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51.
Thanh Hai Nguyen Phan Khanh Linh Tran Van An Dinh Duy Thanh Tran Nam Hoon Kim Joong Hee Lee 《Advanced functional materials》2023,33(7):2210101
Development of multifunctional electrocatalysts with high efficiency and stability is of great interest in recent energy conversion technologies. Herein, a novel heteroelectrocatalyst of molecular iron complex (FeMC)-carbide MXene (Mo2TiC2Tx) uniformly embedded in a 3D graphene-based hierarchical network (GrH) is rationally designed. The coexistence of FeMC and MXene with their unique interactions triggers optimum electronic properties, rich multiple active sites, and favorite free adsorption energy for excellent trifunctional catalytic activities. Meanwhile, the highly porous GrH effectively promotes a multichannel architecture for charge transfer and gas/ion diffusion to improve stability. Therefore, the FeMC–MXene/GrH results in superb performances towards oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) in alkaline medium. The practical tests indicate that Zn/Al–air batteries derived from FeMC–MXene/GrH cathodic electrodes produce high power densities of 165.6 and 172.7 mW cm−2, respectively. Impressively, the liquid-state Zn–air battery delivers excellent cycling stability of over 1100 h. In addition, the alkaline water electrolyzer induces a low cell voltage of 1.55 V at 10 mA cm−2 and 1.86 V at 0.4 A cm−2 in 30 wt.% KOH at 80 °C, surpassing recent reports. The achievements suggest an exciting multifunctional electrocatalyst for electrochemical energy applications. 相似文献
52.
Zhuoran Lv Baixin Peng Ximeng Lv Yusha Gao Keyan Hu Wujie Dong Gengfeng Zheng Fuqiang Huang 《Advanced functional materials》2023,33(16):2214370
Alloying-type metal sulfides with high theoretical capacities are promising anodes for sodium-ion batteries, but suffer from sluggish sodiation kinetics and huge volume expansion. Introducing intercalative motifs into alloying-type metal sulfides is an efficient strategy to solve the above issues. Herein, robust intercalative In S motifs are grafted to high-capacity layered Bi2S3 to form a cation-disordered (BiIn)2S3, synergistically realizing high-rate and large-capacity sodium storage. The In S motif with strong bonding serves as a space-confinement unit to buffer the volume expansion, maintaining superior structural stability. Moreover, the grafted high-metallicity Indium increases the bonding covalency of Bi S, realizing controllable reconstruction of Bi S bond during cycling to effectively prevent the migration and aggregation of atomic Bi. The novel (BiIn)2S3 anode delivers a high capacity of 537 mAh g−1 at 0.4 C and a superior high-rate stability of 247 mAh g−1 at 40 C over 10000 cycles. Further in situ and ex situ characterizations reveal the in-depth reaction mechanism and the breakage and formation of reversible Bi S bonds. The proposed space confinement and bonding covalency enhancement strategy via grafting intercalative motifs can be conducive to developing novel high-rate and large-capacity anodes. 相似文献
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54.
Ziyang Jia Rui Ding Wujiang Yu Yi Li Ailin Wang Miao Liu Feng Yang Xiujuan Sun Enhui Liu 《Advanced functional materials》2022,32(1):2107674
Herein, a trimetallic Ni–Co–Zn perovskite fluoride (ABF3) (denoted as KNCZF) electrode material is explored for advanced aqueous supercabatteries (ASCBs), with KNCZF and activated carbon–FeBiCu@reduced graphene oxides (AC–FeBiCu@rGO) as cathode and anode, respectively, which outperform aqueous supercapacitors (ASCs) and batteries (ABs) with AC and FeBiCu@rGO anodes because of the synergistic effect of pseudocapacitive (KNCZF), capacitive (AC), and faradaic (FeBiCu@rGO) responses. One of the important findings is that the KNCZF shows a typical bulk phase conversion mechanism for charge storage in the alkaline media with the transition of ABF3 perovskite nanocrystals into amorphous metal oxides/(oxy)hydroxides nanosheets, showing the redox-active and redox-inert roles for the Ni/Co and Zn species, respectively, which can be deduced by various ex-situ techniques. Another interesting finding is that the redox-inert Zn species largely enhance the activity of Ni/Co redox-active species in the ABF3 materials, mainly owing to the promotion of surface electroactive sites, adsorption of OH?, and charge transfer of surface Ni/Co atoms by Zn-doping, which can be proved by ex-situ characterizations and theoretical calculations. Overall, this study reveals the structure–activity relationship and charge storage mechanisms of Zn-doping ABF3 materials for advanced ASCBs, showing a great impact on developing advanced electrochemical energy storage. 相似文献
55.
