脱碳处理对Pt/WC复合材料催化性能的影响

采用溶胶-凝胶法,以钨酸钠为钨源、酚醛树脂为碳源合成碳化钨前驱体干凝胶,经原位碳化制备纳米碳化钨（WC）粉体,纳米WC粉体中的玻璃碳采用浓硝酸浸渍法脱除。在纳米WC粉料浆中以甲醛（HCHO）作为氯铂酸（H2PtCl6·6H2O）的还原剂,室温合成得到Pt/WC复合催化剂材料;以XRD、SEM、EDS等测试方法对样品的理化特性进行表征,并在酸性介质中采用循环伏安法测试材料的电化学催化活性。结果表明：相较于未经过脱碳处理的WC,经过浓硝酸脱碳处理后的Pt/WC电极催化材料的催化活性更好。经溶胶-凝胶法及原位碳化制备的纳米WC的颗粒径为20-80纳米,其本身具备较好的电催化活性。样品中残留的玻璃碳对WC具有包覆作用,会降低WC的电催化活性。采取浓硝酸脱碳的方式可有效脱除纳米WC粉体中的玻璃碳,发挥WC材料作为电极催化材料的电催化活性。     

冷中子差分成像模拟研究

冷中子照相利用穿透样品的中子和荧光屏~6Li反应产生的α带电粒子与荧光材料发光,从而在探测器上记录光强度的分布.本文简单介绍了冷中子照相的特点,给出了铍与钛金属宏观总截面随能量的变化,设计特定的样品采用MCNP模拟不同能量下的中子图像,中子图像显现Bragg吸收限上下两幅图像的对比度差异,采用差分成像对两幅中子图像进行处理,凸现了冷中子照相的优点.     

脑显像剂IMP的放射性碘标记及动物实验

文章报道了对本校合成的RS-N-Isopropyl-P-Iodoamphetamine进行~(125)I标记和动物实验的初步结果。我们采用水热法进行同位素交换反应,在Cu(II)和过量还原剂存在的条件下,可以方便地获得高标记率的~(125)I-IMP。经萃取纯化后,放化纯度>98%;游离~(125)I<1%。测定了在大鼠体内静脉注射~(125)I-IMP的分布,结果表明,~(125)I-IMP具有脑摄取率高、脑与血的比值大、在脑贮留时间长等优点,是一种有用的新型脑显象剂。     

Research Profiling of Nano-enchanced Molecular Imaging Technology

Molecular imaging, as an emerging technique in current medical diagnostics, therapy and biology science, has received more and more attention in academia, industry, as well as medical practices. And the applications of nanotechnology in this field stimulate its development. This paper explores the development of the basic research and applied research on nano-enhanced molecular imaging, and does the in-depth analysis by adopting the bibliometrics method. The results show that the US is the leader in this field, who has the absolute advantages. Germany, UK and France and Japan are the followed ones. The rapidly developing Asian countries , China and South Korea might become the potential competitors. Research network analysis draws the conclusion that the other countries and regions share the same research interests with the US. The US not only take the lead in the researching number, but also directing the future orientation of this field. However, the US has not much international collaboration. The collaboration within the country and regions show that collaboration in this field is limited to the regional adjacency. Disciplinary analysis reveals that the major subjects which relate intimately to the nano-enhanced molecular imaging are chemistry, biomedical science and material science.     

基于非截断小波有限元的BLT正向问题研究

针对自发荧光断层成像,提出了一种非截断小波有限元算法.该算法采用单元间非截断组合小波基来逼近未知函数,从理论上解决了二维和三维下复杂形状体的剖分,并成功地应用于自发荧光断层成像正向问题中圆柱和圆球仿体的研究.理论分析和数值仿真结果表明,与传统有限元的数值解相比,该算法在获得同样有效解的情况下减少了单元剖分数,降低了计算的复杂度.     

Study of amperometric diffusion solid-state electrolyte cell operating regimes

Different operating regimes are considered for operation of an amperometric diffusion solid-state electrolyte cell for measuring the volume fraction of oxygen. The design of an oxygen sensor is described. Experimental results confirm the efficiency of the proposed diffusion solid-state electrolyte cell for measuring oxygen in the range of 98–100%. Translated from Izmeritel’naya Tekhnika, No. 10, pp. 64–65, October, 2008.     

Localizable imaging study for the noninvasive diagnosis of lesions with the backscattering polarized light

The asymmetry appearing in the degree of polarization (DOP) distribution of the backscattering polarized light from tissues is investigated by using polarized Monte Carlo simulation. When the incident point is close to the boundary of the lesion inside the tissue, high asymmetry emerges regardless of the polarized direction of the incident light. A noninvasive method based upon the DOP asymmetry of the backscattering light is proposed to locate lesions hidden in live tissues by scanning a point light source. Imaging of the front projection on complicated lesion structures is demonstrated with this method. Its transverse resolution, which is affected by the wavelength of incident light and the size of the scattering particle, can reach the diameter of the lesion scattering particle theoretically while the best longitudinal detection depth can be achieved by choosing a suitable incident wavelength according to the scattering characters of the tissue.