硫酸盐木浆企业恶臭污染状况及治理措施

通过分析硫酸盐木浆企业生产工艺,恶臭气体为硫酸盐木浆企业排放的特征污染物.分析了其产生过程、主要成分、排放方式,对有组织排放和无组织排放恶臭气体的收集提出了相应措施.提出了以收集燃烧为主,结合控制无组织排放,改进生产配方,优化燃烧系统等多种方法综合运用,彻底解决恶臭污染的措施.     

芳纶帘线——轻型载重子午线轮胎理想的胎体骨架材料

采用芳纶帘线替代普通聚酯帘线进行轻型载重子午线轮胎的生产，并将两种化胎性能进行了对比。结果表明，采用芳纶帘线生产的轮胎静负荷性能、耐外性能、强度性能及高速性能等均可达到普通聚酯帘线轮胎的水,轮胎的刚性、转向能动性和驾驶性能提高，而且还可提高生产效率，同时减小了轮胎质量，节约了成本。     

氧脱木质素对稻草SFP浆性能的影响

亚硫酸盐―甲醛―蒽醌(SFP-AQ)法是适合于草类原料的一种制浆方法。文章研究了氧脱木质素对稻草SFP浆的卡伯值、白度、粘度及强度性能的影响。结果表明,较高的用碱量有助于残余木质素的脱除,在合适的工艺条件下,稻草SFP浆单段氧脱木质素的脱木质素率可达50%以上。在氧脱木质素用碱量3.5%、氧压0.4 MPa、温度110℃、时间60 min或90 min的条件下,稻草SFP浆的卡伯值较低、白度较高,而同时具有良好的粘度和强度性能。     

The use of wood pulp and radiation‐modified starch in wastewater treatment

Radiation‐induced graft copolymerization of maize starch/acrylic acid has been performed. Also, natural byproduct wood pulp was used after chemical treatment for the removal of metal ions from the investigated wastewater. The surface and structure morphology of the wood pulp and starch/acrylic acid were investigated by scanning electron microscopy and infrared spectroscopy. The physical parameters, such as swelling, gel percentage, and grafting efficiency (%) of starch/acrylic acid copolymer, were studied. The factors affecting the abilities of the prepared materials for removing heavy metal ions and dyes from aqueous solutions were studied. It was found that the maximum metal uptake is in the following sequence: Fe³⁺ > Cr³⁺ > Pb²⁺ > Cd²⁺. The adsorption capacity of such investigated metal ions increases with the increase of pH values. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

芳纶纤维表面改性及其对芳纶纸力学性能的影响

利用氯磺酸、醋酸酐对芳纶短切纤维进行了改性处理,再用处理后的纤维配抄芳纶纸,探讨了处理工艺对芳纶纸力学性能的影响.结果表明,当氯磺酸浓度为2%,处理时间为10min,处理温度为50℃时,芳纶纸的力学性能较好.用100%的醋酸酐对芳纶纤维进行处理然后配抄成纸,所得纸张的抗张指数和撕裂指数分别提高了63.8%和21.4%.另外,芳纶纤维经过醋酸酐浸泡1min后再用甲醇处理3min,芳纶纸的抗张指数和撕裂指数分别提高了84.7%和38.4%.     

不同筛分设备对化学浆细小纤维质量性能的影响

对漂白针叶木浆进行了纤维筛分分级制取细小纤维试样,对比探讨了DDJ和SWECO圆形振动筛两种细小纤维筛分的特性,并且与标准纤维进行配抄,研究了不同细小纤维添加量对纸张性能的影响.实验结果表明:SWECO细小纤维收益率明显高于DDJ细小纤维;DDJ细小纤维具有较高的表面电荷,而SWECO细小纤维具有较高的粘度、比沉降容积;与DDJ细小纤维相比,SWECO细小纤维更能减少纸张的松厚度和透气度,增强纸张的强度.     

