全文获取类型
收费全文 | 336篇 |
免费 | 25篇 |
国内免费 | 15篇 |
专业分类
电工技术 | 3篇 |
综合类 | 22篇 |
化学工业 | 192篇 |
金属工艺 | 21篇 |
机械仪表 | 9篇 |
建筑科学 | 7篇 |
矿业工程 | 7篇 |
能源动力 | 6篇 |
轻工业 | 20篇 |
水利工程 | 4篇 |
石油天然气 | 11篇 |
武器工业 | 1篇 |
无线电 | 15篇 |
一般工业技术 | 44篇 |
冶金工业 | 8篇 |
原子能技术 | 5篇 |
自动化技术 | 1篇 |
出版年
2023年 | 5篇 |
2022年 | 5篇 |
2021年 | 10篇 |
2020年 | 7篇 |
2019年 | 7篇 |
2018年 | 9篇 |
2017年 | 5篇 |
2016年 | 10篇 |
2015年 | 11篇 |
2014年 | 8篇 |
2013年 | 19篇 |
2012年 | 16篇 |
2011年 | 13篇 |
2010年 | 19篇 |
2009年 | 9篇 |
2008年 | 13篇 |
2007年 | 23篇 |
2006年 | 18篇 |
2005年 | 14篇 |
2004年 | 17篇 |
2003年 | 21篇 |
2002年 | 16篇 |
2001年 | 9篇 |
2000年 | 12篇 |
1999年 | 6篇 |
1998年 | 13篇 |
1997年 | 4篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 11篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有376条查询结果,搜索用时 15 毫秒
1.
Peichun Li Amar Zerroukhi Jianding Chen Yvan Chalamet Thomas Jeanmaire Zhean Xia 《应用聚合物科学杂志》2008,110(6):3990-3998
Chemical shrinkage was used for the in situ measurement of the progressing chemical stabilization reactions and the influence of ozone during the stabilization of polyacrylonitrile. A method for evaluating the activation energy through the sensitivity temperature is presented. The calculated results show that the activation energies were 161.57 kJ/mol in air and 181.23 kJ/mol in ozone-enriched air. Therefore, the chemical reactions were postponed during stabilization in ozone-enriched air. Ozone seemed to act in three ways: first, ozone promoted the formation of the serious skin–core structure. Second, ozone accelerated the chemical reactions and shortened the stabilization time at lower heating rates. Third, ozone postponed the chemical reactions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
2.
用姐妹染色单体交换(SCE)作为指标,研究了~(60)Coγ射线辐照及NADH-PMS(吩嗪硫酸甲酯)系统中产生的超氧阴离子自由基(0_2~(·-))对胎儿脐血淋巴细胞染色体的损伤作用,及活性氧清除剂SOD和甘露醇的保护作用。结果显示γ射线及0_2~(·-)都能诱发细胞SCE频率显著升高,且存在一定的剂量-效应关系。SOD及甘露醇对0_2~(·-)诱发的损伤有明显的保护作用。 相似文献
3.
4.
论述了一种负离子面膜的研制过程。在面膜的制作过程中通过适当的途径加进负离子添加剂,从而使负离子在皮肤表面发挥还原性作用,使已经氧化的皮肤还原,恢复健康状态。通过多次实验,所得产品负离子释放量超过了700个/cm3,具有释放负离子稳定持久、发射远红外线、杀菌、消毒、保健等功效,达到了健康要求。 相似文献
5.
Polymerization of β-butyrolactone has been studied in toluene with Al(OiPr)3 as an initiator. The ring-opening polyaddition proceeds through a coordination–insertion mechanism at a very low rate. Well defined α-isopropylester, ω-hydroxy poly(β-butyrolactone)s (PBL) are formed with a narrow molecular weight distribution at low monomer-to-initiator molar ratios, When this ratio is higher (ca. 170), a competition occurs between propagation and side reactions, i.e. elimination, inter- and intra-molecular transesterifications and thermal degradation, which is responsible for a loss of control of the PBL molecular charcteristics. The addition of a Lewis base (1 equivalent of nicotine/Al) to the Al-alkoxide initiator has no significant effect on the polymerization rate, although the chain microstructure is deeply affected since predominantly syndiotactic PBL chains are formed (63% syndio-diads) in contrast to a completely atactic polymer in the absence of nicotine. 相似文献
6.
Monodispersed spherical β-SiC powder was synthesized by heating spherical gel powder derived from the hydrolysis of a mixture of phenyltriethoxysilane and tetraethyl orthosilicate. The solution was prepared in a beaker and hydrolyzed by NH4 OH without stirring. The monodispersed spherical gel powder of submicrometer size was obtained when the added amount of NH4 OH was greater than 16 moles per mole of silane plus alkoxide, and it became monodispersed spherical β-SiC powder by heat-treating at 1500°C for 4 h in an Ar atmosphere. The SiC content of the powder was 92.6 wt%. 相似文献
7.
以环烷氧锡化合物引发L-丙交酯开环聚合制备高分子量聚L-乳酸。考察了单体引发剂配比、聚合温度和聚合时间等聚合条件对聚合产物特性黏度的影响。用1H-NMR、13C-NMR分析聚合产物微观结构表明,环烷氧锡引发L-丙交酯开环聚合是基于酰氧键断裂开环聚合的“配位-插入”机理。DSC、TGA、XRD等测试结果表明,所得聚L-乳酸具有较高的结晶度和立构规整度。 相似文献
8.
Influence of Some Hofmeister Anions on the Krafft Temperature and Micelle Formation of Cetylpyridinium Bromide in Aqueous Solution 下载免费PDF全文
Md. Nazrul Islam Khokan Chandra Sarker Komol Kanta Sharker 《Journal of surfactants and detergents》2015,18(1):9-16
In this work, the effect of some Hofmeister anions on the Krafft temperature (TK) and micelle formation of cetylpyridinium bromide (CPB) have been studied. The results show that more chaotropic anions increase, while the less chaotropic ones lower the TK of the surfactant. More chaotropic I? and SCN? form contact ion pairs with the cetylpyridinium ion and reduce the electrostatic repulsion between the CPB molecules. As a result, these ions show salting‐out behavior, with a consequent increase in the TK. In contrast, less chaotropic Cl? and NO3? increase the activity of free water molecules and enhance hydration of CPB molecules, showing a decrease in the TK. A rather unusual behavior was observed in the case of SO42? and F?. These strong kosmotropes shift from their usual position in the Hofmeister series and behave like moderate chaotropes, lowering the TK of the surfactant. Because of the high charge density and the strong tendency for hydration these ions preferentially remain in the bulk. Rather than forming contact ion pairs, these ions stay away from the CPB molecules, decreasing the TK of the surfactant. In term of decreasing the TK, the ions follow the order NO3? > SO42? > Cl? > F? > Br? > SCN? > I?. The critical micelle concentration (CMC) of the surfactant decreases significantly in the presence of these ions due to the screening of the micelle surface charge by the excess counterions. The decreasing trend of the CMC in the presence of the salts follows the order SCN? > I? > SO42? > NO3? > Br? > Cl? > F?. 相似文献
9.
10.
醇镁还原法一步制取对氯苯胺是一种新的方法 ,研究发现最佳反应温度为 80℃~ 85℃ ,反应时间为4h ,对氯硝基苯与镁粉的用量 (物质的量比 )为 1∶3,产率为 80 %。 相似文献