Zhonghai Song Ning Cao Xuejiao Gao Qiu Liang 《Fullerenes, Nanotubes and Carbon Nanostructures》2017,25(2):65-70
Ultrathin Co3O4 nanosheets grown on the reduced graphene oxide (Co3O4/rGO) was synthesized by a simple hydrothermal method and was investigated as a cathode in a Li-O2 battery. Benefited from the synergistic effect between Co3O4 and rGO, the hybrid exhibits a high initial capacity of 10,528 mAh g?1 along with a high coulombic efficiency (84.4%) at 100 mA g?1. In addition, the batteries show an enhanced cycling stability and after 113 cycles, the cut-off discharge voltage remains above 2.5 V. The outstanding performance is intimately related to the high surface area of rGO, which not only provide carbon skeleton for the uniform distribution of Co3O4 nanosheets but also facilitate the reversible formation and decomposition of insoluble Li2O2. The results of electrochemical tests confirm that the Co3O4/rGO hybrid is a promising candidate for the Li-O2 batteries. 相似文献
56.
Phase Separation Derived Core/Shell Structured Cu11V6O26/V2O5 Microspheres: First Synthesis and Excellent Lithium‐Ion Anode Performance with Outstanding Capacity Self‐Restoration 下载免费PDF全文
Jian Pei Gang Chen Qiang Zhang Changfeng Bie Jingxue Sun 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(17)
Novel amorphous vanadium oxide coated copper vanadium oxide (Cu11V6O26/V2O5) microspheres with 3D hierarchical architecture have been successfully prepared via a microwave‐assisted solution method and subsequent annealing induced phase separation process. Pure Cu11V6O26 microspheres without V2O5 coating are also obtained by an H2O2 solution dissolving treatment. When evaluated as an anode material for lithium‐ion batteries (LIBs), the as‐synthesized hybrid exhibits large reversible capacity, excellent rate capability, and outstanding capacity self‐recovery. Under the condition of high current density of 1 A g?1, the 3D hierarchical Cu11V6O26/V2O5 hybrid maintains a reversible capacity of ≈1110 mA h g?1. Combined electrochemical analysis and high‐resolution transmission electron microscopy observation during cycling reveals that the amorphous V2O5 coating plays an important role on enhancing the electrochemical performances and capacity self‐recovery, which provides an active amorphous protective layer and abundant grain interfaces for efficient inserting and extracting of Li‐ion. As a result, this new copper vanadium oxide hybrid is proposed as a promising anode material for LIBs. 相似文献
57.
Zhongxue Chen Fei Xu Shunan Cao Zhengfeng Li Hanxi Yang Xinping Ai Yuliang Cao 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(18)
LiV3O8 nanorods with controlled size are successfully synthesized using a nonionic triblock surfactant Pluronic‐F127 as the structure directing agent. X‐ray diffraction, scanning electron microscopy, and transmission electron microscopy techniques are used to characterize the samples. It is observed that the nanorods with a length of 4–8 µm and diameter of 0.5–1.0 µm distribute uniformly. The resultant LiV3O8 nanorods show much better performance as cathode materials in lithium‐ion batteries than normal LiV3O8 nanoparticles, which is associated with the their unique micro–nano‐like structure that can not only facilitate fast lithium ion transport, but also withstand erosion from electrolytes. The high discharge capacity (292.0 mAh g?1 at 100 mA g?1), high rate capability (138.4 mAh g?1 at 6.4 A g?1), and long lifespan (capacity retention of 80.5% after 500 cycles) suggest the potential use of LiV3O8 nanorods as alternative cathode materials for high‐power and long‐life lithium ion batteries. In particular, the synthetic strategy may open new routes toward the facile fabrication of nanostructured vanadium‐based compounds for energy storage applications. 相似文献
58.
Watchareeya Kaveevivitchai Ashfia Huq Shaofei Wang Min Je Park Arumugam Manthiram 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(34)
Rechargeable batteries based on an abundant metal such as aluminum with a three‐electron transfer per atom are promising for large‐scale electrochemical energy storage. Aluminum can be handled in air, thus offering superior safety, easy fabrication, and low cost. However, the development of Al‐ion batteries has been challenging due to the difficulties in identifying suitable cathode materials. This study presents the use of a highly open framework Mo2.5 + y VO9 + z as a cathode for Al‐ion batteries. The open‐tunnel oxide allows a facile diffusion of the guest species and provides sufficient redox centers to help redistribute the charge within the local host lattice during the multivalent‐ion insertion, thus leading to good rate capability with a specific capacity among the highest reported in the literature for Al‐based batteries. This study also presents the use of Mo2.5 + y VO9 + z as a model host to develop a novel ultrafast technique for chemical insertion of Al ions into host structures. The microwave‐assisted method employing diethylene glycol and aluminum diacetate (Al(OH)(C2H3O2)2) can be performed in air in as little as 30 min, which is far superior to the traditional chemical insertion techniques involving moisture‐sensitive organometallic reagents. The Al‐inserted Al x Mo2.5 + y VO9 + z obtained by the microwave‐assisted chemical insertion can be used in Al‐based rechargeable batteries. 相似文献
59.
60.
Silicon‐Sulfur Batteries: A Novel Lithiated Silicon–Sulfur Battery Exploiting an Optimized Solid‐Like Electrolyte to Enhance Safety and Cycle Life (Small 3/2017) 下载免费PDF全文