Liquid Radial Dispersion in Liquid-solid Circulating Fluidized Beds with Viscous Liquid Medium

Liquid dispersion in the radial direction was investigated in the riser of a viscous liquid-solid fluidized bed 0.102 m in diameter and 3.5 m in height. Pressure fluctuations in the riser were also measured and analyzed to examine the behavior of fluidized particles. Effects of liquid velocity (0.15-0.45 m/s), solid circulation rate (2-8 kg/m²s), particle size (1-3 mm), and liquid viscosity (0.96-38 mPas) on pressure fluctuations and the liquid radial dispersion coefficient were determined. The infinite space model was employed to obtain the radial dispersion coefficient from the radial concentration profiles of the tracer. The pressure fluctuations were analyzed by means of autocorrelation coefficient as well as power spectral density function. The dominant frequency obtained from the autocorrelation coefficient or power spectral density function of pressure fluctuations decreases with increasing liquid viscosity or liquid velocity, but it increases with increasing particle size. The liquid radial dispersion coefficient decreases with increasing liquid velocity or viscosity, but it increases as the solid circulation rate or particle size increases. The liquid radial dispersion coefficient is related closely to the resultant behavior of fluidized particles. The radial dispersion coefficient has been well correlated with operating variables in terms of dimensionless groups.     

鼓泡床内气泡-液体两相湍流代数应力模型的数值模拟

现有的气泡 -液体两相流动的数值模拟中 ,或者不考虑湍流 ,或者仅仅考虑液体湍流 ,但是直接模拟和PIV测量结果都表明气泡由于尾迹的作用有强烈的湍流脉动 .本文首次推导和封闭了同时模拟气泡湍流脉动和液体湍流脉动的二阶矩输运方程两相湍流模型 ,并在此基础上建立了代数应力气泡 -液体两相湍流模型 .用代数应力模型模拟了二维矩形断面鼓泡床内气泡 -液体两相流动 .预报结果给出了气泡和液体两相速度场、两相Reynolds应力及湍动能分布和气泡体积分数分布 .模拟结果与PIV测量结果符合很好 ,表明了模型的合理性 .研究结果表明 ,原先静止的液体在气泡因浮力而产生的上升运动的作用下产生回流流动 ,而气泡则只有上升运动 .气泡速度始终大于液体速度 .在床内气泡湍流脉动确实始终很强烈 .液体则由于气泡的作用以及自身速度梯度产生的双重作用而发生湍流脉动 .气泡的脉动显著地大于液体的脉动 .两相湍流脉动都是各向异性的 ,而且气泡湍流脉动的各向异性比液体的更强烈     

Settling velocities of particles in bubbly gas-liquid mixtures

The axial dispersion-sedimentation model is commonly used to describe the axial concentrations of solids in three phase bubble columns at low liquid velocities. When the two parameters of this model, the particle settling velocity and the solids axial dispersion coefficient, are uncoupled by the use of various assumptions, physically unrealistic values of these parameters often result. Direct experimental measurements of solids settling rates in bubbly gas-liquid mixtures were carried out. The measured mean settling velocities decreased slightly with gas flow rate and were equal to or slightly less than the single particle free settling velocity in the liquid alone. Solids axial dispersion coefficients were also obtained from the solids settling rate distribution data, and gave values considerably less than the experimental liquid axial dispersion coefficient.     

用CCD摄像法测量下喷环流反应器内的气泡行为

本文开发了一种集高速视频分析系统和计算机数字图像处理技术于一体的具有普适性的动态高速ＣＣＤ摄像系统，并利用该系统测定了两相三维下喷环流反应气内的环境气泡行为，考察了不同喷咀和操作条件对气泡行为及平均传质比表面积的影响。     

Effect of agitation in the hydrogenation of castor oil

Castor oil was hydrogenated to evaluate the effect of agitation during hydrogenation. The turbine and propeller impellers were evaluated during hydrogenation of castor oil at various temperatures, pressures, and catalyst concentrations. The effect of impeller position in the agitator at definite oil depth was also evaluated. Hydrogenation of castor oil at 130°C, 2.0 kg/cm² hydrogen gas pressure with 0.5% Ni catalyst for 6 h while using two turbine impellers fitted in an agitator, one close to the reactor bottom and another at a height just below the top oil layer, revolving at 350 rpm, resulted in a product of a iodine value of 4.1, hydroxyl value of 156.4, and slip point of 84°C.     

高矣物的特性对双水相相图和头孢氨苄及7-ADCA分配行为的影响

A series of ethylene oxide(EO)-propylene oxide (PO) random co-polymers (EOPO) were used to form aqueous two-phase systems (ATPS) with ammonium sulfate.Effects of EOPO′s properties on the phase separation behaviors and on the partition of cephalexin and 7-aminodesacetoxicephalosporanic acid(7-ADCA) in ATPS were investigated.Both the molar mass and molar ratio of EO to PO of EOPO could greatly influence partition behaviors of cephalexin and 7-ADCA as well as the binodal curve of ATPS. With the increase of molar mass of co-polymer or the decrease of molar ratio of EO to PO,the critical point of ATPS decreased,the binodal curve became more asymmetry,and both cephalexin and 7-ADCA followed the same tendency to partition into the polymer-poor bottom phase.The experimental results shows that it is feasible to partition cephalexin and 7-ADCA in either the polymer-rich top phase or the polymer-poor bottom phase by choosing a specific phase-forming EOPO.     

Heat transfer of gas flow through a packed bed

This paper reports an experimental study of both the transient and steady-state heat transfer behaviour of a gas flowing through a packed bed under the constant wall temperature conditions. Effective thermal conductivities and convective heat transfer coefficient are derived based on the steady-state measurements and the two-dimensional axial dispersion plug flow (2DADPF) model. The results reveal a large temperature drop at the wall region and the temperature drop depends on the axial distance from the inlet. The 2DADPF model predicts the axial temperature distribution fairly well, but the prediction is poor for the radial temperature distribution. Length-dependent behaviour of the effective heat transfer parameters and non-uniform flow behaviour are proposed to be responsible. A comparison with previously published correlations and data in the literature shows that the relationships proposed by Bunnell et al. and Demirel et al. agree well with the measured effective radial thermal conductivity, whereas the wall-fluid heat transfer coefficient is better represented by the Li-Finlayson correlation.     

气体压强对非晶InGaAs薄膜光学常数的影响

论述一种用透射谱包络线法计算非晶薄膜的折射率、消光系数和光学带隙的方法。通过正交实验确定除压强之外的工艺参数,研究压强的改变对薄膜主要光学常数的影响,运用最小二乘法、内插值法在matlab编程基础上,拟合出光学常数曲线,借由观察曲线的特点,分析在低工作气压下,气压的改变对光学常数的影响。     

蜂窝式构件长细比的计算方法

为了进一步研究蜂窝构件稳定承载性能,以现有长细比计算理论为基础,结合蜂窝构件的受力机理和界面特性,提出了蜂窝构件长细比计算中相关参数的计算方法．同时,结合理论推导和数值分析结果,提出了蜂窝构件换算长细比建议计算公式．