硫化铜矿中提取铜的新方法研究

对从硫化铜矿中提取铜的溶剂进行了详细研究，提出了“过硫酸铵－氨水－Ａｇ￣＋”催化、氧化、络合的提取法。     

1，4－丁二醇的生产及市场需求

介绍了１，４－丁二醇的生产工艺、生产能力、产量和市场需求。     

固相缩聚共聚酯的熔融行为和结晶速率研究

通过固相缩聚合成了两种不同结构的高分子量共聚酯，研究了样品的熔融行为和结晶速率。研究发现，共聚酯的熔融峰随着固相聚合温度和时间的变化而与纯ＰＥＴ有明显的差别，共聚酯泊结晶速率与慢于纯ＰＥＴ的结晶速率。     

A Linear Cross-Coupled Control System for High-Speed Machining

We present a linear cross-coupled controller to improve highspeed contouring accuracy independently of tracking accuracy in a biaxial machine tool feed drive servomechanism. Unlike conventional cross-coupled controllers, the cross-coupled controller presented here is a linear system, so it is very easy to perform the stability and steady-state error analysis, and to optimise the controller parameters. The proposed controller is evaluated experimentally on a CNC LOM machine and compared to an uncoupled controller and a conventional cross-coupled controller. Controller performance is evaluated for a circular contour at a feedrate of 30 m min _1 . The experimental results show that the proposed controller can greatly reduce the contour error at large feedrates. The linear cross-coupled controller is simple to implement and is practical.     

纳米级BaAl_2O_4微粉的制备和性质

分别用溶胶 -凝胶法、低温固相反应法 ,制得了纳米级BaAl2 O4微粉 ,用电镜观察了其形貌和粒径的大小 ,用X-射线衍射仪进行了物相分析 ,测定了其纯度与晶型 ,讨论了制备方法与粒度大小的相互影响     

Unperturbed dimension of poly(4-acetoxystyrene) measured in good and theta solvents

In order to obtain the additional data concerning the unperturbed dimension of poly-4-substituted styrene, light scattering measurements are performed on the twenty-two fractions with molecular weight of (0.91–352)·10⁴ of poly(4-acetoxystyrene) in dioxan at 25°C, from which the molecular weight obtained was found easily to be evaluated with the gel permeation chromatography using THF. Phase separation experiments for this polymer indicate that the theta state is attained in isopropyl acetate at 19.7°C and butyl acetate at 26.8°C. By making viscosity measurements at that state, the value of K_Θ is directly evaluated as 5.4·10^?4 dl g^?1. The limiting viscosity number is also obtained in good solvents, THF and dioxan, at 25°C and constants of the Mark-Houwink-Sakurada equation in each solvent are determined. Further, approximately the same K_Θ as above is obtained from these data with the Stockmayer-Fixman plot. The calculated value of steric factor, 2.37, on this polymer may be plausible, compared with those of polyvinylaromatic derivatives.     

Microwave Communication to Moving Parts Inside Machines

Cables to moving parts on a linear actuator in production machines, such as pick-and-place machines, are a source of unreliability owing to the possible breaking of a cable. They further reduce the positioning precision of the actuator owing to additional forces. Slotted waveguide systems for rail vehicles based on 2.4 GHz transmission frequency are well known, but transmitters/receivers and waveguides are bulky. The paper reports on the reduction in size of the equipment, adapted to 5.8 GHz using a commercial off-the-shelf RadioLan communication module. Further, the efficient termination of the wave-guide and a new way to reduce standing-wave effects is also discussed.     

7-羟基全氢化噁唑并噁嗪鞣剂的合成及其鞣性研究

报导了新型鞣剂 7-羟基全氢化唑并嗪 (以下简称 OX- Z)的合成方法。试验确定合成的最佳条件为 :在氮气保护下 ,将等摩尔量的二乙醇胺在 10℃水浴中缓慢滴入乙二醛中 ,滴加时间 0 .5 h,在 2 0℃水浴中继续反应 1.5 h,产率为 6 2 .9%。 OX- Z对浸酸绵羊皮单独鞣制 ,可使收缩温度升高到 87℃。最佳鞣制条件为 :p H10 .0 ,OX- Z用量 5 % ,鞣制时间 8h。在对 OX- Z与皮胶原的结合类型的研究中证明它们之间是以化学键结合的。     

Comparison of inward and outward grown Pt modified aluminide diffusion coatings on a Ni based single crystal superalloy

Two commercial Pt modified aluminide coatings (RT22 and MDC150L) on the same single crystal Ni-based superalloy (CMSX-4) were studied by: scanning electron microscopy; transmission electron microscopy; energy dispersive X-ray spectrometry; and gravimetry. The RT22 coating is an inward grown coating (high activity), while MDC150L is produced by outward growth (low activity). Samples were oxidised in still laboratory air at 1050 °C for various times up to 2000 h. It was found that the outward grown coating produced a slower growing oxide that was more spallation resistant. Several possible reasons for this were identified including: coating purity; coating surface topography; and ductile to brittle transition temperature. The microstructural differences between the two coatings in the as-coated condition were investigated and the development of their microstructure during heat treatment was described. A model for coating growth during heat treatment was proposed.     

大庆长垣外围油田的开发问题

本文在对大庆长垣外围油田的地质情况、油藏类型综合分析评价的基础上,论述了开发这些油田的一系列有关问题。