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21.
Alexander ARGYROS Mark STRATON Andrew DOCHERTY Eun Hee MIN Ziyi GE Kok Hou WONG Francois LADOUCEUR Leon POLADIAN 《中国光电子学前沿》2010,3(1)
Circular birefringence is a property of chiral materials. In this work, we consider the use of chiral materials in optical fibres to produce circularly birefringent optical fibres and in fibres where a contrast in circular birefringence contributes to forming the waveguide. (-)-menthyl methacrylate is also investigated as a possible material for the fabrication of such fibres. 相似文献
22.
Ruilian Chen Dengchong Feng Guojian Chen Xudong Chen Wei Hong 《Advanced functional materials》2021,31(16):2009916
The construction of invisible patterns via high-resolution printing and the independent encoding/decoding of complex information can lead to promising applications in steganography and watermarking for optical encryption. Herein, a rewritable chiral photonic paper formed by cholesteric cellulose nanocrystals and polycation is reported. The chemically crosslinked polycation network interpenetrates in the cholesteric structure while retaining the optical properties of the photonic crystals. The film exhibits controllable wettability via anion exchange, leading to extremely low contrast in the dry state but high contrast by a rapid wetting response. Triple invisible information is independently encoded on the films, including invisible patterns caused by reversible counterion-controlled wettability, permanent fluorescent labels based on fluorescent counterions, and polarization-dependent structural colors based on cholesteric structures. Full color patterns can be reversibly constructed via inkjet printing, with a high resolution of 100 µm. In addition, the circular polarization characteristics of the cellulose nanocrystals, liquid crystals, endow the system with complex and independent responses, realizing a wetting/polarization double-key decryption. This work provides a simple and effective optical technique for coding complex information on a single material platform and expands the techniques available to achieve invisible patterns for sensing and anti-counterfeiting. 相似文献
23.
Thanh‐Dinh Nguyen Bernardo U. Peres Ricardo M. Carvalho Mark J. MacLachlan 《Advanced functional materials》2016,26(17):2875-2881
Iridescence in animals and plants often arises from structural coloration, which involves hierarchical organization of minerals and biopolymers over length scales of the visible spectrum, leading to diffraction of light. In this work, discarded crustacean shells that are not known for their structural colors are used to produce photonic nanostructures of large, freestanding chiral nematic mesoporous chitosan membranes with tunable iridescent color. Bioinspired by colorful nanostructures in nature, photonic hydrogels with Bouligand‐type organization are fabricated from the twisted mesoporous membranes, where the chitosan nanofibrils are a novel precursor for surface acetylation and are also a biotemplate for polymerizing methyl methacrylate. The colors of the hydrogels can be tailored by swelling as they show large volume changes in response to changes in solvent environment. 相似文献
24.
Based on the analytical expression of the electromagnetic field solution of a helical symmetric dielectric material, the relationship between spectral reflectivity and birefringence of a chiral liquid crystal and the blue shift of the Bragg reflection in the condition of oblique incidence are presented in this paper. The theoretical results indicated that: 1) If birefringence (An)of the liquid crystal is greater than 0.2 and the thickness of the liquid crystal layer reaches 3μm, the liquid crystal layer will reflect more than 90% of the incident light; 2)To reflect the whole visible spectrum by Bragg reflection,An of the liquid crystals in plane alignment state should exceed 0.6; 3) When the incident beam inclines to 60°from the normal direction, the blue shift of the reflective spectrum will reach to 100 nm. On the other hand, since the An of the commercial chiral liquid crystals is not larger than 0.2, to get the entire visible reflective spectrum, it needs to introduce a polymer network into the liquid crystals and make a sagging structure on the surface of substrates. The contribution of the network is to establish random anchorage that makes the pitch varied, hence broadening the Bragg reflection spectra.The random distribution of the sagging structure on the surface substrate is used to induce random screw axes of the chiral liquid crystal, which not only causes a blue shift of Bragg reflection but also further stretches the reflection spectra. Experiments demonstrated that the Bragg reflection spectrum could be broadened from by introducing both polymer network and sagging structure on the substrate surface cell. 相似文献
25.
