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61.
Marianne?Bitar Salwa?Karboune Barbara?Bisakowski Selim?KermashaEmail author 《Journal of the American Oil Chemists' Society》2004,81(10):927-932
Chlorophyllase catalyzes the bioconversion of chlorophyll into chlorophyllide by replacing the phytol group with a hydrogen
atom. There is an increased interest in the biotechnological application of chlorophyllase for the removal of green pigments
from edible oil and its potential as an alternative to the use of the conventional bleaching technique. Partially purified
chlorophyllase, obtained from the alga Phaeodactylum tricornutum, was assayed for its hydrolytic activity in an aqueous/miscible organic solvent system containing refined-bleached-deodorized
(RBD) canola oil, using chlorophyll and pheophytin as substrate models. The results indicated that chlorophyllase biocatalysis
could be successfully carried out in an aqueous/miscible organic system containing RBD canola oil. The presence of 20% RBD
canola oil decreased the hydrolytic activity of chlorophyllase by 2.2 and 6.7 times, using chlorophyll and pheophytin as substrates,
respectively. In addition, acetone acted as an activator of chlorophyllase activity at low concentrations and an inhibitor
at higher ones. The optimal reaction conditions for chlorophyllase biocatalysis in the aqueous/miscible organic system were
determined to consist of 20% RBD oil and 10% acetone at a 200 rpm agitation speed and at a temperature and substrate concentration
of 35°C and 12.6 μM for chlorophyll, and 30°C and 9.3 μM for pheophytin. 相似文献
62.
Xiaojun Hu James K. Daun Rachel Scarth 《Journal of the American Oil Chemists' Society》1993,70(5):535-537
Turbidity components in refined canola oils were collected by filtration at 4 and 20°C. Major components (thin-layer chromatography)
at both temperatures were wax esters (WE), hydrocarbons (HC) and triacylglycerols (TG) while free fatty acids (FFA) and fatty
alcohols (FAL) were found in minor amounts at 4°C. WE had carbon numbers of 40 to 56 (made up of combinations of C16 to C30
alcohols and C16 to C28 fatty acids). HC were mostly C29 and C31 with lesser amounts of C24, C28 and C32. TG, compared to
the corresponding liquid oil, still contained C18:1 as the major component, but had less C18:2 and particularly less C18:3
and at least two times higher levels of saturated fatty acids. The FFA were mainly long-chain C22:0, C24:0 and C20:0 (in order
of amount). FAL were mainly long-chain C26:0, C28:0 and C30:0 but ranged from C16:0 to C32:0.
Presented in part at the 1991 American Oil Chemists’ Society Annual Meeting and Exposition, Chicago, May 15. Received Outstanding
Paper Award 1991, Chicago (82nd) Annual Meeting. 相似文献
63.
Mohammed Al‐Khusaibi Michael H. Gordon Julie A. Lovegrove Keshavan Niranjan 《International Journal of Food Science & Technology》2012,47(8):1701-1709
The changes occurring in the levels of nutritionally relevant oil components were assessed during repeated frying of potato chips in a blend of palm olein and canola oil (1:1 w/w). The blend suffered minimal reductions in omega‐3 and omega‐6 polyunsaturated fatty acids. There was no significant difference between the fatty acid composition of the oil extracted from the product and that of the frying medium, in all three cases. The blend also contained a significant amount of tocols which add a nutritional value to the oil. The concentration of the tocols was satisfactorily retained over the period of oil usage, in contrast to the significant loses observed in the case of the individual oils. The blend also performed well when assessed by changes in total polar compounds, free fatty acids, p‐anisidine value. When fried in used oil, the product oil content increased progressively with oil usage time. This study shows that blended frying oils can combine good stability and nutritional quality. 相似文献
64.
D. M. Chapman 《Journal of the American Oil Chemists' Society》1994,71(4):397-400
Silica hydrogels acidified with strong mineral acids, such as sulfuric acid, are highly effective chlorophyll and phospholipid
adsorbents relative to traditional acid-activated bleaching earth (ABE), but they are not effective β-carotene adsorbents.
