LiFePO4/C复合材料的制备和性能

采用高温固相合成法二次灼烧工艺制备锂离子电池正极复合材料LiFePO4/C。经300℃和650℃二次灼烧,得到了从纳米到亚微米尺寸的LiFePO4和LiFePO4/C复合材料。X射线衍射(XRD)结果表明,所得到的LiFePO4和LiFePO4/C样品具有单一的橄榄石型晶体结构,且具高纯度。在多种碳源(如乙炔黑、Vulcan XC-72碳黑、鳞状石墨、各向异性石墨和葡萄糖)制备的LiFePO4/C复合材料中,以葡萄糖为碳源合成的样品具有最好的电化学性能。在电池工作温度由室温提高到40℃时,由于复合材料的电子电导率增大和锂离子在材料中的扩散速度加快,电池的充放电循环性能明显提高。     

动态陶瓷膜在针织印染废水回用处理中的应用

应用陶瓷膜作为支撑体,再用高岭土进行动态涂膜,形成孔径约为0.2μm的动态膜,对针织印染废水的生化出水进行深度处理,以达到水回用的目的。讨论了动态涂膜后陶瓷膜的操作条件。试验结果表明,操作压力为0.1MPa、错流速度为1.5m/s时处理效果最佳。在中试过程中,动态陶瓷膜的深度处理保证了出水水质,使最终出水能回用于印染加工。     

内壳垫片无废料级进模设计

通过对典型零件无废料排样级进模冲裁中出现的问题进行了分析,提出了解决方案。介绍了相应的模具结构,对同类件具有很好的借鉴作用。     

基于柔度差曲率矩阵的结构损伤识别方法

柔度是较频率和位移模态更敏感的结构损伤标示量。提出利用结构损伤前、后的柔度矩阵,先后对柔度矩阵差的列、行进行两次差分,求得柔度差曲率矩阵(δFlexibility Curvature Matrix),并以其对角元素作为检测结构损伤指标(δFCMD)的新方法。该方法仅需低阶模态参数即可进行损伤检测,不论对简支梁、悬臂梁、固支梁,或多跨连续梁,单一位置损伤、支撑处损伤、轻微损伤,还是多种损伤共存,均具有损伤定位的能力、并能定性反映损伤程度。通过与已有的柔度差、柔度变化率、均匀荷载面曲率差等柔度指标的数值模拟分析研究,显示了该指标检测损伤的有效性和优越性。     

Structure factors of modified liquid Al–Si alloys

The structure factor and the coordination numbers of liquid Al–Si alloys with different Si content have been measured by a high temperature X-ray diffractometer. Radial distribution functions (RDFs), the nearest atomic distance and the coordination numbers of eutectic Al–Si alloys before and after being modified with Sr and Sb were studied. The RDFs of the liquid alloy were decomposed by five Gaussian peaks. The results show that a Si–Si covalent bond exists in the liquid of eutectic and hyper-eutectic alloys. Sr in the liquid Al–Si has a capability to weaken the covalent bonds of Si–Si, suppressing the nucleation of the eutectic silicon phase. On the other hand, Sb in the liquid Al–Si increases the order degree of Si atoms, decreasing the supercooling degree of the nucleation and promoting the nucleation of eutectic silicon.     

基于Matrix 2003与效应的产品工业设计创新方法研究

产品创新直接关系到产品自身在市场的竞争力.当前工业设计产品创新缺乏一些具体的理论支撑,因此需要将其他领域的理论融入工业设计当中能够有效提高新产品设计的效率.为提高工业设计中的创新效率,介绍了一种将工业设计理论与Matrix 2003结合的创新原理,总结了六大设计要素,并利用这些设计元素将创新原理按照"时间-空间-交互"三大维度进行划分,形成一种独特的创新矩阵,以最终理想产品所达到的效应为目标进行求解,从而为工业设计产品的创新提供了一种快捷有效的方法流程.最后以快递车车厢的改进为工程实例进一步验证方法的有效性和实用性.     

Effect of integrated extrusion–equal channel angular pressing temperature on microstructural characteristics of low carbon steel

Abstract

In the present research, a combined forward extrusion–equal channel angular pressing was developed and executed for the deformation of a plain carbon steel. In this method, two different deformation steps, including forward extrusion and equal channel angular pressing, take place successively in a single die. The deformation process was performed at different deformation start temperatures (800, 930 and 1100°C). Three-dimensional finite element simulation was used to predict the strain and temperature variations within the samples during deformation. With microstructural observations and the results of finite element simulation, the main grain refinement mechanisms were studied at different deformation temperatures. The results show that the forward extrusion–equal channel angular pressing is effective in refining the ferrite grains from an initial size of 32 μm to a final size of ～0·9 μm. The main mechanisms of grain refinement were considered to be strain assisted transformation, dynamic strain induced transformation and continuous dynamic recrystallisation, depending on the deformation temperature.     

TiO2光催化抗菌陶瓷的制备

制备了SiO2-Zr3(PO4)4改性的TiO2粉体,将其添加到陶瓷釉料中,研制出了TiO2光催化抗菌陶瓷,分别就改性TiO2粉体的光催化活性和TiO2光催化抗菌陶瓷的光催化抗菌机理进行了研究.研究表明,37.2%Zr3(PO4)4和11.5%SiO2改性的TiO2粉体经1323K处理后,仍具有较好的光催化活性,将其添加到陶瓷釉料中制备出的TiO2先催化抗菌陶瓷对大肠杆菌的抑菌率达98%.     

Annealing process of fine grained co-stabilised (Y,Mg)-PSZ/MgAl2O4 ceramics

Abstract

Co-stabilised (Y,Mg) partially stabilised zirconia (PSZ) ceramics with MgAl₂O₄ spinel additions were produced, with industrial zirconia as the main starting material. Powders were prepared using a mechanical milling–mixing process. The effect of the annealing process on the mechanical properties, phase compositions, and microstructure of fine grained PSZ ceramics was investigated.