全文获取类型
收费全文 | 3365篇 |
免费 | 167篇 |
国内免费 | 275篇 |
专业分类
电工技术 | 69篇 |
综合类 | 160篇 |
化学工业 | 1050篇 |
金属工艺 | 1161篇 |
机械仪表 | 51篇 |
建筑科学 | 78篇 |
矿业工程 | 58篇 |
能源动力 | 102篇 |
轻工业 | 9篇 |
水利工程 | 13篇 |
石油天然气 | 147篇 |
武器工业 | 7篇 |
无线电 | 113篇 |
一般工业技术 | 566篇 |
冶金工业 | 175篇 |
原子能技术 | 27篇 |
自动化技术 | 21篇 |
出版年
2024年 | 13篇 |
2023年 | 47篇 |
2022年 | 67篇 |
2021年 | 84篇 |
2020年 | 105篇 |
2019年 | 94篇 |
2018年 | 77篇 |
2017年 | 123篇 |
2016年 | 133篇 |
2015年 | 104篇 |
2014年 | 130篇 |
2013年 | 196篇 |
2012年 | 199篇 |
2011年 | 254篇 |
2010年 | 199篇 |
2009年 | 212篇 |
2008年 | 178篇 |
2007年 | 222篇 |
2006年 | 249篇 |
2005年 | 201篇 |
2004年 | 199篇 |
2003年 | 132篇 |
2002年 | 102篇 |
2001年 | 90篇 |
2000年 | 66篇 |
1999年 | 81篇 |
1998年 | 64篇 |
1997年 | 43篇 |
1996年 | 32篇 |
1995年 | 24篇 |
1994年 | 26篇 |
1993年 | 14篇 |
1992年 | 13篇 |
1991年 | 12篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1974年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有3807条查询结果,搜索用时 15 毫秒
11.
Jaspreet S. Gandhi William J. van Ooij 《Journal of Materials Engineering and Performance》2004,13(4):475-480
Organofunctional silanes recently have emerged as outstanding, environmentally friendly corrosion protectors for metal substrates,
compared with conventional chromate treatments. A simple immersion technique is typically used to coat the metal surface with
silane films. However, the thickness and uniformity of the films are uncontrolled in this process. This paper proposes a new
deposition technique for the silane films on the metal surface, i.e., by electrodeposition. Hydrolyzed silanes are water-soluble,
ionized molecules, so they can be deposited on metals by electrodeposition. Various combinations of silane mixtures were tested
at different voltages, pH values, bath concentrations, and exposure times on panels of alloy aluminum and mirror-polished
ferro-plate. The surface structure was characterized by scanning electron microscopy (SEM) and ellipsometry. The resistance
of the film to corrosion was investigated by direct current (DC) polarization and electrochemical impedance spectroscopy (EIS)
techniques. Electrodeposition results in a more organized and uniform film with fewer pores, compared with immersed or dipped
films.
This paper was presented at the 2nd International Surface Engineering Congress sponsored by ASM International, on September
15–17, 2003, in Indianapolis, Indiana, and appears on pp. 320–26 of the Proceedings. 相似文献
12.
碱性电镀光亮锌镍合金研究 总被引:3,自引:1,他引:3
研究了镀液的组成与镀层中镍含量、镀层的相结构以及阴极电流效率的关系。提出了碱性电镀光亮锌镍合金的最佳镀液组成和工艺规范,并对茴香醛、四乙烯五胺和ZN—A5添加剂的吸附行为及其对锌镍电沉积过程的阻化作用进行了探讨。 相似文献
13.
土壤中阴离子对碳钢腐蚀的影响 总被引:2,自引:0,他引:2
应用弱极化曲线技术和交流阻抗谱研究了土壤中C1-、SO4^2-、CO3^2-、NO3-离子对碳钢腐蚀的影响。结果表明:阴离子对碳钢腐蚀的影响是显著的。当土壤中分别添加Cl-、CO3^2-、NO3-离子时,随着阴离子含量的增大,碳钢的腐蚀速率增大,在某一离子含量时,腐蚀速率达到最大,然后腐蚀速率随着离子含量的增加而减小。在含SO4^2-离子的土壤中随着SO4^2-离子含量的增大,土壤中碳钢的腐蚀速率增大。在有四种阴离子土壤中,阻抗谱均为单容抗弧,且大都在低频区出现扩散弧。 相似文献
14.
NICKEL ELECTROPLATING has been practicallyused for decades.There is an unknown part in theplating,although this is easy to plate.Applications ofthe plating are described from the practical viewpoint.Purpose of Nickel Electroplating(1)Decorative,and corrosion resistanceNickel electroplating is deposited on iron,cupper,zinc and aluminum substrate etc.,and chromiumplating is usually deposited on nickel plating.Hexavalent chromium plating has an important effecton the corrosion resisitan… 相似文献
15.
