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101.
利用微机在电位溶出理论滴定曲线上叠加偶然误差模拟实际滴定曲线,比较了从滴定曲线求水中痕量金属有机络合参数的两种数学处理方法;并对滴定程序进行了优化。  相似文献   
102.
《分离科学与技术》2012,47(5):1065-1077
Abstract

A theoretical study about 235U enrichment by the chemical exchange method in U(IV)‐U(VI) system on anion‐exchange resins is presented. The 235U isotope concentration profiles along the band were numerically calculated using an accurate mathematical model and simulations were carried out for the situation of product and waste withdrawal and feed supply. By means of numerical simulation, an estimation of the migration time, necessary for a desired enrichment degree, was obtained. The required migration distance, the production of uranium 3 at.% 235U per year and the plant configuration are calculated for different operating conditions. An analysis of the process scale for various experimental conditions is also presented.  相似文献   
103.
络合萃取法处理含苯胺工业废水   总被引:7,自引:1,他引:7  
采用络合萃取法处理苯胺废水。在常温、油水相比为1:10的条件下,将体积分数为70%磷酸三丁酯-30%煤油组成的萃取剂三级络合萃取苯胺废水,苯胺脱除率可达99.84%,提出了处理苯胺工业废水的综合工艺流程。  相似文献   
104.
以废催化剂为原料制备氧化锌及铜粉的研究   总被引:4,自引:0,他引:4  
孟韵  王犇 《无机盐工业》2001,33(3):35-36
以铜-锌废催化剂为原料制备高纯、肤色活性氧化锌等产品,不仅回收了资源,而且减少了环境污染。研究采用氨络合转换方法,制备了医用或化妆品活性氧化锌等产品。  相似文献   
105.
三烷基氧膦(TRPO)萃取有机羧酸的研究   总被引:5,自引:0,他引:5  
络合萃取法对有机物稀溶液的分离具有高效性和高选择性。选择甲酸、乙酸、一氯乙酸、二氯乙酸、三氯乙本酸为分离对象,三烷基氧膦(TRPO)为络合剂,煤油为稀释剂,进行了系统的萃取相平衡实验。结果表明,溶质的pKa对络合萃取影响起主导作用。红外光谱定性分析表明,TRPO萃取有机羧酸为氢键溶剂比历程,负载有机酸的TRPO中的P=0吸收峰的位移与有机羧酸的酸性有关。采用质量作用定量定律分析方法,建立了相平衡分配系数的表达式,模型拟合精度是令人满意的。  相似文献   
106.
Peculiarities in catalytic activity in carbon monoxide oxidation as well as some structure, electronic and magnetic properties of the three oxide catalysts, Mn3+–O/Al2O3 (1), Mn3+–O–Fe/Al2O3 (Mn-substituted spinel, 2) and -Fe2O3/Al2O3 (3), were studied by kinetic measurements and by Mössbauer spectroscopy. The catalysts 1 and 2 showed a kinetic bistability with a sharp transition towards more reactive state at 200°C (ignition point). In contrast, for catalyst 3, at 200–250°C, the behavior of reaction rate against temperature did not display noticeable hysteresis. On cooling the catalysts 1 and 2, extinction was observed at about 170 and 120°C, respectively, i.e., at 30–80°C lower than the corresponding ignition points. Proximity of activation energy for the high and low activity (15–19 kJ/mol) for both Mn-containing catalysts suggests an increase in the number of active sites at high temperature with no changes in the reaction mechanism. The considerable difference between Mn-containing catalysts 1, 2 and Fe-containing catalyst 3 may be caused by Jahn–Teller (JT) type distortions of the oxygen polyhedron around Mn3+. A significant spontaneous axial bond stretching within the local polyhedron seems to diminish Mn–O binding energy, facilitate the participation of surface oxygen species, OS, in the oxidation of CO by a redox mechanism and promote oxygen vacancies at the surface that would cause considerable effect on the activity. An increase in the width of the counterclockwise hysteresis loop for the catalyst 2 compared to the catalyst 1 indicates that clusters of mixed spinel provide more active sites and more labile OS species than clusters of the binary Mn oxide.  相似文献   
107.
以磷酸三丁酯 (TBP)、三烷基胺 (73 0 1)为络合剂 ,分别采用甲苯、异丙基甲酮、正辛醇、煤油作为稀释剂对丁二酸稀溶液进行络合萃取。结果表明 :混合型络合剂对丁二酸稀溶液进行萃取 ,可取得满意的分离效果 ,平衡分配系数D高达 15 .2 8;讨论了丁二酸溶液初始浓度、溶液pH值以及温度对络合萃取相平衡分配系数的影响。利用傅立叶红外光谱仪测定了负载有机相中萃合物的结构 ,对三烷基胺络合萃取丁二酸稀溶液的机理进行了探讨  相似文献   
108.
易江华  章传力 《染料与染色》2012,49(2):42-43,51
采用自行研制的萃取剂-PN处理醚化含酚废水,处理后的废水可以达到国家三级排放标准.废水萃取率大于99.5%,反萃取率大于99.3%,萃取剂可以循环套用,反萃取后的碱液回收利用酚降低生产成本.  相似文献   
109.
《分离科学与技术》2012,47(12):1801-1809
The strongly basic polystyrene gel resins Amberjet 4200, Amberjet 4600, and the macroporous strongly basic polystyrene Purolite A 520E were investigated for their sorption properties towards Cd(II), Co(II), and Zn(II) complexes with MGDA. The object of the study was the sorption behavior of three metal ions on the above-mentioned anion exchangers, depending on the metal ions’ concentration, pH, contact time, and temperature. MGDA is an alternative, environmentally friendly complexing agent. The sorption data were fitted to the Langmuir and Freundlich models. Three different kinetic behaviors: pseudo first order, pseudo second order, and intraparticle diffusion were tested. The variations of thermodynamic functions were also calculated.  相似文献   
110.
In this study, imidazolium functionalized poly(vinyl alcohol) (PVA) was synthesized by acetalization and direct quaternization reaction. Afterwards, composite anion exchange membranes based on imidazolium‐ and quaternary ammonium‐ functionalized PVA were used for direct methanol alkaline fuel cell applications. 1H NMR and Fourier transform infrared spectroscopy data indicated that imidazole functionalized PVA was successfully synthesized. Inductively coupled plasma mass spectrometry data demonstrated that the imidazolium structure was efficiently obtained by direct quaternization of the imidazole group. Composite anion exchange membranes were fabricated by application of the functionalized PVA solution on the surface of porous polycarbonate (PC) membranes. Fuel cell related properties of all prepared membranes were investigated systematically. The imidazolium functionalized composite membrane (PVA‐Im/PC) exhibited higher ionic conductivity (7.8 mS cm?1 at 30 °C) despite a lower water uptake and ion exchange capacity value compared to that of quaternary ammonium. In addition, PVA‐Im/PC showed the lowest methanol permeation rate and the highest membrane selectivity as well as high alkaline and oxidative stability. Dynamic mechanical analysis results reveal that both composite membranes were mechanically resistant up to 107 Pa at 140 °C. The superior performance of imidazolium functionalized PVA composite membrane compared to quaternary ammonium functionalized membrane makes it a promising candidate for direct methanol alkaline fuel cell applications. © 2020 Society of Chemical Industry  相似文献   
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