A new colloidal precursor cooperative conversion route to nanocrystalline quaternary copper sulfide

A novel milk-like Cu-thiourea colloid has been synthesized. Nanocrystalline quaternary copper sulfide Cu₂FeSnS₄ was obtained through the Cu-thiourea colloidal precursor cooperative conversion route at low temperature. The samples were characterized by means of X-ray powder diffraction, transmission electron microscopy, scanning electron microscopy, inductively coupled plasma atomic emission spectroscopy, and X-ray energy dispersive spectroscopy techniques. The reaction details and features were described and discussed.     

The reaction of ceria coatings on mica with H2S: An in-situ X-ray diffraction study

Thin layers of ceria were deposited on the surface of mica platelets in solution. The reaction of such particles with hydrogen sulfide yields a red colored special effect pigment. The ceria layer reacts with H₂S to produce a variety of sulfide and oxysulfide phases. The reaction path discovered in situ by time and temperature resolved X-ray diffraction is CeO₂→CeS₂→C-Ce₂S₃→Ce₁₀S₁₄O. The reaction itself is extremely variable depending on gas flow, heating rates and decomposition atmospheres. Effects on the thin film are recorded by scanning electron microscopy (SEM) and revealed a destruction of the layer once red Ce₁₀S₁₄O was formed. The product layer then reveals the typical nonwetting behaviour of a liquid on a surface.     

A comparative study of the gas sensing behavior of nanostructured nickel ferrite synthesized by hydrothermal and reverse micelle techniques

A comparative study of gas sensing behavior of nanocrystalline nickel ferrite synthesized by micro-emulsion and hydrothermal method to liquefied petroleum gas (LPG) is presented. Nanocrystalline nickel ferrite synthesized by hydrothermal method indicated higher electrical conductivity and gas sensitivity at low operating temperature compared to nanocrystalline nickel ferrite synthesized by reverse micelle technique. This difference in the gas sensing behavior can be attributed to the presence of more oxygen vacancies (i.e. non-stoichiometry) in the hydrothermally synthesized nickel ferrite. Incorporation of palladium had a catalytic effect and the operating temperature was significantly reduced in both the samples. The higher operating temperature of the reverse micelle nickel ferrite material makes the sensor response speed faster (∼10 s) compared to the hydrothermally synthesized material (∼1 min).     

Electrical conductivity and gas sensitivity of Zn-Sb-O thick films

The thick film of Zn-Sb-O was prepared by coating the paste of nanoparticles mixture (Sb₂O₃:ZnO=1:3) on the alumina substrate, followed by sintering at 500-900 °C for 2 h in air. The electrical resistance and gas-sensing properties to benzene, alcohol and acetone of Zn-Sb-O films were found to be dependent on the change of phase structure caused by sintering temperature.     

阴离子型水性超分散剂的制备及其表征

根据超分散剂作用机理及结构设计原则，以马来酸酐、正丁醇、丙烯酸为原料，过硫酸铵为引发剂，通过先酯化后共聚的方法，制备出低相对分子质量的水溶性超分散剂。通过红外光谱（FT-IR）对聚合物的结构进行表征，运用乌氏黏度法测定其相对分子质量．用合成的超分散剂对纳米二氧化钛、纳米碳酸钙进行了分散稳定性的研究，发现该超分散剂能使纳米二氧化钛在水溶液中稳定分散1152h以上，使纳米碳酸钙悬浮液的黏度降低到接近水的黏度．该超分散剂能有效的分散超细粒子．     

The Influence of Ir and Pt Addition on the Synthesis of Fullerenes at Atmospheric Pressure

The addition of metallic Ir and Pt to a fullerene-forming, atmospheric-pressure plasma reactor was found to influence the generation of carbonaceous products. It was observed that the added metals were efficiently dispersed into the plasma and that their presence increased the yield of fullerenes. The addition of Ir led to a noticeable shift in the fullerene distribution towards C₆₀, whereas the addition of Pt increased the proportion of C₆₀ oxides and decreased the proportion of higher fullerenes. Addition of Ir also caused a reduction of the soot particle size and the formation of a considerable quantity of carbon nanotubes.     

L-抗坏血酸亚铁的合成及表征

研究了VeCO3的制备以及利用自制的FeCO3与L-抗坏血酸作用合成L-抗坏血酸亚铁.主要探讨了溶剂的用量、反应时间以及温度对产物收率和产品质量的影响.确定了最佳反应条件为:溶剂用量为20mL,时间为120min,反应温度为100℃,产率可达68.1%.并通过x射线能谱和红外吸收光谱等测试手段对产品进行了表征.     

利用铝（100）面隧道孔制备纳米模板及有序阵列材料

高纯铝箔通常通过电化学扩面后用作铝电解电容器的阳极材料。利用铝箔（100）面隧道孔制备纳米模板。这种纳米模板的特点是制作简单、模板面积大，纳米阵列材料形状可控性强。还利用两步电化学侵蚀铝箔的特殊工艺，研制出纵横交错的TiO2纳米有序阵列材料。     

Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

双三羟甲基丙烷的制备及应用研究进展

综述了双三羟甲基丙烷的合成法和回收法的特点,对比说明了蒸馏-结晶回收法和溶剂-结晶回收法的原理、条件和优缺点。对双三羟甲基丙烷应用进行了重点综述,从合成原理、应用配方和应用特点等方面详细介绍了各个领域中的具体应用情况。指出产品应用开发是今后双三羟甲基丙烷的主要研究方向,重点研究双三羟甲基丙烷的酯化物合成技术、应用配方,加快工业化进程,解决产品积压问题。