采用电化学恒电位沉积方法在ITO导电玻璃上和在ZnO薄膜上沉积氧化亚铜(Cu2O),并通过X射线衍射(XRD)和扫描电镜(SEM)对晶体的微观结构和表面形貌进行了分析.在ZnO基底上沉积得到了纳米级的Cu2O粒子并且具有明显择优取向,而在ITO导电玻璃上仅得到粒径为2—5胛的Cu2O粒子,没有明显的择优取向,对薄膜的生长机理进行了讨论. 相似文献
16.
Tin electrodeposition in its initial stages in acid sulfate/gluconate baths was studied with varying tin and gluconate concentrations using potential-controlled electrochemical techniques. The deposit morphology was observed by scanning electron microscopy (SEM). A comparison with tin electrodeposition from acid sulfate baths in the absence of gluconate was also carried out. Use of a highly acidic bath leads to nonuniform deposits, even in the presence of gluconate; at pH 4 deposits are uniform, brilliant and suitable for finishing applications. Tin crystallites have a well defined morphology which depends on bath agitation conditions. In the absence of agitation, the crystallites have the same tetragonal shape as in a sulfate bath without gluconate. 相似文献
17.
T. Ohgai I. Enculescu C. Zet L. Westerberg K. Hjort R. Spohr R. Neumann 《Journal of Applied Electrochemistry》2006,36(10):1157-1162
Polycarbonate templates of (30±1) μm thickness containing cylindrical etched-track nanochannels of (500±50) nm diameter were used for electrodeposition of Ni nanowires. Using 104 channels per cm2, the most favourable deposition potential of − 1.0 V was determined in a potentiostatic mode by varying the deposition potential with respect to an Ag/AgCl reference electrode over a range between − 0.1 V and − 1.5 V. The deposition efficiency at − 1.0 V was estimated around 10%. The resulting single wires had a resistance around 200 Ω and showed an anisotropic magnetoresistance (AMR) effect of 1%, applicable to directionally sensitive magnetic field sensors. 相似文献
18.
Nickel electrodes were prepared by electrodeposition in electrolytes of various anionic compositions. The deposition conditions and bath types were evaluated with special emphasis on the electrocatalytic properties for the oxygen evolution reaction (OER). Electrochemical characterizations in a 5 mol/L KOH solution at 25°C showed that the electrode deposited from the chloride bath, having a low Tafel slope of 50 mV/dec and an overpotential of 396 mV at 100 mA/cm2, is the most catalytically active among electrodes prepared in electrolytes of various anionic compositions. The electrode activity for the OER is related to the real surface areas, which depend on the anion compositions in the deposition bath and the deposition conditions. 相似文献
19.
Tz. Boiadjieva D. Kovacheva K. Petrov S. Hardcastle A. Sklyarov M. Monev 《Journal of Applied Electrochemistry》2004,34(3):315-321
The effect of polyethylene glycol (PEG 1500) as additive and of deposition conditions on Zn—Cr alloy electrodeposition from an acidic sulfate electrolyte at room temperature, without agitation was investigated. PEG polarizes the overall cathodic reaction and inhibits Zn deposition. Cr codeposition with Zn starts at a cathodic potential of about –1,95 V vs Hg/Hg2SO4, which is reached at current density of about 20 A dm–2 in galvanostatic conditions. Zn—Cr alloy coatings containing up to 28 at % Cr were obtained depending on the plating conditions. SEM observations showed an island-like structure, formed by the local growth of crystals, which covered the surface during further deposition. In the first stages of electrodeposition the powder diffraction spectra contain lines of b.c.c. -(Zn,Cr) phase (a
3.02 Å). After 30 s deposition time weak lines of Zn-based phase (a
2.67 Å, c
4.90 Å) appear, and become clearly visible in coatings deposited for 90 s. The average Cr content in the alloy coatings decreases with advancing deposition. The as-plated surface contains C in organic compounds and Zn(OH)2. After 50 min sputtering, Zn and a mixture of Cr, Cr2O3 and Cr7C3 were found. The presence of organic C and O, probably from inclusions of PEG, were also detected. 相似文献
20.
电沉积锌钴磷合金时阴极行为的研究 总被引:3,自引:1,他引:3
用动电位扫描法研究了在氯化物镀液中电沉积Zn-Co-P合金时的阴极行为。认为在镀液中加入配体柠檬酸钠可以提高阴极极化。加入次磷酸钠有利于合金镀层的形成。 相似文献