氟烷基硅烷改性硅树脂陶瓷防污剂研制及应用

通过添加甲基三氟丙基二甲氧基硅烷来改性硅树脂陶瓷防污剂可明显地改善防污剂的耐油性污渍的性能,同时氟烷基硅烷改性硅树脂陶瓷防污剂保持了有机硅树脂防污剂的持久防污性能的优点。用金相显微镜、扫描电镜观察抛光砖表面孔隙的变化。     

On the oxidation kinetics and mechanisms of various SiC-coated carbon-carbon composites

SiC coatings on the surface of C-C were produced by either silicone resin impregnation/ pyrolysis or reaction sintering. Cycles of resin impregnation/pyrolysis produced an SiC coating, on the walls of fine open pores, which was effective in reducing the oxidation rate of C-C and in shifting the transition temperature to a higher value. Unless it is pre-coated with a pyrocarbon layer before sintering, plain reaction sintered SiC has oxidation behaviors similar to those of the above-mentioned SiC. The dense pyrocarbon film deposition on the surface of C-C could form a better SiC film than others. The carbon film homogenized the surface of C-C and a dense SiC film was established. The oxidation of the coated C-C can be modelled by a set of “oxidation resistors” in series and/or in parallel, with each resistor corresponding to an oxidation element. The controlling mechanism can be resolved from the activation energy. A combined resistant layer, consisting of resin impregnation, pyrocarbon film and reaction sintering SiC, showed the best oxidation resistance of any single-layer coated C-C composite.     

一种基于生成树的分类去除关联规则冗余方法

在信息及数据爆炸的时代,冗余问题已经成为数据挖掘者获得知识的重大障碍,而目前解决的方法会导致关联规则的不完整性。基于此,文中引入了有向超图表示关联规则,重定义了邻接矩阵,介绍了冗余规则分类处理思想,将冗余规则分为从属规则和重复路径规则,通过VB编程去除了从属规则冗余,以及利用生成树算法去除了重复路径规则冗余。实验结果证明,此方法创新性地结合了图论中有向超图、生成树与关联规则的知识,维护了关联规则的完整性和准确性,同时去除了全部冗余规则。     

决策表中基于对象的μ-约简方法研究

研究了不协调决策表中基于对象的μ-约简问题,给出了μ-约简的一些性质及等价定义,得到了μ-约简的判定定理和相应的可辨识矩阵及辨识公式,从而提供了不协调目标信息系统知识约简的新方法。并通过实例将决策表中基于对象的约简与整体约简进行了对比,结果表明前者可以得到更简洁的知识。该方法也适用于协调目标信息系统。     

组合梁钢框架与地基基础的共同作用分析

在简化计算组合梁的基础上,利用ANSYS有限元程序对组合梁钢框架与地基基础的共同作用进行了建模计算,讨论了不同基础形式和刚度对上部框架的影响,以及按组合框架与按纯钢框架计算的差别。分析结果表明,基础变形对组合梁钢框架的内力重分布的影响是显著的;与不考虑组合作用的计算方法相比,按组合框架计算不仅使竖向荷载作用下中间支座处梁截面负弯矩大幅度下降,有利于支座节点的设计,同时也使整个结构的刚度提高,解决了水平荷载作用下钢框架本身过于柔弱、层间位移难以控制、底层柱子弯矩过大的问题;此外,考虑组合作用加大了对基础变形的约束,也使基础沉降差异引起的上部结构的次生应力变小。     

三维织物及复合材料的发展与应用

本文介绍了三维织物及其复合材料的发展现状及应用研究情况。     

An algorithm and observability research of autonomous navigation and joint attitude determination in asteroid exploration descent stage

In this paper, an autonomous relative navigation and joint attitude determination algorithm in asteroid exploration descent stage is researched based on feature point information of perpendicular asteroid surface image observed by optical navigation camera, distance vectors from spacecraft to asteroid measured by three angled installed lidars and relative velocity increment measured by accelerometer when the relative distance vector to the centroid of asteroid can not be obtained. The inertial attitude of spacecraft is determined by sun vector, star vectors and inertial angular velocity respectively measured by sun sensor, star trackers and inertial reference unit. Also, in order to obtain measurement error model transferred from sensor noise, a covariance matrix solver considering error correlation is presented via the error model of normalized vector to first order. Numerical simulation and improved observability evaluation of filtering are undertaken to discuss the results of complete sensor observation and weak observation of lidars, and verify the effectiveness of the presented relative navigation and attitude determination algorithm.     

Ameliorating effect of silica addition in the anode-catalyst layer of the membrane electrode assemblies for polymer electrolyte fuel cells

Incorporation of silica particles through a sol-gel process into the anode-catalyst layer with a sol-gel modified Nafion-silica composite membrane renders easy retention of back-diffused water from the cathode to anode through the composite membrane electrolyte, increases the catalyst-layer wettability and improves the performance of the Polymer Electrolyte Fuel Cell (PEFC) while operating under relative humidity (RH) values ranging between 18% and 100% with gaseous hydrogen and oxygen reactants at atmospheric pressure. A peak power density of 300 mW cm⁻² is achieved at a load current-density value of 1200 mA cm⁻² for the PEFC employing a sol-gel modified Nafion-silica composite membrane and operating at 18% RH. Under similar operating conditions, the PEFC with a Membrane Electrode Assembly (MEA) comprising Nafion-silica composite membrane with silica in the anode-catalyst layer delivers a peak power density of 375 mW cm⁻². By comparison, the PEFC employing commercial Nafion membrane fails to deliver satisfactory performance at 18% RH due to the limited availability of water at its anode, acerbated electro-osmotic drag of water from anode to cathode and insufficient water back diffusion from cathode to anode causing the MEA to dehydrate.     

基于ATP-EMTP的330 kV半复合传输杆塔雷电反击过电压仿真研究

介绍复合材料传输杆塔的优势与研究进展以及三种传统杆塔模型.为了验证330 kV半复合传输塔单根接地引下线设计的合理性,运用电磁暂态分析软件ATP-EMTP,建立输电线路、雷电流波形以及杆塔多波阻抗仿真模型.通过分析杆塔雷电过电压分布,判断接地引下线与传输线之间是否会发生闪络.     

加工条件对PP/芳纶复合材料横向拉伸性能的影响

对单向聚丙烯／芳纶纤维复合材料的横向拉伸性能进行了研究，讨论了压制时间、成型温度、成型压力，以及芳纶纤维的体积含量等对复合材料体系横向拉伸强度的影响。结果发现，随着压制时间、成型温度的增加，复合材料体系的横向拉伸强度提高；随成型压力的提高，复合材料的横向拉伸强度先升后降。此外，复合材料的横向拉伸强度随着芳烃纤维体积含量的增加而大幅度降低。