When an acidified silica is used as the only bleaching agent, sulfuric acid leaches into the oil, and after deodorization,
Tintometer red and yellow (R/Y) numbers are higher than those for ABE-bleached and deodorized oils. The fixed R/Y colors do
not arise solely from the decomposition of β-carotene during deodorization. Sequential treatments of canola oils with sulfuric
acid/silica and ABE can be performed to overcome all of the drawbacks associated with sulfuric acid/silica treatment alone,
such that finished oils can be produced by lower overall adsorbent dosages. 相似文献
65.
Ryszard Amarowicz Fereidoon Shahidi 《Journal of the American Oil Chemists' Society》1994,71(5):551-552
The compound 1-O-β-D glucopyranosyl sinapate (GPS), a phenolic glycoside, was separated from ethanolic extracts of defatted canola meal by
a two-step chromatographic method. The first step involved Sephadex LH-20 chromatography with methanol as the eluting solvent.
The solvent from the fraction containing GPS was evaporated, and glucopyranosyl sinapate was subsequently separated by a semi-preparative
high-performance liquid chromatography method with an RP-18 column and a mobile phase consisting of water/acetonitrile/acetic
acid (88∶10∶2, vol/vol/vol). 相似文献
66.
Assessment of lipase- and chemically catalyzed lipid modification strategies for the production of structured lipids 总被引:5,自引:0,他引:5
Wendy M. Willis Alejandro G. Marangoni 《Journal of the American Oil Chemists' Society》1999,76(4):443-450
The purpose of the present study was to devise a two-step reaction to produce partial glycerides, which would subsequently be used as substrates in both lipase-catalyzed and chemically catalyzed esterification reactions with caprylic acid. The yields and kinetics of these two-step reactions were compared to established lipase-catalyzed acidolysis and transesterification as well as to chemical transesterification reactions. Acyl migration did not occur during the hydrolysis or short-path distillation steps in the preparation of free fatty acid-free partial glycerides for esterification reactions. No significant differences in final yields (59.9% to 82.8% w/w of total triacylglycerols) of new structured lipids were detected among lipase-catalyzed (24 h) and chemically catalyzed (5 h) reactions; however, the yield of new structured triacylglycerols (TAG) after 2 h was lower for acidolysis than for the other lipase-catalyzed reactions (P≤0.05). Since no differences in final yields were detected among the reactions, chemical esterification using hydrolyzed oil could represent the best synthetic option, since it offers the advantage of positional distribution control associated with lipase-catalyzed reactions as well as rapid reaction times associated with chemically catalyzed reactions. Attempts to evaluate the positional distribution of caprylic acid using allyl magnesium bromide (Grignard reagent) were hampered by production of unknown species, which prevented accurate determination of the concentration of some key fatty acids. 相似文献
67.
Wright CF von Keyserlingk MA Swift ML Fisher LJ Shelford JA Dinn NE 《Journal of dairy science》2005,88(1):238-243
This experiment used 18 lactating Holstein cows in a 3 x 3 Latin square replicated 6 times to determine the effectiveness of processing with moist heat or moist heat combined with lignosulfonate (LSO3) for increasing the ruminal undegradable fraction of canola meal for use as a protein supplement for lactating dairy cows. Diets were formulated to be isonitrogenous and contained one of 3 forms of canola meal; untreated canola meal (UCM), heat-treated canola meal (HTCM) or heat-and LSO3-treated canola meal (LSO3CM). Total collection of urine and feces was taken from each cow during the last 5 d of each 42-d experimental period. Milk production was greater for cows fed the LSO3CM diet (36.6 kg/d) than for cows fed the UCM diet (34.8 kg/d) but did not differ from cows fed the HTCM diet (35.3 kg/d). Digestibility of crude protein was lower for cows supplemented with LSO3CM and they had reduced concentrations of ruminal ammonia N, blood urea N, and milk urea N compared with cows supplemented with UCM or HTCM. Dry matter intake and apparent digestibilities of neutral and acid detergent fiber were increased in cows fed the LSO3CM diet. Urinary N excretion (as % of N intake) was reduced in cows fed the LSO3CM diet. These results indicate that moist heat combined with LSO3 treatment of canola meal was effective in increasing the proportion of crude protein digested in the lower digestive tract of lactating cows and was therefore used more effectively as a source of protein than UCM or HTCM. 相似文献
68.
