粗晶硬质合金强度和致密度影响因素的研究

针对粗晶WC-Co硬质合金的成分和工艺优化要求,运用正交实验设计,考察了含碳量、烧结工艺、钴含量、镍含量、球磨球料比和球磨时间对试样抗弯强度和体积收缩率的影响。研究表明,烧结制度是影响抗弯强度的最主要因素;其次是碳含量与烧结工艺的交互作用、Co含量与球磨时间的交互作用。烧结工艺是影响体积收缩率的最主要因素。     

多目标条件下矿山充填材料配比优化实验

为准确确定某铁矿尾砂胶结充填材料最优配比,分别选择制浆水性、砂灰质量比和料浆质量浓度与充填体强度、料浆坍落度和料浆泌水率作为尾砂胶结充填材料配比优化的影响因素和充填性能评价指标.基于响应面–满意度函数耦合理论,采用Box-Behnken实验设计方法开展13组不同充填配比实验,构建充填性能评价指标的响应面函数,研究各影响因素与目标响应量的相关关系及多目标条件下的最优充填材料配比.结果表明,制浆水性对响应量影响不显著;砂灰质量比对充填体强度影响极显著;坍落度受料浆质量浓度、砂灰质量比影响较显著;砂灰质量比和料浆质量浓度对料浆泌水率的影响均极为显著,且二者之间存在极显著的交互作用.该矿尾砂胶结充填材料最优配比为:制浆水性为海水,砂灰质量比为8.44:1,料浆质量浓度为72%,该配比条件下对应的响应量预测结果为:充填体28 d龄期单轴抗压强度为2.00 MPa,料浆塌落度为27.15 cm,料浆泌水率为7.35%,与验证实验结果基本吻合,为现场工业实验提供强有力的理论支撑.     

用水量对胶凝砂砾石抗压强度的影响

胶凝砂砾石材料是一新型筑坝材料,拥有广阔的发展前景。用水量是影响胶凝砂砾石强度的重要因素。通过抗压强度试验分析用水量对胶凝砂砾石抗压强度的影响,得出:最优用水量随胶凝材料掺量的增大而增大,随砂率的增大而增大,最优用水量为85~125 kg/m~3;最优水胶比随胶凝材料用量的增加而减小,随龄期的增加呈减小的趋势,最优水胶比为0.95~1.35。用水量对抗压强度的影响仅次于水泥用量,在施工过程中,应将其作为胶凝砂砾石材料的一项重要参数来控制,以保证胶凝砂砾石材料的性能。     

Theoretical analysis of a new segmented anchoring style in weakly cemented soft surrounding rock

According to the tensile failure of rock bolt in weakly cemented soft rock, this paper presents a new segmented anchoring style in order to weaken the cumulative effect of anchoring force associated with the large deformation. Firstly, a segmented mechanical model was established in which free and anchoring section of rock bolt were respectively arranged in different deformation zones. Then, stress and displacement in elastic non-anchoring zone, elastic anchoring zone, elastic sticking zone, softening sticking zone and broken zone were derived respectively based on neural theory and tri-linear strain softening constitutive model of soft rock. Results show that the anchoring effect can be characterized by a supporting parameter b. With its increase, the peak value of tangential stress gradually moves to the roadway wall, and the radial stress significantly increases, which means the decrease of equivalent plastic zone and improvement of confining effect provided by anchorage body. When b increases to 0.72, the equivalent plastic zone disappears, and stresses tend to be the elastic solutions. In addition, the anchoring effect on the displacement of surrounding rock can be quantified by a normalization factor δ.     