Sunghun Lee Daniel Limbach Kwon-Hyeon Kim Seung-Jun Yoo Young-Seo Park Jang-Joo Kim 《Organic Electronics》2013,14(7):1856-1860
We report a high performance orange organic light-emitting diode (OLED) where red and green phosphorescent dyes are doped in an exciplex forming co-host as separate red and green emitting layers (EMLs). The OLED shows a maximum external quantum efficiency (EQE) of 22.8%, a low roll-off of efficiency with an EQE of 19.6% at 10,000 cd/m2, and good orange color with a CIE coordinate of (0.442, 0.529) and no color change from 1000 to 10,000 cd/m2. The exciplex forming co-host system distributes the recombination zone all over the EMLs and reduces the triplet exciton quenching processes. 相似文献
26.
The GaSb layers investigated were grown directly on GaAs substrates by molecular beam epitaxy (MBE) using SnTe source as the
n-type dopant. By using admittance spectroscopy, a dominant deep level with the activation energy of 0.23-0.26 eV was observed
and its concentration was affected by the Sb4/Ga flux ratio in the MBE growth. A lowest deep-level concentration together with a highest mobility was obtained for GaSb
grown at 550°C under a Sb4/Ga beam equivalent pressure (BEP) ratio around 7, which should correspond to the lowest ratio to maintain a Sb-stabilized
surface reconstruction. In the Hall measurement, an analysis of the temperature-dependent mobility shows that the ionized
impurity concentration increases proportionally with the sample’s donor concentration, suggesting that the ionized impurity
was introduced by an SnTe source. In addition, optical properties of an undoped p-, a lightly and heavily SnTe-doped GaSb
layers were studied by comparing their photoluminescence spectra at 4.5K. 相似文献
27.
28.
描述了适用于光波分复接网络高速连续可调液晶滤波器。该滤波器利用手征近晶型液晶作为F-P标准具有源腔材料得到了微秒级开关速度。使用商品 BDH764E液晶材料制成地光滤波器,开关速度小于10μs,可调范围给30nm,通带中心在1.55μm。 相似文献
29.
HU Bin-jie YUNG Kai-ning 《通信学报》2004,25(12):148-151
The scattering of a plane wave with a linear polarization by a conducting finite helix is presented. The analytical expresses of scattering field are obtained based on the boundary condition of a sheath helix model. Effects of a pitch angle and electrical size of the helix on the resonant behavior are investigated. The analysis shows that resonant behavior of the forward/backward scattering far field is only depended on the pitch electrical size and the radial electrical size, but it is independent of the turn of the helix. 相似文献
30.
Lei Chen Cheng Chen Zhi Yang Shan Li Chiheng Chu Baoliang Chen 《Advanced functional materials》2021,31(46):2105731
The demands for green production of hydrogen peroxide have triggered extensive studies in the photocatalytic synthesis, but most photocatalysts suffer from rapid charge recombination and poor 2e− oxygen reduction reaction (ORR) selectivity. Here, a novel composite photocatalyst of cyano-rich graphitic carbon nitride g-C3N4 is fabricated in a facile manner by sodium chloride-assisted calcination on dicyandiamide. The obtained photocatalysts exhibit superior activity (7.01 mm h−1 under λ ≥ 420 nm, 16.05 mm h−1 under simulated sun conditions) for H2O2 production and 93% selectivity for 2e− ORR, much higher than that of the state-of-the-art photocatalyst. The porous g-C3N4 with Na dopants and cyano groups simultaneously optimize two limiting steps of the photocatalytic 2e− ORR: photoactivity, and selectivity. The cyano groups can adjust the band structure of g-C3N4 to achieve high activity. They also serve as oxygen adsorption sites, in which local charge polarization facilitates O2 adsorption and protonation. With the aid of Na+, the O2 is reduced to produce more superoxide radicals as the intermediate products for H2O2 synthesis. This work provides a facile approach to simultaneously tune photocatalytic activity and 2e− ORR selectivity for boosting H2O2 production, and then paves the way for the practical application of g-C3N4 in environmental remediation and energy supply. 相似文献