PS-b-PNIPAAm嵌段共聚物多孔薄膜的制备及形貌研究

将两亲性PS-b-PNIPAAm嵌段共聚物(BCP)溶解在四氢呋喃中配制成浓度为2%(质量分数)的溶液,旋涂后得到初生嵌段共聚物薄膜,以乙醇为退火溶剂退火后,探讨了退火时间对薄膜微孔结构的影响,结果表明,随着退火时间的延长,膜表面的微相分离越明显,微孔结构的分布更均匀。进一步将在乙醇中退火预处理的薄膜分别在乙醇或去离子水中进行溶胀处理,通过选择性溶胀成孔法制备PS-bPNIPAAm纳米多孔膜。研究了溶胀时间、温度及溶剂类型对薄膜形貌的影响,结果发现升高溶胀温度和延长溶胀时间均有助于膜表面微孔结构的形成,且该过程中乙醇的成孔作用比水的作用更为明显。     

金刚石的同质外延掺硼和Schottky特性

在＜１００＞取向的金刚石衬底上，用微波ＰＣＶＤ法进行同质外延，掺杂和Ｓｃｈｏｔｔｙ特性的实验研究，总结了反应气体，碳源浓度等因素对外延层形貌、结构的影响，Ｂ／Ｃ比对掺硼外延层结构、形貌和电学性能的影响，以及接触金属，温度对Ｓｃｈｏｔｔｋｙ特性的影响。     

纳米晶薄膜Li_xPb_(0.9-x)La_(0.1)TiO_3合成及离子电导特性

纳米晶薄膜LixPb0.9-xLa0.1TiO3（x=0，0．1，0．2，0．6）以普通玻璃为衬底通过溶胶—凝胶方法烧结制备而成。对LPLT薄膜进行DTA，XRD等测试手段分析。通过交流阻抗数据的分析，在室温下电导率高达2．3×10－3S·cm-1     

Application of Magnetron Sputtering in Fabricating MEMS Microbatteries

With the development of MEMS and the electronic devices's miniaturization and integration, a new kind of power sources that can satisfy the need for high energy density is required. Microbatteries are being researched abroad for their advantages of extreme thinness and long-term power supply. The development of MEMS microbatteries are reviewed and suggestedmagnetron sputtering in fabricating a high-performance microbattery. The technics as annealing are analyzed. The microbattery with a LiNi1-x Cox O2 cathode exhibited stable cycle ability and a high specific discharge capacity, which was attributed to the alloying effect of the LiNiO2and LiCoO2.     

Formation of structure of the CdTe film, recrystallized on Mo/glass substrate under high temperature and mechanical pressure

Large-grained and 7 μm thick CdTe film has been fabricated on top of Mo coated soda-lime glass substrate. As a new approach the dynamic recrystallization process (DRC) was used to form the structure of films. For the characterization of the structure and composition of the films a scanning electron microscopy (SEM), energy dispersive X-ray microanalysis (EDS) and X-ray diffraction (XRD) methods were used. The changes in the structure of films were studied in accordance with the process temperature, pressure and as-deposited film thickness. Significant changes in the CdTe film were observed after DRC of deposited films at the process temperatures between 450 °C and 550 °C. EDS quantitative analysis showed that during the recrystallization the Mo and CdTe films composition remained stable for all studied samples. The XRD results showed that the increase in the process temperature caused improvement in orientation of the films along direction of (111). The DRC temperature above 550 °C reduced the orientation again. The limits of the temperature and pressure in application of soda-lime glass in DRC were found and discussed.     

The Potential Role of SP-G as Surface Tension Regulator in Tear Film: From Molecular Simulations to Experimental Observations

The ocular surface is in constant interaction with the environment and with numerous pathogens. Therefore, complex mechanisms such as a stable tear film and local immune defense mechanisms are required to protect the eye. This study describes the detection, characterization, and putative role of surfactant protein G (SP-G/SFTA2) with respect to wound healing and surface activity. Bioinformatic, biochemical, and immunological methods were combined to elucidate the role of SP-G in tear film. The results show the presence of SP-G in ocular surface tissues and tear film (TF). Increased expression of SP-G was demonstrated in TF of patients with dry eye disease (DED). Addition of recombinant SP-G in combination with lipids led to an accelerated wound healing of human corneal cells as well as to a reduction of TF surface tension. Molecular modeling of TF suggest that SP-G may regulate tear film surface tension and improve its stability through specific interactions with lipids components of the tear film. In conclusion, SP-G is an ocular surface protein with putative wound healing properties that can also reduce the surface tension of the tear film.     

介质薄膜的透射光谱测量及其光学参数的分析

介绍介质薄膜透射光谱的测量以及基于分析薄膜透射光谱的计算薄膜光学参数的方法。对制备在玻璃基板上的二氧化钛、二氧化硅和氧化锌薄膜进行了可见光谱区的透射比测量，并用包络线方法和最优化方法对这些透明薄膜的光学参数进行了计算和分析。着重讨论了最优化方法在分析薄膜光学参数中的应用及其误差分析。此外，还对包络线方法和最优化方法进行了比较。     

魔芋葡甘聚糖抗菌复合膜的研制及其应用

以魔芋葡甘聚糖(Konjac Glucomannan,KGM)为基质,加入增塑剂、脂质、乳化剂、抗菌剂及生物抑制剂,在温度为50℃条件下干燥10 h,所制得的膜具有良好的阻湿阻气性能、可降解和抗菌性,有一定的强度.将该膜材料应用于龙眼保鲜上,效果优于普通聚乙烯薄膜袋.     

LF精炼炉三相电极的建模及仿真

针对LF钢包精炼炉三相电极调节器存在的问题,采用机理法推导得出了三相电极间的影响系数,并进行了仿真研究。本课题为“九·五”攻关课题。