超重型切削过程硬质合金刀具高温力学特性

超重型切削过程中,刀具的高温失效是硬质合金刀具破损的主要形式之一。首先,通过理论分析、切削仿真及数学模型进行切削热产生过程分析,并研究切削温度对硬质合金刀具变形抗力的影响;然后,进行切削温度及材料高温硬度测量实验,实验结果验证模型有效,硬质合金和工件材料试块的硬度在1000℃时分别下降了28%和60%左右;最后,从刀具几何结构优化设计和复合涂层技术两方面提出超重型切削专用硬质合金刀具抗高温性能的提效措施,在5组切削参数下进行刀具寿命对比实验,优化设计的XF8刀具寿命是YT15刀具的2~5倍。研究结果可以为重型高效切削刀具技术的研究及推广提供借鉴。     

《老子》的政治观

《老子》以“道”为核心概念,运用“反者,道之动”的辩证思维,主张“道法自然”的治理模式,强调“无为则无不为”、“无为而治”的方法论,以“圣人无常心,以百姓心为心”的民治思想基础达到“我无为而民自化”的治理境界,最终实现“小国寡民”的理想社会状态。《老子》主张从解构的角度审视权力和政治的功用与同时代其他各家思想的治理向度迥然不同,不仅促成了古代中国社会“治世”的出现,对当下中国正在进行的有限政府构建和深化改革也提供了有益的启示。     

Mechanism and prediction of failure of diamond films deposited on various substrates by HFCVD

Diamond films were deposited on the WC-Co cemented carbide and Si3N4 ceramic cutting tool substrates by hot-filament-assisted chemical vapour deposition. The adherence property of diamond films was estimated using the critical load (Pcr) in the indentation test. The adhesive strength of diamond films is related to the intermediate layer between the film and the substrate. Poor adhesion of diamond films to polished cemented carbide substrate is owing to the formation of graphite phase in the interface. The adhesion of diamond films deposited on acid etched cemented carbide substrate is improved, and the peeling-off of the films often happens in the loosen layer of WC particles where the cobalt element is nearly removed. The diamond films' adhesion to cemented carbide substrate whose surface layer is decarbonizated is strengthened dramatically because WC phase forms by reaction between the deposited carbon and tungsten in the surface layer of substrates during the deposition of diamond, which results in chemical combination in the film-substrate interface. The adhesion of diamond films to silicon nitride substrate is the firmest due to the formation of chemical combination of the SiC intermediate layer in the interfaces. In the piston-turning application, the diamond-coated Si3N4 ceramic and the cemented carbide cutting tools usually fail in the form of collapsing of edge and cracking or flaking respectively. They have no built-up edge(BUE) as long as coating is intact.As it wears through, BUE develops and the cutting force on it increases 1 - 3 times than that prior to failure. This can predict the failure of diamond-coated cutting tools.     

硬质合金复合材料

一种由硬质合金基体和硬质合金粒子制成的硬质合金复合材料。硬质合金表面均匀地分布一层高于基体硬度的粒子,这种复合材料具有表面高耐磨性,中心高韧性的特点。     

纳米晶WC-10Co复合粉末的烧结致密化行为

研究了机械合金化纳米晶WC-10Co复合粉末的真空烧结致密化行为和一般规律.结果表明:烧结温度的提高和烧结时间的延长有利于样品的烧结致密化过程,在1 275～1 300℃致密化速度快,在1 300℃,15 min左右致密化过程已基本完成;VC、Cr3C2等复合晶粒长大抑制剂含量的增加不利于致密化过程;新型晶粒长大抑制剂A可以更有效地阻碍晶粒长大;纳米晶WC-10Co-0.8VC/Cr3C2-0.2A复合粉末压坯在1375℃,30min烧结条件下,所得的密度为14.48 g/cm3,晶粒尺寸约为180 nm.     

硬质合金与钢的热等静压扩散连接

研究了硬质合金ＹＧ１５Ｃ与４５~＃碳钢的热等静压扩散连接工艺，探讨厂连接温度、压力、保温保压时间、中间夹层及其厚度和连接残余热应力等对接合强度的影响．结果表明：热等静压扩散连接强度强烈依赖于连接温度，受控于连接后因ＹＧ１５Ｃ与４５~＃钢热膨胀失配而产生的残余热应力。采用镍箔作中间夹层可有效地减小残余热应力对连接的影响，显著提高接合强度．