Kinetics of oxygen absorption in aqueous sodium dithionite solutions

The absorption and reaction of oxygen in aqueous alkaline solutions of sodium dithionite has been experimentally investigated in a novel gas-liquid contactor. The novel gas-lift bubble column contactor was used to study the kinetics over wide ranges of reactant concentrations, temperature, and pH. The oxygen-sodium dithionite reaction was found to be first-order with respect to dithionite in the range of dithionite concentration < 0.1 M, and second-order in the range of dithionite concentration > 0.1 M. The reaction with respect to oxygen was found to be zero-order for all dithionite concentrations. These results and experimental investigations of the effect of solution alkalinity and temperature on the reaction rate are consistent with previous findings obtained in different gas-liquid contactors. The results thus confirm the feasibility of using the gas-lift bubble column for the kinetics of gas-liquid reactions.     

34CrMoV结构钢动态再结晶行为研究

应用Gleeble-1500热模拟实验机进行等温压缩试验,研究了变形工艺参数对34CrMoV结构钢动态再结晶行为的影响.结果表明,其流变应力随变形温度升高而降低,随应变速率提高而增大;随着应变速率的降低,应变量的增加和变形温度的升高,动态再结晶速度加快且奥氏体晶粒得到细化.     

A Study of Surface Deformation during Wire‐Rod Rolling of High Speed Steels using Experimental and Computational Techniques

The evolution of surface defects during shape rolling of high‐speed steel billets is studied using longitudinal surface defects prepared by machining and welding. The reduction of the defects during rolling in a production mill is compared to the total area reduction of the billets. Samples are collected after pass 4, 6, 8, 14, 19 and the final pass, 28, representing the finished 5.5mm wire. By inspecting the cross sections, the rotation of the billets from pass to pass is evaluated. Results from FE simulations on solid billets are compared to the experimental results. Generally, simulations predict less reduction than observed experimentally. In most cases cracks reduce most effectively followed by carbon steel welds and stainless steel welds.     

碳钢高温变形后的静态软化行为

在形变温度为1133K、形变速率为2×10~(-3)s~(-1)的试验条件下,采用两段加载拉伸试验方法研究了0.4%C-1.5%Mn钢高温变形后的静态软化行为.调查了由两次加载拉伸变形时的屈服应力求得的静态软化率以及相对峰值应力比和峰值应变比随等温保持时间的变化.详细讨论了动态回复组织和动态再结晶组织对高温变形后的静态软化过程的影响.     

Cyclic X-Y mechanical tests: A new method to perform in situ reversed-deformation experiments in the high-voltage electron microscope

There has been, in the past, only limited success with in situ cyclic or reversed plastic deformation tests in the transmission electron microscope (TEM). This is probably partly due to problems associated with buckling of the foil when an applied tensile or shear stress is reversed. Mechanical analysis shows that dislocation movement can be reversed by tensile stressing in alternating perpendicular directions (i.e., 90° rotations of a tensile stress); thus buckling of the foil can be avoided. A design for performing such X-Y in situ TEM tests is presented, with observations that demonstrate its feasibility.     

黄泛区公路地基压实标准的研究

采用有限差分的计算方法，分析了黄泛区公路地基在不同压实度和压实深度条件下的沉降规律，提出了地基的压实标准和处置技术措施．研究认为，对高度〈6m的路基，保证90％的压实度对减少路基的工后沉降变形至关重要．对高度〉6m的路基，提高地基压实度，特别是将压实度由90％提高到93％，对降低地基沉降的作用不大．加大地基的压实深度，与提高压实度表现出相似的规律性，但对降低地基沉降的效果更明显．应根据路基高度提出地基的压实控制标准．路基高度≤2m，地基表层30压实度应≥93％；路基高度2～6m，地基表层30压实度应≥90％；路基高度〉6m，地基表层30压实度应〉185％．指出采用强夯、冲击碾压实地基，是黄泛区经济有效的工程技术措施．     

The intervalley X6→Γ6, L6 scattering time in GaAs measured by ultrafast pump-probe infrared absorption spectroscopy

A direct measurement of the dynamics of electrons in the X₆ valley for a GaAs crystal by time-resolved absorption spectroscopy is reported for the first time. IR picosecond probe pulses were used to monitor the growth and decay of the population in the X₆ valley subsequent to excitation by a 527 nm pump pulse. The intervalley X₆→Γ₆, L₆ scattering time t_x of 0.70 ± 0.50 ps is determined and the crossection for the X₆→X₇ transition is estimated to be 1.8 × 10⁻¹⁶ cm².     

现浇混凝土构件与砌体接触面收缩和温度应力裂纹的探讨

分析讨论了建筑物由于收缩及温度应力而引起的过纹，提出了在设计施工中应考虑的问题和采取的防止措施。     

GCr15控制轧制新工艺的模拟研究

用热扭转试验机，实现了热变形模拟轴承钢控制轧制工艺。研究了形变过程中所发生的静态和动态软化过程，观察了形变后的组织，证实在生产过程中实现的可能性，为在生产中推广使用提供了科学依据。     

表面微观屈服应力与表面变形研究

本文对表面微观屈服应力的测量与计算方法及表面变形的应变曲线进行了分析研究。结果表明，表面微观屈服应力与加载方式有关；表面变形的应力应变曲线具有双线性特征。