首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   35494篇
  免费   2433篇
  国内免费   1522篇
电工技术   517篇
技术理论   1篇
综合类   2378篇
化学工业   19414篇
金属工艺   1411篇
机械仪表   787篇
建筑科学   228篇
矿业工程   309篇
能源动力   669篇
轻工业   1355篇
水利工程   46篇
石油天然气   1858篇
武器工业   401篇
无线电   1913篇
一般工业技术   5265篇
冶金工业   688篇
原子能技术   157篇
自动化技术   2052篇
  2024年   81篇
  2023年   410篇
  2022年   566篇
  2021年   821篇
  2020年   766篇
  2019年   708篇
  2018年   744篇
  2017年   852篇
  2016年   1056篇
  2015年   1088篇
  2014年   1717篇
  2013年   1742篇
  2012年   2192篇
  2011年   2723篇
  2010年   2049篇
  2009年   2262篇
  2008年   1945篇
  2007年   2524篇
  2006年   2283篇
  2005年   2105篇
  2004年   1711篇
  2003年   1577篇
  2002年   1432篇
  2001年   1175篇
  2000年   1022篇
  1999年   816篇
  1998年   669篇
  1997年   468篇
  1996年   407篇
  1995年   330篇
  1994年   304篇
  1993年   231篇
  1992年   170篇
  1991年   117篇
  1990年   105篇
  1989年   56篇
  1988年   46篇
  1987年   31篇
  1986年   20篇
  1985年   19篇
  1984年   24篇
  1983年   13篇
  1982年   13篇
  1981年   12篇
  1980年   7篇
  1979年   15篇
  1978年   9篇
  1977年   5篇
  1975年   2篇
  1951年   6篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
The polymerization of α‐methylstyrene (AMS) catalyzed by Maghnite‐H+ (Mag‐H) was investigated. Mag‐H is a montmorillonite sheet silicate clay, exchanged with protons. It was found that the cationic polymerization of AMS is initiated by Mag‐H at ambient temperature in bulk and in solution. The effect of the amount of Mag‐H, the temperature, and the solvent was studied. The polymerization rate increased with increase in the temperature and the proportion of catalyst, and it was larger in nonpolar solvents. These results indicated the cationic nature of the polymerization. It may be suggested that the polymerization is initiated by proton addition to monomer from Mag‐H. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
82.
Electrochemical treatment processes can significantly contribute to the protection of the environment through the minimization of waste and toxic materials in effluents. From a pharmaceutical point of view and due to the existing resemblance between the electrochemical and biological reactions, it can be assumed that the oxidation mechanisms on the electrode and in the body share similar principles. In this paper, the application of electrochemical studies in the design of an environmentally friendly method was delineated for the new hydrocaffeic acid (HCA, 3,4-dihydroxy hydrocinnamic acid) derivatives synthesis at carbon electrodes in an undivided cell. In this cell, the EC mechanism reaction was involved, comprising two steps alternatively; (1) electrochemical oxidation and (2) chemical reaction. In particular, the electro-organic reactions of HCA, an important biological molecule, were studied in a water–acetonitrile (90:10 v/v) mixture in the presence of benzenesulfinic acid (3) and p-toluenesulfinic acid (4). The research included the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential electrolysis and product spectroscopic identification.  相似文献   
83.
Two series of semiflexible random thermotropic copolymers containing 8‐(3‐hydroxy phenyl) octanoic acid (HPOA) with either 3‐chloro‐4‐hydroxy benzoic acid or 3,5‐dibromo‐4‐hydroxy benzoic acid were prepared by melt polycondensation techniques. The copolyesters were characterized with Fourier transform infrared spectroscopy, dilute solution viscometry, hot‐stage polarized light microscopy, differential scanning calorimetry, thermogravimetric analysis, and wide‐angle X‐ray diffraction. Studies revealed that the amount of HPOA as a disruptor incorporated into the backbone of substituted 4‐hydroxy benzoic acids had a detrimental effect on the liquid‐crystalline behavior. Mesophase‐transition temperatures were observed between 210 and 250°C, and the optical textures were of typical nematic phases. The degree of crystallinity decreased with an increase in the HPOA content. The thermal stability of the copolymers was in the range of 310–370°C. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008  相似文献   
84.
