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91.
92.
Hydrogen sulfide (H2S) was introduced into a microwave plasma chemical vapor deposition of microcrystalline diamond thin film. Secondary-ion mass spectroscopy showed that sulfur concentration was controlled from 2 × 1015 to 9 × 1017 cm− 3 by controlling the H2S/CH4 ratio, while that of hydrogen concentration was around 5 × 1020 cm− 3 and was independent of the H2S/CH4 ratio. Electrical conductance increased linearly as the S concentration increased from 2 × 1015 to 3 × 1016 cm− 3 without significant deterioration of film crystallinity, i.e., the amount of sp2 phase did not increase. Non-ohmic conduction was converted to ohmic conduction when the S concentration reached 9 × 1017 cm− 3 by increasing the H2S/CH4 ratio to 30,000 ppm. This modification was consistent to the formation of a graphitic phase by heavy S-doping, which was identified by Raman spectra and surface morphology. 相似文献
93.
94.
Chemical Processing of Nanostructured Cemented Carbide 总被引:1,自引:0,他引:1
Chemical processing is becoming a vital component in the economic development of advanced engineering materials. Our research group on chemical processing has been focussed on the development of process to produce nanophase cemented carbide. It is a much more direct route for making WC/Co than traditional processing methods, and offers the potential for lower cost production of novel materials with homogeneous nanophase microstructures and improved properties. This paper addresses the scientific and technical issues relating to the chemical processing of nanophase WC/Co composite powder and their sintering. 相似文献
95.
介绍表面化学改性活性炭研究进展,针对其特点和改性方法作了系统描述.在此基础上,对其去除水中有机物、重金属离子、亚硝酸盐等污染物质做了简要说明. 相似文献
96.
制备了金-海藻酸钙-几丁聚糖微胶囊,提出了修饰用于蛋白质药物靶向传输的多糖载体-几丁聚糖的新方法,该方法通过在几丁聚糖微胶囊表面结合金的纳米微粒使微胶囊表面结构发生变化,从而改变微胶囊的性质,这种修饰方法目前未见报道.文中对制备条件进行了优化,并对金-海藻酸钙-几丁聚糖微胶囊的粒径分布进行了表征.文中选择在pH值为5时反应2 h,制得的柠檬酸体系和丙烯酸体系的金-海藻酸钙.几丁聚糖微胶囊的平均直径分别为216.686um和196.850um. 相似文献
97.
Kaan
cal Michael U. Gutmann Guido Sanguinetti Ramon Grima 《Journal of the Royal Society Interface》2022,19(192)
Estimating uncertainty in model predictions is a central task in quantitative biology. Biological models at the single-cell level are intrinsically stochastic and nonlinear, creating formidable challenges for their statistical estimation which inevitably has to rely on approximations that trade accuracy for tractability. Despite intensive interest, a sweet spot in this trade-off has not been found yet. We propose a flexible procedure for uncertainty quantification in a wide class of reaction networks describing stochastic gene expression including those with feedback. The method is based on creating a tractable coarse-graining of the model that is learned from simulations, a synthetic model, to approximate the likelihood function. We demonstrate that synthetic models can substantially outperform state-of-the-art approaches on a number of non-trivial systems and datasets, yielding an accurate and computationally viable solution to uncertainty quantification in stochastic models of gene expression. 相似文献
98.
MLCC装配质量优化研究 总被引:2,自引:2,他引:0
针对本所产品中多层陶瓷电容器(MLCC)在经过环境试验后出现的失效问题,通过对失效原因进行分析,结合生产实际情况,进行了技术改进.制作了技术改进前后的试验板,经过环境试验后测试,结果表明,未改进前的试验板中的MLCC出现问题,而改进后的试验板没有发现问题.最后对故障MLCC进行了DPA检查,结果发现MLCC端头出现45°角裂纹.试验结果表明经过技术改进后有效地解决了MLCC装配质量问题,提高了产品装配合格率,达到了预期的效果. 相似文献
99.
A recursive orthogonal least squares (ROLS) algorithm for multi-input, multi-output systems is developed in this paper and is applied to updating the weighting matrix of a radial basis function network. An illustrative example is given, to demonstrate the effectiveness of the algorithm for eliminating the effects of ill-conditioning in the training data, in an application of neural modelling of a multi-variable chemical process. Comparisons with results from using standard least squares algorithms, in batch and recursive form, show that the ROLS algorithm can significantly improve the neural modelling accuracy. The ROLS algorithm can also be applied to a large data set with much lower requirements on computer memory than the batch OLS algorithm. 相似文献
100.