聚碳酸酯基聚氨酯/芳纶纤维复合材料的制备与性能

以聚碳酸酯二元醇为软段,利用预聚体法制备了系列聚碳酸酯基聚氨酯/芳纶浆粕纤维(Aramid pulp)复合材料,研究了芳纶浆粕纤维对聚碳酸酯基聚氨酯弹性体(PUE)力学性能的影响。采用扫描电镜、X射线衍射、差示扫描量热分析、热重分析、红外光谱及电子拉伸机等测试仪器对聚氨酯复合材料的结构与性能进行了表征和分析。结果表明,芳纶浆粕纤维能有效实现对聚氨酯弹性体的增强作用,其中对撕裂强度的增强尤为突出。当芳纶浆粕纤维用量为0.5%时,复合材料的撕裂强度由106 k N/m提高到120 k N/m,表现出最好的力学性能;芳纶浆粕纤维在聚氨酯中分散均匀,提高了复合材料的热稳定性。     

一种纸浆模塑蜂窝板材缓冲性能的研究

目的 为了解决因技术水平制约,纸蜂窝材料芯纸构型单一、单层厚度受限等瓶颈问题,开发一种通用型缓冲结构板材。方法 以纸浆模塑为原材料,以六棱柱结构为例,设计并加工出一种通过正反插方式组合而成的蜂窝板材,并采用有限元方法进行仿真,得到关键结构参数和相关最优参数组合。结果 正反插结构的纸浆模塑板材具有较好的耦合效应,承载能力相较于单层板材大幅提高;结合极限载荷、比吸能等评价指标对板材性能进行定量分析,初始压缩载荷最大可达到73.7kN,满足托盘等重型包装器具的承载需求。通过极差和方差分析可知,各结构参数对板材承载性能和缓冲性能的影响程度,研究表明单元壁厚、中截面边长对该板材承载性能和缓冲性能影响显著。结论 正反插结构解决了现有纸蜂窝材料高度、厚度受限,构型单一等瓶颈问题,提高了纸浆模塑蜂窝板材的承载性能和缓冲性能,可以满足重载要求。与之相关的其他正多边形锥形薄壁管单元亦可以使用同样的正反插设计理念和研究方法。     

Flotation performances of polymorphic pyrrhotite

The floatability of different crystalline structures of pyrrhotite (monoclinic and hexagonal) was studied. It is shown that the floatability of monoclinic and hexagonal has obvious difference, and that the flotation recovery of monoclinic pyrrhotite is larger than that of hexagonal pyrrhotite using different collectors. When butyl dithiophosphate is used as the collector, the recovery is larger than that by sodium butyl xanthate and sodium diethyl dithiocarbamate. At the pH values ranging from 6 to 9, monoclinic pyrrhotite can be floated well, and the flotation recovery is higher than 90%. Monoclinic and hexagonal pyrrhotites are more easily activated by Cu²⁺ in acidic conditions than in alkaline conditions. But Cu²⁺ cannot activate hexagonal pyrrhotite using sodium diethyldithiocarbamate as the collector. By the measurement of contact angle, it is indicated that monoclinic and hexagonal pyrrhotites float well and are easily activated by Cu²⁺ when dithiophosphate is used as the collector. Using sodium diethyl dithiocarbamate as a collector, the relationship between potential and pH range for pyrrhotite flotation is established. At pH 5, the optimal potential range for flotation of monoclinic pyrrhotite is about 125–580 mV (vs SHE), with the maximum flotation occurring at about 350 mV (vs SHE); the optimal potential range for flotation of hexagonal pyrrhotite is 200–580 mV (vs SHE), with the maximum flotation occurring at about 300 mV (vs SHE).     

离心式纸浆泵内部流动的数值模拟

为研究小流量工况下离心式纸浆泵内部流动特性,采用Mixture多相流模型对某一离心式纸浆泵内部流动进行三维不可压两相湍流流动计算,并与清水工况的计算结果进行了比较。对比分析了不同流量工况及介质对泵内流体速度、压力和体积浓度分布的影响,并预测了水力性能。结果显示:纸浆泵叶轮流道内速度变化不均,存在大面积回流;相同介质时,流量越小叶轮流道内部流动越不稳定;相同工况下,清水介质下的流动较两相流时更为稳定;两相流时泵的扬程及效率整体都低于清水介质;纸浆分布局部不均,叶片表面进口处叶根和叶顶部位浓度较大,易造成局部磨损,降低叶轮寿命。