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91.
SiO2·Bi2O3对NiZn铁氧体的烧结和磁性能的影响 总被引:2,自引:0,他引:2
本文采用溶胶-凝胶法制备NiZn铁氧体-SiO2·Bi2O3复合材料。结果表明:烧结过程中Bi2O3与SiO2形成非晶态玻璃相促进烧结,使瓷体烧结温度降至1030℃,并且瓷体的磁导率随非磁性玻璃相的增加显著减少。磁导率的变化主要是由于非磁性相的引入导致磁路隔断、退磁场增加以及铁氧体晶粒减小所致。加入适量非磁性相有助于改善瓷体的高频特性。 相似文献
92.
为提高石蜡相变乳液的传热性能,通过添加氧化石墨烯(GO),制备了GO/石蜡复合相变乳液并对其相关性能进行了表征。搭建了流动阻力、对流换热试验台,对比研究了石蜡相变乳液及GO/石蜡复合相变乳液的流动阻力特性和对流换热特性,试验结果表明,由于GO的亲水性,复合相变乳液都表现出较好的稳定性。当GO的质量分数为0.01%、0.02%、0.03%时,复合相变乳液的热导率分别增加了20.01%、30.50%、35.18%。添加GO使乳液的流动阻力略有增加,直管段最大增加了6.70%,90°弯管处最大增加了13.20%;对流传热系数随着GO浓度的增加而增大,当GO浓度为0.03%时,对流传热系数最大提高了43.90%。 相似文献
93.
将壳聚糖/钙盐复合膜浸泡在磷酸二氢钾溶液中制备了壳聚糖/磷钙杂化膜.用电子扫描电镜观察杂化膜和膜内磷钙微粒的形貌,研究了杂化膜的力学性能、溶胀率、吸光度及热稳定性.结果表明,杂化膜内磷钙晶体为柱状和层状结构,磷钙被包裹在杂化膜内,并与壳聚糖膜形成紧密的连续结构.随着膜中磷钙的质量分数从2.1%增加到8.0%,膜的溶胀率从102%增加到144%,其在200~800 nm波长范围的吸光度也逐渐增加.当磷钙的质量分数为7.0%时,杂化膜的力学性能最佳,其拉伸强度为54.42 MPa、弹性模量为4045.72 MPa、断裂伸长率为4.85%.杂化膜的热分解温度为299℃,高于壳聚糖膜的分解温度290℃.这种具有层状磷钙结构的杂化膜具有良好的生物相容性,可作为一种潜在的支架材料. 相似文献
94.
B. Stypuła J. Banaś M. Starowicz H. Krawiec A. Bernasik A. Janas 《Journal of Applied Electrochemistry》2006,36(12):1407-1414
The anodic behaviour of copper was investigated in ethanol solution containing LiClO4, LiCl electrolyte and water. The type of electrolyte and the water content influences the mechanism of the anodic process and the formation of anodic products. In LiClO4 electrolyte the dissolution of copper is related to the oxidation of Cu(I) to Cu(II). In solutions of LiCl the etching of copper begins with the creation of soluble complexes of Cu(I) with chloride ions and solvent molecules. At potentials above 0.4 V the formation of alkoxides was observed in both solutions, characterized by a yellow tint. On the other hand, above 0.8 V (i.e. above the equilibrium potential of alcohol oxidation) copper dissolution is accompanied by the formation of a blue colloidal suspension of Cu (II) copper salt. Anodic etching of copper in solutions containing 3% H2O at potentials higher than 0.4 V leads to the formation of colloidal suspension of copper oxide nanoparticles. 相似文献
95.
利用导电高分子聚(3,4-二氧乙基噻吩)/聚(对苯乙烯磺酸)(PEDOT/PSS)作保护剂,制备了银纳米颗粒,用UV-Vis和TEM对其进行了表征.结果表明,选择合适量的PEDOT/PSS保护剂可以得到大小分布较窄银纳米颗粒. 相似文献
96.
97.
An investigation was undertaken on the application of dilute chitosan solutions gelled by tyrosinase‐catalyzed reaction with 3,4‐dihydroxyphenethylamine (dopamine). The tyrosinase‐catalyzed reaction with dopamine conferred water‐resistant adhesive properties to the semidilute chitosan solutions. The viscosity of the chitosan solutions increased highly by the tyrosinase‐catalyzed reaction and the subsequent reactions between o‐quinone compounds and chitosan. These highly viscous, gel‐like modified chitosan materials were allowed to spread onto the surfaces of the glass slides, which were tightly lapped together and held them in water. Tensile shear adhesive strength of over 400 kPa was observed for the modified chitosan samples. The increase in the amino group concentration of the chitosan solutions and the molecular mass of the chitosan used effectively led to the increase in adhesive strength of the glass slides. In addition, in the case where the chitosan solution was gelled by the enzymatic reaction with dopamine in the presence of poly(ethylene glycol), adhesive strength sharply increased at shorter reaction times concomitantly with the increase in the viscosity of the chitosan solutions because the tyrosinase activity effectively was retained by poly(ethylene glycol). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1818–1827, 2007 相似文献
98.
99.
Preparation of methanol oxidation electrocatalysts: ruthenium deposition on carbon-supported platinum nanoparticles 总被引:3,自引:0,他引:3
Methanol oxidation electrocatalysts were prepared from Ru electrochemical or spontaneous deposition on commercial-grade carbon-supported Pt nanoparticles (Pt-Vulcan XC72, E-TEK). The resulting Ru coverage was estimated by cyclic voltammetry in supporting electrolyte. The maximum electrocatalytic activity for methanol oxidation at room temperature was observed at lower Ru coverage for spontaneous deposition than for electrodeposition;
Ru 10% vs 20%, respectively. On the other hand, higher current densities for methanol oxidation were obtained in the case of electrodeposited Ru. These two results were related to the presence of non-reducible ruthenium oxides in the spontaneous deposit. The present work provides evidence that (i) efficient DMFC electrocatalysts can be achieved by Ru deposition on Pt nanoparticles, and (ii) formation of a PtRu alloy is not a required condition for effective methanol electrooxidation. 相似文献
100.
Structural characterization by transmission electron microscopy of metal nanoparticle coatings on oxide nanospheres has been
employed to point out the potential of such materials for use as porous support model catalysts. On silica and titania nanospheres
of various origins surface-mediated metal deposition at mild temperature conditions has been utilized to fabricate Pt, Pd,
Ag, and Au nanoparticle coatings on the oxide supports. Promising coating characteristics have been achieved for Ag and Au
nanoparticles by direct reduction on terminating hydroxyl-rich St?ber silica. A high-resolution electron microscopy analysis
directed to surface stress, lattice contraction and planar lattice defects of the latter particles revealed no strong metal-support
interaction. 相似文献