K.A. Christen D.J. Schingoethe K.F. Kalscheur K.K. Karges 《Journal of dairy science》2010,93(5):2095-2104
This study compared high protein dried distillers grains (HPDDG) with soybean meal (SBM), canola meal (CM), and dried distillers grains with solubles (DDGS) as protein supplements in dairy diets. A lactation trial used 12 multiparous cows averaging 78 d in milk at the start of the experiment in a 4 × 4 Latin square design with 28-d periods. Weeks 1 and 2 of each period were used for adjustment and wk 3 and 4 for data collection. Each treatment diet consisted of 55% forage and one of the 4 protein supplements in a concentrate mix. Total mixed diets averaged 15.3% crude protein, with 38% of the protein from one of the 4 protein supplements. Dry matter intake (24.4 kg/d) and crude protein intake (3.57 kg/d) were similar for all 4 diets. Milk production (31.8 kg/d), protein yield (1.05 kg/d), fat yield (1.29 kg/d), and protein percentage (3.31) were similar for all 4 treatment diets. Milk fat percentage was lower when fed DDGS (3.78) than when fed SBM or HPDDG (4.21), but similar with CM (4.07). Feed efficiency (1.44 kg of energy-corrected milk/kg of dry matter intake) and nitrogen efficiency (0.29) were not affected by diet. Total milk nitrogen and true milk protein were highest when fed the HPDDG diet. Molar proportions of acetate, propionate, and the acetate to propionate ratio in ruminal contents and ruminal ammonia concentrations were similar for all diets. Arterial and venous concentrations of total essential AA tended to be lower when fed CM, reflecting lower concentrations of His, Ile, Leu, and Val when fed the CM diet. Extraction efficiency of AA from blood by the mammary gland indicated that Met was the first limiting AA when fed the SBM diet, whereas Lys was first limiting for the other diets. Phenylalanine was third limiting with all diets. Feeding HPDDG was equally as effective as feeding SBM, CM, and regular distillers grains as a protein supplement for lactating cows. 相似文献
69.
K. Lacki Z. Duvnjak 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1996,65(3):211-220
Transformation of 3,5-dimethoxy-4-hydroxy cinnamic acid (sinapic acid), sinapaldehyde, sinapine and sinapoyl in the model system containing an enzyme secreted by the fungus Trametes versicolor was investigated. The affinity of this enzyme was highest for sinapic acid followed by sinapaldehyde and sinapine. The optimum temperature and pH for these transformations were 50°C and pH 3·3, 50°C and pH 4·5, 60°C and pH 4·0 for sinapaldehyde, sinapine, and sinapic acid, respectively. The apparent heat of the enzyme-sinapic acid complex formation is −2557·6 J mol−1. Higher concentrations of sinapine and sinapic acid caused enzyme inhibition. When canola meal was treated with this enzyme the phenolics content in this commodity was decreased by 90%. 相似文献
70.
油菜籽及其饼粕中硫代葡萄糖苷总量快速测定方法的研究 总被引:5,自引:1,他引:5
本研究对油菜籽及其饼粕中硫代葡萄糖苷总量的检测方法进行了研究和试验,将葡萄糖释放——酶鉴定法作为快速检测的首选方法。在试验中发现了葡萄糖释放——酶鉴定法和硫酸根离子沉淀法检测结果之间呈线性相关并建立了线性方程,对这两种方法的适用性进行了比较。 相似文献