Poly(3-n-octyloxythiophene), a conjugated polymer, which possessed solubility in common organic solvents, was synthesized by electrochemical polymerization in the presence of lithium perchlorate as the supporting electrolyte and sodium dodecyl sulfate as the surfactant in an aqueous medium. Characterizations of the intermediate, monomer, and polymer were performed by NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, and gel permeation chromatography. The process of electrochemical polymerization and the electrochemical redox behaviors were investigated by cyclic voltammetry and the potentiostatic method. A poly(3-n-octyloxythiophene) film that was deposited on a platinum electrode was found to exhibit electrochromic behaviors, and it switched electrochemically between blue–green oxidized and dark red reduced states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
85.
A series of polyurethane (PU) elastomers was prepared by the reaction of poly(?‐caprolactone) and 4,4′‐diphenylmethane diisocyanate, which was extended with a series of chain extenders (CEs) having 2–10 methylene units in their structure. The completion of the reaction was confirmed by Fourier transform infrared spectroscopy. The chemical structures of the synthesized PU samples were characterized with Fourier transform infrared, 1H‐NMR, and 13C‐NMR spectroscopy, and the thermal properties were determined by thermogravimetric analysis, DSC, and dynamic mechanical thermal analysis techniques. The mechanical properties were also studied and are discussed. The thermogravimetric analysis and DSC analysis showed that CE length had a considerable effect on the thermal properties of the prepared samples. The dynamic mechanical thermal analysis and damping peaks were also affected by the number of methylene units in the CE length. The elastomer extended with 1,2‐ethane diol exhibited optimum thermal properties, whereas the elastomer based on 1,10‐decane diol displayed the worst thermal properties. Tensile strength and elongation at break decreased with increasing CE length, whereas hardness showed the opposite trend. The glass‐transition temperature moved toward lower temperatures with increasing CE length. The decrease in the glass‐transition temperature and tensile properties were interpreted in terms of decreasing hard segments and increasing chain flexibility. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
86.
合成十二烷基葡萄糖苷的工艺条件   总被引:4,自引:0,他引:4  
采用对甲苯磺酸为催化剂 ,以D 葡萄糖和正十二醇为原料直接合成十二烷基糖苷 ,研究了工艺条件对反应速率、产物收率与色泽的影响。结果表明 ,催化剂用量对产物色泽无影响 ,适宜的工艺条件为 :正十二醇 /D 葡萄糖 (摩尔比 ) =4∶1,反应温度 110~ 12 0℃ ,反应时间 4h ,反应压力 4kPa ,搅拌速率大于 840r/min ,对甲苯磺酸 /D 葡萄糖 (摩尔比 ) =1.5 %,MgO为较好的中和剂。产物为乳白色 ,十二烷基糖苷总收率大于89%。  相似文献   
87.
胡四海  朱伯铨 《武钢技术》2003,41(6):17-21,28
以脱硅锆、轻烧氧化镁、消石灰为原料,进行了MgO-ZrO2-CaO系原料的合成,研究了化学组成(包括ZrO2含量、CaO/ZrO2比),烧成温度,杂质等对合成料性能和组织结构的影响。  相似文献   
88.
89.
90.
Simple and accurate closed‐form formulas obtained by using a differential evolution algorithm are presented for the synthesis of coplanar waveguides (CPW). The results of the synthesis formulas proposed in this article are compared with those of the quasi‐static analysis, the synthesis formulas reported by the other researchers and also the experimental works available in the literature. The accuracy of the proposed synthesis formulas is found to be better than 0.75% for 9256 CPWs samples. © 2008 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2008.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号