用流体静力学称量法测定黄金饰品中金的含量

本文研究了用流体静力学称量法，通过测定密度计算金饰品中金的含量，该法简单实用，设备投产少，能满足用户日常检定的需要。该法克服了“试金石”法检定黄金的粗糙性，又解决了电子探针在测试过程中，可能对材料成人偏析所造成的误差。     

杂原子分子筛ZrBSiALPO4-5的合成结构及催化性能的研究

我们用水热合成法合成了一种锆 -硼 -硅磷铝分子筛 ,通过化学分析、测定晶胞参数及用XRD ,MASNMR方法进行表征 ,证实了锆 -硼 -硅原子进入了分子筛骨架 ,并且具有和AlPO4- 5相似的结构 ;用IR ,NH3 -TPD表征方法测出了它们的酸性 ,测定结果表明 ,它具有L -酸和B -酸中心 ,以中等强度酸为主 ,在苯与烯烃烷基化反应中表现出良好的催化活性和长寿命并且对 2 -位和 3-位苯的烷基化反应具有高选择性 ,有可能替代HF成为一种环境友好的新型催化剂     

Correlation of the transport properties of simple fluids at low temperatures and high pressures based on the generalized Eucken relation and the molecular dynamics of hard sphere fluid

A generalized correlation is developed for the viscosity and thermal conductivity of isotropic fluids under high pressures (up to 200 MPa) and low temperatures (down to 85 K). Two known observations have been taken into consideration in the development of the correlation. First, the Alder correction factors for the Enskog theory values of transport coefficients obtained from molecular dynamics simulations for hard sphere fluids are incorporated. The inclusion of these corrections in the theory makes it possible to describe correctly the density dependence of the hard sphere viscosity and thermal conductivity at high pressures. The hydrodynamic cage effect, which is manifested in the molecular motions of dense fluid systems, is thus correctly accounted for. Second, the generalized Eucken relation, which relates the thermal conductivity to the viscosity, is incorporated. As a consequence, an internally consistent correlation is obtained, which can adequately predict the behavior of the thermal conductivity from given values of viscosity. Tests on simple fluids, such as argon, krypton, etc., show that the correlation is valid within a few percent for the entire fluid range where experimental data are available for comparison, and also along the vapor-liquid saturation line, with the exclusion of the critical region. Furthermore, since the variables appearing in the theory are in reduced form, a corresponding states correlation is established for isotropic fluids.     

PBT工程塑料生产中MFR的控制

针对使用BUSS捏合机生产聚对苯二甲酸丁二酯(PBT)过程中出现的熔体流动速率(MFR)与产品配方体系中低分子量PBT树脂用量间的异常关系进行了研究和分析。结果表明，混炼加工PBT时，产品的MFR取决于两个因素的综合作用，一为产品配方中高、低粘度树脂的比例；二为低分子量树脂对主机功率的影响。综合二者影响，PBT的MFR与低分子量PBT用量关系近似为y=0．0471x^2-3．6347x 107．83。     

GPC法测定PAN的平均相对分子质量及其分布

用凝胶渗透色谱 (GPC)测定PAN的平均相对分子质量及其分布。采用宽分布的PAN标准试样 ,在溶剂二甲基甲酰胺中加入 0 .0 4～ 0 .0 8mol/L的NaNO3替代LiBr ,提高了色谱柱的分离效果。用计算机模拟出PAN的GPC校正曲线方程 ,对宽分布的标准试样进行重复测定 ,结果相对标准偏差均小于 3 .5 %。     

Transport properties of nonelectrolyte liquid mixtures—IV. Viscosity coefficients for benzene,perdeuterobenzene, hexafluorobenzene,and an equimolar mixture of benzene + hexafluorobenzene from 25 to 100°c at pressures up to the freezing pressure

Viscosity coefficient measurements made with an estimated accuracy of ±2% using a self-centering falling body viscometer are reported for benzene, perdeuterobenzene, hexafluorobenzene and an equimolar mixture of benzene + hexafluorobenzene at 25, 50, 75 and 100°C at pressures up to the freezing pressure. The data for each liquid at different temperatures and pressures are correlated very satisfactorily by a graphical method based on plots of 9.118×10⁷ V ^2/3/(MRT)^1/2 versus logV, and are reproduced to within the experimental uncertainty by a free-volume form of equation. Application of the empirical Grunberg and Nissan equation to the mixture viscosity coefficient data shows that the characteristic constant G is practically temperature- and pressure-independent for this system.     

The molecular structure of asphaltene: an unfolding story

From detailed chemical and thermal degradation studies, a host of structural units have been identified in Alberta asphaltenes. It has been shown that the extent of aromatic condensation is low and that highly condensed pericyclic aromatic structures are present in very low concentrations. From the available data reported to date, it is concluded that petroleum asphaltenes were mainly derived through the catalytic cyclization, aromatization and condensation of n-alkanoic, probably fatty acids, precursors.     

熔体流动时间法测定PBT树脂特性粘数的研究

开发了一种新的特性粘数分析方法 ,该方法采用熔体流动时间计算特性粘数 ,与经典特性粘数分析方法有很好的相关性且具有分析时间短、费用低、无污染等优点。     

绥化市地下水水化学特征及水质现状评价

为了查明绥化市的地下水环境状况,运用描述性统计、地统计学理论、相关分析、Piper三线图法等对绥化市的地下水水化学特征进行全面分析。在此基础上采用了基于综合赋权的五元联系数法对研究区水质现状进行评价,并且利用秩相关系数法进行水质变化趋势分析。结果表明,研究区地下水略偏酸性,部分水样的水质指标存在超标现象。地下水中Ca 2＋为优势阳离子,HCO 3－为优势阴离子。研究区的铁、锰、氟超标是受原生污染影响,地下水中的Cl－与SO 2－4,Na＋与Mg 2＋存在同一来源。将基于综合赋权的五元联系数法的评价结果与模糊综合评判法相比较,结果表明其评价结果是合理可靠的,符合客观实际。通过秩相关系数法表明研究区地下水水质状况在一定程度上有所改善。     

一级倒立摆SIRMs动态权重模糊推理算法仿真

为解决倒立摆采用常规模糊控制算法,其推理规则数目随输入变量成指数增长的问题,对直线一级倒立摆设计了基于SIRMs和动态连接权重模型的模糊控制器,该控制器将倒立摆的四输入变量的模糊控制化成单维模糊控制问题来解决,大大减少了模糊规则数。仿真结果表明,该控制算法能够较好地完成倒立摆的运动控制,具有很强的鲁棒性和动静态特性。