Enhanced thermal stability of Bi2Te3-based alloys via interface engineering with atomic layer deposition

The ease of Te sublimation from Bi₂Te₃-based alloys significantly deteriorates thermoelectric and mechanical properties via the formation of voids. We propose a novel strategy based on atomic layer deposition (ALD) to improve the thermal stability of Bi₂Te₃-based alloys via the encapsulation of grains with a ZnO layer. Only a few cycles of ZnO ALD over the Bi₂Te_2.7Se_0.3 powders resulted in significant suppression of the generation of pores in Bi₂Te_2.7Se_0.3 extrudates and increased the density even after post-annealing at 500 °C. This is attributed to the suppression of Te sublimation from the extrudates. The ALD coating also enhanced grain refinement in Bi₂Te_2.7Se_0.3 extrudates. Consequently, their mechanical properties were significantly improved by the encapsulation approach. Furthermore, the ALD approach yields a substantial improvement in the figure-of-merit after the post-annealing. Therefore, we believe the proposed approach using ALD will be useful for enhancing the mechanical properties of Bi₂Te₃-based alloys without sacrificing thermoelectric performance.     

北洺河铁矿全尾砂胶结充填治理塌陷区的可行性研究

北洺河铁矿为践行“绿水青山就是金山银山”的绿色发展理念,探索利用选厂尾矿治理地表塌陷区方案。通过对北洺河铁矿塌陷区稳定性分析以及对全尾砂膏体制备、输送、胶结充填技术可行性试验研究,并结合经济估算、环境和社会效益等综合分析,认为全尾砂胶结充填治理塌陷区的方案可行。     

全尾砂和废石联合胶结充填体最佳配比及应用

针对红岭铅锌矿分级充填骨料来源不足、地表废石堆积污染环境的情况,提出将该矿选厂产生的全尾砂和地表废石作为充填骨料的联合胶结充填方案。分别测试了全尾砂和地表废石的物理化学性质,验证了碎石和全尾砂作为联合充填骨料的可行性。通过充填配比试验,分析了不同配比全尾砂废石充填体强度特性,得出了最佳充填配比。结果表明,充填试块的强度随灰砂比减小而减小,随养护龄期增加呈增大趋势,随充填料浆质量浓度增大而增大,最佳配比为: 胶结充填灰砂比1∶8、普通充填灰砂比1∶12,全尾砂∶废石配比4∶6,质量浓度78%。根据研究结果,在红岭铅锌矿进行了全尾砂废石充填技术工业应用,证实该技术可行。     

基于P波模量的原位胶结充填体强度预测模型研究

原位胶结充填体质量评价通常采用单轴抗压强度作为表征指标,由于在现场工程中无法快速、准确获取充填体的强度值,因此需要建立一种参数易于获取且准确的原位胶结充填体强度预测模型。基于胶结充填体物理力学参数的内在联系,从量纲平衡的角度探索了胶结充填体单轴抗压强度与P波模量的关系。根据C矿和I矿两种原位胶结充填体的密度、P波速度及取芯强度的测试数据,采用线性拟合的方法获得了基于P波模量的原位胶结充填体强度预测模型。通过对C矿和I矿的强度预测模型拟合效果分析可知,P波模量与取芯强度呈正相关性,且拟合效果较好,证明原位胶结充填体强度预测模型精度高,具有很强的实用性。     

水热合成Bi-Te-Se合金及其热电性能

用水热法在473K下反应24h,制备了Bi-Te-Se三元合金.其粉末产物由结构相同成份接近的两相Bi-Te-Se合金组成.粉末在523K,50MPa压力下热压成的块材也是两相结构.粉末和块体材料的微观形貌均由层片状颗粒组成,层片厚度为100nm左右.通过改变Te的相对含量,可以调节施主掺杂浓度.材料具有很低的热导率,在349K时试样Bi2Te2.85Se0.45具有晶格热导率最低值为0.33W/m·K.此时,它也具有最高的ZT值为0.60.     

