel force and shear resistance were measured according to the FINAT test methods No. 9, 1 and 8. An evaluation was also made for the relationship between pressure-sensitive properties and molecular parameters. Introducing power feed to semibatch emulsion polymerization had no significant effect on the latex preparations and could improve the final conversion and the colloidal stability. The observed particles were grown without significant secondary nucleation. The power feed methods had no effect on the glass transfer temperature (Tg) of the shell layer also. Emulsion polymerization conducted by positive power feed resulted in the formation of longer primary polymer chains at the beginning than that conducted by negative power feed and standard uniform feed, which caused a very high gel fraction. As pressure-sensitive adhesives prepared by using the positive power feed had the highest gel content and strongest core–shell interaction, they exhibited the highest shear resistance, but the lowest tack and peel force. 相似文献
954.
The effect of rubber blend ratio and testing rate on the adhesion properties of epoxidized natural rubber (ENR 25)/styrene–butadiene rubber (SBR) blend adhesive were studied using 40 parts per hundred parts of rubber (phr) of coumarone-indene resin as the tackifying resin. Toluene and poly(ethylene terephthalate) (PET) film were used as the solvent and substrate, respectively. A SHEEN hand coater was used to coat the adhesive on the PET substrate at 30, 60, 90, and 120 µm coating thickness. Viscosity was determined by a Brookfield viscometer whereas loop tack, peel strength, and shear strength were measured by a Llyod Adhesion Tester at various testing rates from 10 to 60 cm/min. Results show that viscosity increases gradually with % ENR 25. However, loop tack, peel strength, and shear strength of adhesives indicate a maximum value at 40% ENR 25, after which the adhesion properties decreases with further increase in % ENR 25. This observation is attributed to the varying degree of wettability which culminates at an optimum value of 40% ENR 25 blend ratio. In all cases, the adhesion properties increase with increasing coating thickness and rate of testing. 相似文献
955.
Physico‐chemical,thermal, and mechanical approaches for the characterization of solubilized and solid state chitosans
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Narimane Mati‐Baouche Hélène De Baynast Christophe Vial Fabrice Audonnet Shengnan Sun Emmanuel Petit Fabienne Pennec Vanessa Prevot Philippe Michaud 《应用聚合物科学杂志》2015,132(2)
This study was conducted on the both solid and solubilized chitosans to propose an approach for the physico‐chemical, thermal and mechanical characterizations of this polysaccharide. The polysaccharide used was a 90% deacetylated chitosan having a molecular weight of 98.4 kDa. The flow property of chitosan solutions was evaluated revealing a shear‐thinning behavior. The thermal characterization was carried out by studying heat specific capacity, glass transition temperature, and thermal conductivity on chitosan dried specimens (solid state). Their Tg were measured by DSC and confirmed by DMA at 102 and 122°C depending on concentrations of initial chitosan solutions. The mechanical characterization was conducted by analyzing Young modulus, tensile strength, and elongation at break of chitosan specimens. They exhibited a higher elongation at break and a lower tensile strength when made from high concentrated chitosan solution (9% w/v). Differences in mechanical behavior of specimens were explained by differences of crystallinity. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41257. 相似文献
956.
Oxirane Cleavage Kinetics of Epoxidized Soybean Oil by Water and UV‐Polymerized Resin Adhesion Properties
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Yonghui Li Donghai Wang Xiuzhi Susan Sun 《Journal of the American Oil Chemists' Society》2015,92(1):121-131
Di‐hydroxylated soybean oil (DSO), a biobased polyol synthesized from epoxidized soybean oil (ESO) could be used to formulate resins for adhesives; however, current DSO synthesis requires harsh reaction conditions that significantly increase both cost and waste generation. In this paper, we investigate the kinetics of oxirane cleavage in ESO to DSO by water and elucidate the role of different process parameters in the reaction rate and optimization of reaction conditions. Our kinetic study showed that ESO oxirane cleavage was a first‐order reaction and that the ESO oxirane cleavage rate was greatly influenced by tetrahydrofuran (THF)/ESO ratio, H2O/ESO ratio, catalyst content, and temperature. Optimized reaction parameters were THF/ESO of 0.5, H2O/ESO of 0.25, catalyst content of 1.5 %, and reaction time of 3 h at 25 °C. DSO with hydroxyl value of 242 mg KOH/g was obtained under these conditions. We also characterized the structure, thermal properties, adhesion performance, and viscoelasticity of UV‐polymerized resins based on this DSO. The resin tape exhibited peel adhesion strength of 3.6 N/in., which is comparable to some commercial tapes measured under similar conditions. 相似文献
957.
Liang Jiang Zhimeng Liu Kai Hu Weibo Kong 《Journal of Adhesion Science and Technology》2019,33(1):2-17
Acrylic latex laminating adhesives (ALLAs) were successfully prepared via a monomer-starved seeded semi-continuous emulsion polymerization with butyl acrylate (BA), methyl methacrylate (MMA), styrene (St), acrylamide (Am), and methacrylate glycidyl ether (GMA) as monomers. Impacts of GMA on the final latex, the dried latex films and the adhesive properties of ALLAs were investigated, respectively. The results indicated that the increase of GMA contents in the pre-emulsion feed has no apparent effect on the final latex average particle size and size distribution, while the gel contents, glass transition temperature (Tg) and water contact angle of the ALLAs gradually increased, and the molecular weight (Mn, Mw) obviously increased. Additionally, as the amount of GMA increased from 0 to 10?wt%, the maximum peel strength of the composite films reached 3.72 N/15mm with 5?wt% GMA contents. When heated to 65?°C, the peel strength of the composite films with 5?wt% of GMA can still maintain an acceptable peel strength (2.51 N/15mm) for application, showing excellent adhesive performance and heat resistance properties. 相似文献
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