Preparation and structure of fluorinated/non-fluorinated polyacrylate gradient emulsion blend film

The emulsion blend method, which is environmentally friendly and energy saving, was used to prepare a compositional gradient film of fluorinated/non-fluorinated polyacrylate in this paper. The size and glass-transition temperature (T_g) of the emulsion particles were designed to enhance the driving force of their selective congregation and promote the formation of gradient structure. The structures and surface properties of the obtained films were characterized. The results showed that when the fluorinated components have much smaller particle size and higher T_g than those of fluorine-free polyacrylate components, the gradient structures formed in the direction across the film thickness of the films. The concentration of the fluorinated component increased gradually from film-glass interface to film-air interface in the blend film, making the surface free energies of the two sides of the gradient film distinctively different.     

Metal‐containing Polymers via Electropolymerization

Electropolymerization represents a suitable and well‐established approach for the assembly of polymer structures, in particular with regard to the formation of thin, insoluble films. Utilization of monomers that are functionalized with metal complex units allows the combination of structural and functional benefits of polymers and metal moieties. Since a broad range of both electropolymerizable monomers and metal complexes are available, various structures and, thus, applications are possible. Recent developments in the field of synthesis and potential applications of metal‐functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research.     

Correlation between structural and optical properties of 30 nm and 60 nm lead sulfide nanowires

PbS nanowires with 30 nm and 60 nm diameter fabricated under the same condition of electrochemical deposition with sulfuric and oxalic anodic alumina membranes (AAM), respectively, have been successfully prepared in order to study their optical properties in relation to their size. Scanning electron microscopy indicates that the 60 nm PbS nanowire arrays have the same shape with the 30 nm. X-ray diffraction result shows that 60 nm PbS nanowires are crystalline and have a highly (200) preferential orientation like 30 nm ones. UV spectrum considers the nanowire size decrease as the absorption peak shifts to the blue. The quantum confinement effects compared between 30 nm and 60 nm PbS nanowire arrays were observed by the measurements of ultraviolet-visible absorption spectroscopy (UV-vis).     

A π-extended tetrathiafulvene derivative: Synthesis and photoluminescence properties

Solid-state emissive organic materials have received increasing attention due to their prospective applications in large-area. Here, a novel π-extended tetrathiafulvene derivative DPD with donor-π-donor structure has been newly developed to produce the prominent characteristic of aggregation-induced enhanced emission (AIEE) that exhibits higher fluorescence quantum efficiency in solid film compare to its solutions. The AIEE mechanism of DPD was studied in detail through photophysical investigations and can be dominant attributed to the formed excimer state of DPD and J-aggregates in solid state.     

Hematite solid and hollow spindles: Selective synthesis and application in gas sensor and photocatalysis

Hematite solid spindles and hollow spindles have been selectively synthesized by a template-free, economical hydrothermal method, using FeCl₃·6H₂O as the starting materials and NaOH as the homogeneous precipitant. XRD analyses indicated that the products consisted of α-Fe₂O₃. SEM and TEM measurements showed that the morphologies of products were in the shape of solid spindles and hollow spindles, respectively. A possible formation process based on the nucleation-oriented aggregation-recrystallization mechanism is proposed. Moreover, the as-prepared hollow spindle-like α-Fe₂O₃ exhibits a good response and reversibility to some organic gas, such as 2-propanol and acetone. Compared with other hematite nanostructures, the porous hollow hematite spindles show outstanding performance in gas sensing due to their large surface area and porous hollow structure. Because of the unique porous hollow structures of the samples, the photocatalytic property of the spindle-like α-Fe₂O₃ was also investigated.     

ZnCl2-assisted Synthesis of ZnSe Polycrystal

A chemical-assisted element direct-reaction method is developed to synthesize ZnSe compound semiconductor material at a relatively low temperature (～1000 C). ZnSe polycrystal was obtained in the closed-tube systems with Zn-Se, Zn-Se-Zn(NH3)2Cl2, Zn-Se-NH4Cl and Zn-Se-ZnCl2. The as-synthesized samples were tested by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and analyzed by thermodynamic numerical method. The results demonstrate that the synthesis efficiency is higher than 99.96% for Zn-Se-ZnCl2 system at around 1000 C for 3 weeks. It also exhibits that not only temperature, but also low apparent ratio of volume and surface area of the source materials and higher ZnCl2 content are required to achieve high synthesis efficiency. A SeCl transporting reaction synthesis process is proposed based on the thermodynamic analysis.     

Novel transparent and flexible nanocomposite film prepared from chrysotile nanofibres

In the present study, chrysotile nanofibres, obtained from physicochemical dispersion of natural chrysotile, were used to prepare nanofibre sheets by vacuum filtration. As-prepared sheets were then impregnated by UV-curable resin and cured by ultraviolet light to fabricate the flexible and transparent nanocomposite films. Observed from SEM, the transparent films showed a smooth surface and a typical sandwich structure in cross section, viz. nanofibre sheet filled with resin was sandwiched by two layers of resin. XRD patterns indicated the amorphous nature of cured resin and characteristic crystallographic structure of chrysotile in nanocomposite films. Though the nanofibre sheets were white in colour, and nanofibre contents in nanocomposites were as much as 43.4 wt%, the nanocomposite films displayed an excellent optical transparency with about 85% light transmittance in the visible light range. Tensile tests showed that the addition of nanofibres resulted in a great improvement in mechanical strength of the nanocomposite films; with the increase of nanofibre contents, the modulus and tensile strength of nanocomposite films increased gradually.     

复合包装材料剥离强度的检测方法

本文介绍了包装复合材料的分类、包装复合包装材料剥离强度的定义、检测方法及注意事项。     

低温切削技术及其应用研究

低温切削是指在低温环境下进行的切削过程,它利用低温下材料的物理化学性质,实现特定的加工目的。分析了低温切削技术的特点及其制冷技术,阐述了机械制造领域中低温切削技术的研究成果及应用状况。