EXPERIMENTAL INVESTIGATIONS INTO THE INFLUENCE OF MAJOR OPERATING PARAMETERS DURING MICRO-ELECTRO DISCHARGE DRILLING OF CEMENTED CARBIDE

Present study investigates the influence of major operating parameters on the performance of micro-EDM drilling of cemented carbide (WC-10wt%Co) and identifies the ideal values for improved performance. The operating parameters studied were electrode polarity, gap voltage, resistance, peak current, pulse duration, pulse interval, duty ratio, electrode rotational speed and EDM speed. The performance of micro-EDM drilling process was evaluated by machining time, material removal rate (MRR), relative electrode wear ratio (RWR), spark gap, surface finish and dimensional accuracy of micro-holes. It has been found that there are two major conflicting issues in the micro-EDM of carbide. If the primary objective is to obtain better surface finish, it can be obtained by the sacrifice of high machining time, low MRR and high RWR. However, for faster micro-EDM, the surface roughness is higher and electrode wear is again much higher. It is concluded that negative electrode polarity, gap voltage of 120 V, resistance of 33 Ω, peak current of 8 A, pulse duration of 21 μs, pulse interval of 30 μs, duty cycle of 0.47, electrode rotational speed of 700 rpm and EDM speed of 10 μm/s can be considered as ideal parameters to provide improved performances during the micro-EDM of WC-Co.     

脂肪族离子固化剂改性水泥土的机理研究

水泥基材料加固土(水泥土)存在早期强度低、易开裂变形等性能缺陷。为对其改性,在水泥土中掺入含水率体积1/300～1/50不等的新型土壤固化材料,离子固化剂(ISS)。通过无侧限抗压强度试验、体积化学减缩试验,探究了ISS改性水泥土的可行性,并通过对表面吸附特性、物相构成演变、微结构特性的表征及分析,对ISS改性水泥土的机理进行了系统的研究。结果表明:ISS分子对于水泥土各组分具有显著的选择吸附性;ISS掺入水泥土后,能够提升体系内各组分的分散性并降低黏土矿物结合水的能力,进而加速土体内水化反应产物的生成,优化土体孔隙结构,提升土体强度并增大体积化学减缩;最优ISS掺量为1/150,过量的掺入会减弱ISS的改性效果,但可降低水泥土体积的化学减缩。相关成果可为离子固化剂应用于水泥土的改性提供一定的参照。     

碱激发铜镍水淬冶炼渣制备充填胶凝材料研究

为研究某铜镍矿产出的铜镍水淬冶炼渣大宗量处置技术,基于铜镍水淬冶炼渣制备充填胶凝材料的可行性和技术工艺,本研究开展了冶炼渣粉磨试验和激光粒度分析、基于冶炼渣的碱激发胶凝材料配比正交试验、充填体试块单轴抗压强度试验、充填体试块及胶凝材料净浆试块SEM测试,结果表明:该铜镍矿冶炼厂产出的铜镍水淬冶炼渣有一定的火山灰活性,但其火山灰活性较低;实验室配制的碱激发剂对该铜镍水淬冶炼渣激发作用不明显;该冶炼渣的最佳粉磨时间为50min,D(0.5)为28μm。在普通硅酸盐水泥为主要胶凝材料的碱性充填料浆中,冶炼渣的掺入引起了钙矾石生成量的增加,随着粉磨冶炼渣粒径的减小,冶炼渣颗粒表面的溶蚀现象越来越明显。     

窄长采场胶结充填体强度要求及结构设计

为了解决金厂河多金属矿空场嗣后充填法窄长采场胶结充填体强度要求优化设计问题,以该矿矿岩-充填体力学参数为基础,利用优选3种理论方法,进行了强度要求解析计算.通过构建矿山典型开采区域的三维数值模型,采用FLAC3D软件开展了两步骤采充时序的数值模拟计算,搜索得出了一步骤窄长采场胶结充填体极限稳定状态下的强度数值解,进而对...     

极弱胶结地层煤巷支护体系与监控分析

针对极弱胶结地层煤巷围岩自稳能力差、自稳时间短、围岩变形剧烈等特征,采用FLAC3D深入揭示了矩形、切圆拱形与直墙拱形等3种断面形状煤巷开挖后围岩位移、塑性区及应力分布规律,确定了极弱胶结地层煤巷合理断面形状;结合国内外煤巷支护理论与技术,提出了极弱胶结地层煤巷"双层锚固平衡拱结构",基于煤层厚度与巷道埋深,分类提出了极弱胶结地层煤巷支护技术方案,模拟验证了支护方案的合理性与可行性;基于围岩变形与支护结构受力实时监测及分析,动态掌握了极弱胶结地层煤巷围岩变形与支护结构受力状态,评价了支护效果与验证了支护方案的可行性。监测结果表明,切圆拱形断面煤巷成型较好、受力均匀,有利于巷道围岩的整体稳定,提高了煤巷开挖后的自稳与承载能力;锚网索联合支护技术方案有效地控制了极弱胶结地层煤巷围岩大变形与破坏,保证了巷道围岩与支护结构的长期稳定及安全。