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41.
The effects of different inorganic and organic counterions on the physicochemical behavior of three commercial linear alkylbenzene
sulfonates (LAS) have been studied. It has been found that the counterion hydration radius of the corresponding commercial
linear alkylbenzene sulfonates has great influence on solubility, viscosity, surface tension and critical micelle concentration
(CMC). The counterion has no influence on the detergency performance of the finished formulation. The alkyl chain length and
the presence of tetralines have an important influence on solubility, viscosity and surface tension. 相似文献
42.
研究了甲基丙烯磺酸钠(SMAS)、丙烯酰胺(AM)与淀粉接枝共聚物的合成方法,接枝反应的影响因素和热稳定性。实验结果表明,该接枝反应基本符合自由基反应的一般规律,并且其聚合产物具有明显的抗高温能力。 相似文献
43.
丙烯腈/醋酸乙烯酯/甲基丙烯磺酸钠三元水相共聚体系竞聚率的研究 总被引:2,自引:0,他引:2
根据该AN/VAC/SMAS三元共聚体系特征,根据竞聚率计算的原理,融合二元共聚和三元共聚的基础理论,利用核磁共振技术测定共聚物组成,用Mayo-lewis共聚物组成方程拟合实验数据计算竞聚率.同时研究了AN/VAC/SMAS三元水相共聚反应体系的特征,测定了该三元共聚体系表现竞聚率. 相似文献
44.
Mercier Gustavo A. Jr; Osman Roman; Weinstein Harel 《Protein engineering, design & selection : PEDS》1988,2(4):261-270
A proton transfer triggered by a ligand interacting with thereceptor had been suggested as the initial step in the activationof a receptor for the neurotransmitter serotonin (5-hydroxy-tryptamine;5-HT). To evaluate the role of the receptor macromolecule inmodulating the primary molecular event in ligand-mediated activation,the process of proton transfer was analysed in the environmentof a protein model for the 5-HT receptor. In the absence ofa detailed receptor structure, the enzyme actinidin was chosenas the model for the receptor based on criteria obtained fromstructure-activity considerations on the ligands. The firstsimulation of a mechanism for receptor activation was performedon this model using methods of theoretical chemistry to studythe effect of specific structural elements. The premise is thatthe role of the elements of secondary structure of soluble proteins(e.g. actinidin) in determining structure-function relationsin these macromolecules is maintained when these elements arepart of membrane-bound receptor proteins. Results from the calculationsof the effects of the six alpha helices of actinidin on theproton transfer process from the imidazolium side chain of His162 to the thiol side chain of Cys 25 in the protein show thatthe helices contribute in different ways to modulate the energyof proton transfer. The largest helix, Al, opposes the protontransfer through the effect of the helix dipole. The chargedresidues (primary structure) in helix A3 favor the proton transfer,and mask the effect of its helix dipole (secondary structure)which opposes the transfer. The direction of the proton transfersimulated for the activation mechanism is opposite to that assumedin the catalytic process of the thiol protease, and the entireprotein environment opposes the transfer. This supports thespecific role of the ligand in triggering the proton transferas a response to its binding. 相似文献
45.
用共沉淀法制备Fe3O4磁流体,总结出用十二烷基磺酸钠与聚乙二醇作为表面活性剂制备水基磁流体的合适条件:(1)反应温度为室温或不高于35℃;(2)表面活性剂十二烷基磺酸钠的最佳用量为0.0030~0.0040 g/80 mL;(3)第一次包裹的最佳pH为9~10;(4)聚乙二醇作为第二次包裹的表面活剂时,体系最佳温度为40℃左右;(5)表面活性剂聚乙二醇的最佳用量为0.0050~0.0060 g/80 mL。通过实验制得了能稳定存在180 d的水基磁流体。并用透射电镜、红外光谱、分光光度计、古埃磁天平等进行了初步表征。 相似文献
46.
47.
48.
一般的酸性染料溶解度较小,而本文所介绍的单或双偶氮酸性染料,实际上是以碱金属盐的形式存在,由于加入了(按重量计)80%~30%的木质素磺酸铵,改善了室温的冷水溶解度。木质素磺酸铵既作为标准化试剂,用来调节高强度染料到稳定的商品染料,同时又能提高染料在室温时冷水溶解度。 相似文献
49.
Dmitri V. Besedin Leila Yu. Ustynyuk Yuri A. Ustynyuk Valerij V. Lunin 《Topics in Catalysis》2005,32(1-2):47-60
The model reactions of ethylene polymerization and hydrogenolysis of linear alkanes (propane, n-butane, and n-pentane) on the silica-supported zirconium hydrides (Si–O)3ZrIVH, (Si–O)2ZrIVH2, and (Si–O)2ZrIIIH were studied using the DFT approach. Catalytic processes under study were shown to occur involving different surface hydrides. The ethylene polymerization was found to proceed at comparable rates on the zirconium monohydrides, (Si–O)3ZrH, and dihydrides, (Si–O)2ZrH2. Cleavage of linear alkanes on the monohydrides (Si–O)3ZrH is thermodynamically unfavorable; however, the dihydrides (Si–O)2ZrH2 can act as catalysts of the process under mild conditions. Hydrides of the trivalent zirconium, (Si–O)2ZrIIIH, can also contribute to the hydrogenolysis reaction. A feature of all the systems studied is low regioselectivity of the corresponding processes. 相似文献
50.
K. Wakui K. Satoh G. Sawada K. Shiozawa K. Matano K. Suzuki T. Hayakawa Y. Yoshimura K. Murata F. Mizukami 《Catalysis Letters》2002,81(1-2):83-88
Dehydrogenative cracking reaction of n-butane was studied using HZSM-5 catalyst modified with various metal oxides. Alkaline earth (magnesium), transition metal (cobalt) and rare earth (lanthanum) elements are used for the modification. The selectivity of the products was studied at low conversion (20%). Methane, ethane, ethylene, propylene, butenes and butadiene were the main products. With the use of the cobalt- or magnesium-containing HZSM-5, dehydrogenative cracking was observed and the selectivity of ethylene was much larger than that of ethane. On the other hand, the selectivity of ethylene and ethane were almost the same in the reaction using the lanthanum-containing HZSM-5. It is considered that the cobalt- and magnesium-loaded sites on HZSM-5 played an important role in the dehydrogenative cracking. 相似文献