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31.
The change in structure and adhesion strength of the interface by heating in air has been investigated for a plasma- sprayed
alumina coating on a ceramic substrate with a 50Ni- 50Cr alloy bond coating. A veined structure composed of NiO, NiCr
2O4, and NiAl2O4 oxides grew from the bond coating into cracks or pores in the top coating and the alumina substrate after heating at 1273
K for 20 h in air. The NiAl2O4 spinel may have formed by the oxidization of nickel, which subsequently reacted with the alumina coating or the substrate.
The mechanism of the penetration of the spinel oxides into the cracks or pores is not clear. The adhesion strength of the
coating is increased to about 15 MPa after heating at 1273 K for 20 h in air, compared to an as- sprayed coating strength
of only 1.5 MPa. 相似文献
32.
An iron electrode was modified by electrolytic reduction in deaerated acetonitrile solution of p-toluenediazonium tetrafluoroborate CH3C6H4N2BF4 (TDFB) or p-hydroxymethylbenzenediazonium tetrafluoroborate HOCH2C6H4N2BF4 (HOTDFB) below 10 °C to form a self-assembled monolayer (SAM) of toluene CH3C6H4- or hydroxymethylbenzene HOCH2C6H4- (HOMB) moiety, probably adsorbed on the electrode by the formation of a covalent bond between carbon and iron atoms, as shown in references. The protective ability of the layer was examined by polarization measurement of the electrode in an aerated 0.5 M NaCl solution. The protective efficiencies of these two SAMs were not high, around 30%, a little higher than that of the toluenethiol CH3C6H4SH SAM which was anchored on iron via a coordinate bond between sulfur and iron atoms. The iron surfaces modified with TDFB and HOTDFB were characterized by contact angle measurement, FTIR reflection spectroscopy and X-ray photoelectron spectroscopy. The persistence in protection of iron against corrosion by coverage with the HOMB SAM was confirmed by polarization measurements after immersion in 0.5 M NaCl for a long period of the time. 相似文献
33.
本文介绍了一种新型的操作工艺简单、耐水、耐热、耐酸碱溶液的环氧树脂结合剂的制备方法:结合剂采用环氧树脂和聚酰胺固化体系,并用液体端羧基丁腈橡胶(CTBN)对环氧树脂进行改性,在固化剂中添加改性固化利A提高固化物的耐热性。此树脂结合剂初始固化温度为3min,成型方便,是一种适于异形金刚石磨具使用的树脂结合剂C在150℃固化3h并在室温放置1天后,固化物具有高的硬度和耐热性以及优异的粘接性能,可以在150℃长期使用。 相似文献
34.
针对我国陶瓷高速砂轮特别是粗粒度高速砂轮回转强度不稳定的问题,本文主要对粘土—钾长石—硼玻璃、粘土—钾/钠长石—硼玻璃、粘土—钾长石—钙玻璃、粘土—钾长石—锂辉石等系统的结合剂进行研究。在现行的同一工艺条件下,用白刚玉WA46#磨料90%、陶瓷结合剂10%制备成磨具进行陶瓷结合剂的性能比较,对结合剂中不同成份对砂轮强度的影响进行了探讨,以找到一种既能满足现行生产工艺,又能提高粗粒度陶瓷高速砂轮回转强度的陶瓷结合剂。研究结果表明:在常用的粘土一钾长石~硼玻璃系统中引入钠长石,当钠长石达到适当比例(2l%),所制备的结合剂生产的陶瓷砂轮回转强度提高,且与现行生产工艺匹配,工艺性能稳定,有望成为改进陶瓷结合剂的一种新的途径。 相似文献
35.
Composition and microstructure characteristics in bond area of TIG welding for high strength ZA alloy 总被引:2,自引:0,他引:2
1 INTRODUCTIONZAalloyisfirstlyusedasthesubstituteofbronzeandbabbitalloyin 196 0s .Withthedevelopmentofsci enceandtechnology ,manynewZAalloyshavebeende velopedinrecentyears[1] .Theyarewidelyusedinsuchindustrialfieldsasmechanical,instrument ,lightindus try ,electr… 相似文献
36.
Ines Hofinger Jörg Möller Manfred Bobeth Karen Raab 《Journal of Thermal Spray Technology》2002,11(3):387-392
The adherence of plasma sprayed NiCrAlY bond coats can be improved by an appropriate substrate surface finish. The interface
fracture energy for crack propagation along the coating/substrate interface has been measured for different surface roughness
by means of a specially designed four-point bending test. An increase of the interface fracture energy of about 15% was observed
for a three times higher surface roughness. In addition, four-point bending tests with the coating on the side face of bending
specimens were performed to analyze the fracture and spalling behavior of the coatings both under large tensile and compressive
substrate deformations. 相似文献
37.
T.J. Nijdam 《Surface & coatings technology》2006,201(7):3894-3900
A combined pre-annealing and pre-oxidation treatment was developed for the processing of partially yttria stabilized (PYSZ) thermal barrier coatings (TBC) on top of NiCoCrAlY bond coatings (BC). To develop this pre-treatment, the influence of the oxygen potential during pre-annealing and pre-oxidation on the life span and failure mechanisms of the entire high temperature coating system upon thermal cycling was investigated. The results of this study showed that the service life of the coating system depended strongly on the composition and microstructure of the thermally grown oxide (TGO) after pre-oxidation. The longer life spans were obtained if the TGO thickened very slowly during thermal cycling due to a large α-Al2O3 grain size. Such a slow-growing TGO corresponded with a pre-treatment for which θ-Al2O3 was formed during pre-oxidation and for which the yttrium was located within a high density of pegs along the TGO/BC interface after pre-oxidation. If the yttrium was present on top of the TGO after pre-oxidation, a thick mixed alumina-zirconia layer formed upon thermal cycling. This mixed oxide layer contributed significantly to the total oxide layer thickness, resulting in short life spans. The formation of NiAl2O4 spinel in between the TBC and the α-Al2O3 should be avoided, since this can lead to premature failure along the spinel/α-Al2O3 interface. 相似文献
38.
利用Gleeble 3500热模拟实验机,在800~1100℃、10~90min和6-20MPa条件下对Ti3SiC2和Ni进行真空扩散连接。通过正交实验,研究了连接温度、连接压力和高温保温时间对试样连接强度的影响,优选出最佳工艺参数。结果表明,扩散连接工艺参数显著影响Ti3SiC2/Ni接头的剪切强度。在1000℃、10min和20MPa实验条件下,获得的Ti3SiC2/Ni接头的剪切强度达到(121±7)MPa,接近Ti3SiC2陶瓷的剪切强度。 相似文献
39.
研究了不同pH值和F-浓度人工唾液对钛/瓷结合性能的影响.将实验室制备的钛瓷粉分层烧结于钛片上,浸泡于37℃,pH2.7、pH7.0/F-100 μg·mL-1与pH2.7/F-100 μg·mL-1的人工唾液中,测量了浸泡7d和30d试件的三点弯曲结合强度,应用扫描电镜观察了瓷剥脱后钛表面的形貌,并进行了EDX分析.结果显示:pH2.7/F-100 μg·mL-1组试件的钛/瓷结合强度明显低于未浸泡组,其余各组与未浸泡组相比无显著差异.研究结果提示:酸性环境中,F-的存在可使钛/瓷结合强度降低,而酸性环境和低浓度的F-环境对钛/瓷结合强度则没有明显影响,口腔内有钛瓷修复体的患者应慎用含氟口腔产品. 相似文献
40.