激光熔敷合金层组织及腐蚀磨损特性研究

利用ＣＯ＿２连续激光器在４５钢表面进行了激光熔敷镍基合金、镍基Ｃｒ＿２Ｏ＿３合金和镍基ＷＣ合金，以２Ｃｒ１３不锈钢为对比材料，系统地研究了激光熔敷层在不同冲击速度和腐蚀介质浓度下的腐蚀磨损特性，并根据组织分析、显微硬度测试及腐蚀磨损后的表面形貌观察，探讨了激光熔敷层的腐蚀磨损过程。结果表明：激光熔敷层的腐蚀磨损性能均比２Ｃｒ１３不锈钢好。     

A comparative thermodynamic study of sorption systems: second law analysis

As a consequence of the phasing out of CFCs, sorption systems appear to be potential candidates to replace vapour compression systems. Amongst sorption systems there exists a choice between several systems, such as liquid absorption, solid adsorption and chemical reaction heat pumps. Nevertheless, few comparative studies between these systems have been undertaken so far. It is the aim of this paper to present such a study based on combined first and second law thermodynamical analysis of the different cycles. Simple entropy generation processes explain why the basic cycles for these systems yield performances much lower than the Carnot efficiency. The possibility of operating regenerative cycles with internal heat recovery and higher efficiencies has also been considered for typical common base conditions. Different entropy generation considerations have been visualised, such as thermal coupling (external/internal), non-uniform temperature component entropy production and other irreversible processes for the COP degradation in these systems. It is found that thermal coupling irreversibilities in solid sorption systems and other internal irreversibilities in liquid sorption systems with solution heat exchanger are dominant in the actual COP degradation with respect to the reversible Carnot COP.     

Sensitizing Mechanism and Adsorption Properties of Dye—Sensitized TiO2 Thin Films

The dye-sensitized TiO2 complex films were prepared by the dye coat onto TiO2 surfaces,and the sensitizing mechanism and adsorption properties of the dye-sensitized TiO2 complex films were inverstigated.The influence of the application conditions of dye adsorbed on TiO2 films on the amount of dye adsorption was discussed.Experimental results show that the concentration,the temperature of dye solutions and the dipping time of TiO2 films in the dye solutions have a significant influence on the amount of dye adsorption.Cell test indicates that the conversion efficiency of light to electricity increases with the amount of dye adsorption.     

含羧基的聚乙烯醇胺肟螯合纤维吸附钯的研究

研究了含羧基的聚乙烯醇胺肟（ＰＶＡＡＯ－ＡＡｃ）螯合纤维对钯的吸附，讨论了ｐＨ、温度、浓度、吸附时间对吸附率及回收率的影响。确定了最佳吸附条件，吸附钯的纤维用５％硫脲＋０．１０ｍｏｌ／Ｌ硝酸溶液可以解吸。     

吸附制冷循环的热力计算及热力学评价方法探讨

在化工吸附，吸附热力学及Polanyi吸附位势理论的基础上，介绍吸附制冷基本型循环，推演其参数坐标图，进而分析，给出其主要性能指标的热力计算，然后以热力学的逆卡诺循环和内可逆三热源循环模型为指针，对此制冷循环进行考察。并结合热力计算对其热力学完善性做出评价，从而给出了吸附制冷基本型循环合适的热力学评价方法。     

一类Boltzmann & Darwin混合寻优策略的收敛特性研究

基于文［１］提出的求解组合最优化问题的Ｂｏｌｔｚｍａｎｎ＆Ｄａｒｗｉｎ混合寻优策略，本文进一步分析研究了Ｂｏｌｔｚｍａｎｎ＆Ｄａｒｗｉｎ混合寻优策略非时齐情形下的收敛特性，包括全局收敛性和收敛速度。结果表明，Ｂｏｌｔｚｍａｎｎ＆Ｄａｒｗｉｎ混合寻优策略的收敛特性优于模拟退火（ｓｉｍ－ｕｌａｔｅｄ ａｎｎｅａｌｉｎｇ）方法的收敛特性。     

TNT-RDX混合废水处理的实验研究——生物-吸附法

介绍了在２５￣３５℃的温度下，用厌氧－兼氧－水生生物－吸附组合工艺处理ＴＮＴ和ＲＤＸ混合废水的方法，进行了日处理量为６０￣９００Ｌ的实验室放大实验。当ＴＮＴ和ＲＤＸ混合废水总浓度为４￣１２ｍｇ／Ｌ时，经过该工艺处理后可达到国家排放标准。其中厌氧－兼氧能去除废水中８０％以上的ＴＮＴ和ＲＤＸ，水生生物（水葫芦）对ＴＮＴ及ＲＤＸ也有一定的降解效果，最后用活性炭吸附可以实现深度处理。     

Alkali-metal Na Adsorption and Promoted Oxidation on Si(100)2×1 Surface

The alkali-metal Na adsorption on Si(100)2×1 surface and its promoted oxidation and Si oxidegrowth have been investigated by means of thermal desorption,work function,Auger electronspectroscopy and photoemission electron spectroscopy.The experimental data showed that therewas a new state,interface electron state,near the Fermi level after the deposition of Na atoms.It wasfound that the presence of Na always caused an increase of the oxygen initial uptake whereas thepromotion of Si oxide growth was observed only at the coverage of Na greater than 0.5 ML.A newmechanism of Na-promoted Si oxide growth is suggested in this paper.     

Use of TNSAC in phosphate adsorption studies and relationships. Isotherm relationships and utility in the field

There is a need for developing low cost, easily and abundantly available, yet efficient, adsorbents for the removal of phosphates during the tertiary treatment of wastewaters. The tamarind nut shell activated carbon (TNSAC) prepared on a laboratory scale has been used to evaluate its performance for phosphate adsorption. This paper describes the laboratory production of this adsorbent material in its various forms, and discusses the effects of the TNSAC process variables (the unrinsed and rinsed forms of the TNSAC and the impregnation ratio) on its performance in adsorbing phosphate. The material has been shown to be a good alternative adsorbent. As much as 95% phosphate removal by the unrinsed TNSAC is possible in about 30 min under the test conditions. The phosphate adsorbing capacity is about two times higher for the unrinsed TNSAC in comparison to the rinsed TNSAC. The adsorption rates, however, transit to extremely low rates towards the end when equilibrium conditions could be attained in about 2 h contact time. The phosphate removal mechanics are adsorption and precipitation/ion exchange when unrinsed TNSAC is used, and adsorption alone for the rinsed TNSAC. The maximum phosphate removal is found to take place at an impregnation ratio of 1.0 for both forms of the TNSAC.