ZAS35锌合金/碳钢层状复合材料的制备

研究了经熔剂法预处理的碳钢热浸镀ZAS35锌合金工艺、ZAS35锌合金/碳钢双金属制作工艺及双金属界面特性.试验表明,采用700 ℃及10 min热浸镀法,铸型预热至500 ℃,ZAS35合金液浇注温度为700     

Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting

The design of highly efficient, stable, and noble‐metal‐free bifunctional electrocatalysts for overall water splitting is critical but challenging. Herein, a facile and controllable synthesis strategy for nickel–cobalt bimetal phosphide nanotubes as highly efficient electrocatalysts for overall water splitting via low‐temperature phosphorization from a bimetallic metal‐organic framework (MOF‐74) precursor is reported. By optimizing the molar ratio of Co/Ni atoms in MOF‐74, a series of Cox Niy P catalysts are synthesized, and the obtained Co4Ni1P has a rare form of nanotubes that possess similar morphology to the MOF precursor and exhibit perfect dispersal of the active sites. The nanotubes show remarkable hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) catalytic performance in an alkaline electrolyte, affording a current density of 10 mA cm^?2 at overpotentials of 129 mV for HER and 245 mV for OER, respectively. An electrolyzer with Co4Ni1P nanotubes as both the cathode and anode catalyst in alkaline solutions achieves a current density of 10 mA cm^?2 at a voltage of 1.59 V, which is comparable to the integrated Pt/C and RuO₂ counterparts and ranks among the best of the metal‐phosphide electrocatalysts reported to date.     

双标倒垂孔的施工与控制

介绍了目前比较成功的倒垂孔钻孔、钻孔偏斜、保护管安装、双金属标的埋设及安装等施工方法和控制措施。     

智能电表用磁保持继电器失效原因及机理分析

磁保持继电器是智能电表的核心部件之一,应具有高的可靠性、安全性及抗短路电流能力。本文针对智能电表用磁保持继电器的常见失效原因进行了分析。结果表明,触头表面污染引起磁保持继电器熔焊失效;复合铆钉触头开裂导致磁保持继电器熔焊失效或断开失效;在进行短路载流能力试验时,不合理的磁保持继电器结构引发爆炸;中间位置导致磁保持继电器出现断开失效。     

基于BS 7910的异种钢焊缝缺陷安全性评定及实验验证

介绍了BS7910-1999的平面缺陷的2种评定方法（1A和2A）;并用这2种方法对异种钢焊缝缺陷进行安全性评定。评定结果表明,8个具有焊接缺陷的节流孔板均通过了2A评定。同时进行了焊接件的疲劳和爆破实验。实验结果显示,疲劳试验并没使原有裂纹扩展,爆破压力与无缺陷管相当。BS7910—1999的评定结论和实验结果基本吻合。     

FeCoNiCrCu高熵合金涂层对复合铸造Al/Mg双金属组织和性能的影响

目的 研究不同厚度的Fe Co Ni Cr Cu高熵合金涂层对Al/Mg双金属组织和力学性能的影响。方法 通过超音速火焰喷涂工艺在A356嵌体表面喷涂不同厚度的FeCoNiCrCu高熵合金涂层,采用消失模复合铸造工艺制备Al/Mg双金属,利用扫描电镜、EDS能谱及XRD衍射仪、维氏硬度测试仪和万能试验机对Al/Mg双金属界面微观组织和力学性能进行测试和分析。结果 未喷涂高熵合金涂层的Al/Mg双金属界面由共晶层和金属间化合物层组成,断裂位置主要位于金属间化合物层,裂纹从Al₃Mg₂扩展至共晶层结束,具有典型的脆性断裂特征,剪切强度仅为30.37 MPa。当高熵合金涂层厚度为5μm时,Al/Mg双金属形成了Al₃Mg₂+Mg₂Si/AlxFeCoNiCrCu+FeCoNiCrCu+Al-Mg-Co-Ni混合相/δ-Mg+Al₁₂Mg₁₇共晶组织的复杂界面,断裂发生在高熵合金层与δ-Mg+Al₁₂Mg_17<...     

Mesoporous silica template-derived nickel-cobalt bimetallic catalyst for urea oxidation and its application in a direct urea/H2O2 fuel cell

Ni-based catalysts are considered as an efficient anode material for urea fuel cells due to the low cost and high activity in alkaline media. Herein, we demonstrate that Ni-Co bimetallic hydroxide particles with highly porous nanostructures can be synthesized using mesoporous silica nanoparticles as templates. The replicated nanostructures of the Ni-Co hydroxide samples from the mesoporous silica templates are observed. The porous Ni_0.8Co_0.2(OH)₂ particles exhibited considerably enhanced electro-catalytic activity for urea oxidation reaction by providing a high surface area and fast mass transport for urea oxidation reaction. It is also found that the Co-doping at 20% significantly reduce the overpotential and increase the peak current of urea oxidation reaction. A direct urea/H₂O₂ fuel cell with the porous Ni_0.8Co_0.2(OH)₂ as anode material shows an excellent performance with maximum power densities of 11.2 and 25.6 mW cm⁻² at 20 °C and 70 °C with 0.5 M urea in 5 M KOH, respectively. Thus, this work suggests that the highly porous Ni_0.8Co_0.2(OH)₂-derived from the mesoporous silica templates can be used for urea oxidation and as an efficient anode material for urea-based fuel cells.     

Effective buffer layer thickness of La-doped CeO2 for high durability and performance on La0.9Sr0.1Ga0.8Mg0.2O3-δ electrolyte supported type solid oxide fuel cells

Solid oxide fuel cells (SOFCs) have been gaining increased attention in the energy sector. Commonly, yttria-stabilized zirconia is widely employed as commercial electrolyte, however, resulted in drawbacks such as high-temperature operating and low conductivity which negatively affect the durability and efficiency. Thus there are many efforts to find high-ionic conductors. From the point of manufacturing, the major difficulty of LaGaO₃-based electrolyte as a high-ionic conductor is its incompatibility with commercial Ni-based anodes during high-temperature processes as well as operating. Several interlayers have been introduced to prevent the reaction between LaGaO₃-based electrolyte and Ni-based anode. In this study, we investigate the optimal thickness of the La-doped CeO₂ (LDC) interlayer by the screen-printing method using La_0.9Sr_0.1Ga_0.8Mg_0.2O_3-δ for the commercial electrolyte supported SOFCs. As a result, the superior power performance of 2.2 W·cm^?2 at 1123 K is achieved through the optimized LDC thickness of 20 μm through not lab-scaled but commercial ceramic manufacturing processing.     

负载镍、铜双金属催化剂的表征及催化性能

采用活性炭、α-Al_2O_3、硅胶和ZSM-5为载体,制备了负载镍、铜双金属催化剂.用SEM、XRD、XPS测示仪对反应前后的催化剂结构进行了表征.考察了所制备的催化剂在乙醇羰基化反应中的活性,提出了催化剂失活的原因.