多元高铬铸铁在反击式破碎机板锤上的应用

在高铬铸铁中加入多种少量和微量合金元素用以生产反击式破碎机板锤，可使产品耐磨性和综合力学性能得到很大程度的改善。使用寿命比原用高锰钢提高4倍以上。     

锂离子电池正极材料第一原理计算研究

利用第一原理计算方法可分析和预测锂-金属氧化物电池正极材料在Li离子嵌入脱出过程中的电势和稳定性等性能。本文详细介绍了第一原理计算方法的理论背景以及目前LiCoO2正极材料计算研究的现状。利用此方法对LiNiO2及多组分材料掺杂进行研究是今后工作的重点。     

Sensing, modeling and control for laser-based additive manufacturing

Laser-Based Additive Manufacturing (LBAM) is a promising manufacturing technology that can be widely applied to part preparation, surface modification, and Solid Freeform Fabrication (SFF). A large number of parameters govern the LBAM process. These parameters are sensitive to the environmental variations, and they also influence each other. This paper introduces the research work in RCAM on improving the performance of the LBAM process. Metal powder delivery real-time sensing and control is studied to achieve a controllable powder delivery for fabrication of functionally graded material. A closed-loop control system based on infrared image sensing is built for control of the heat input and size of the molten pool in the LBAM process. The closed-loop control results show a great improvement in the geometrical accuracy of the built features. A three-dimensional finite element model is also established to explore the thermal behavior of the molten pool in the closed-loop controlled LBAM process.     

多元酚——甲醛树脂中游离酚,游离醛含量的测定

多元酚－－甲醛树脂是本院开发的热固粘接剂新产品，本文给出了这一产品技术指标中游离酚、游离醛含量的测定方法，并对方法进行了讨论。     

无垫片焊接密封法兰计算方法的讨论

应用华脱尔斯法建立了内、外焊唇焊接法兰结构的力学模型,在相同设计条件和材料状况下,进行了内、外焊唇结构法兰的受力分析、设计计算和结构尺寸对比。笔者认为:如果设计计算成立且焊接条件允许,内焊唇结构的法兰比外焊唇结构的法兰螺栓载荷减小,截面积减少,法兰直径和厚度也相应大幅降低。     

Effect of surface free energy on the adhesion of biofouling and crystalline fouling

Pipelines and heat exchangers using seawater as coolant suffer from biofouling. Biofouling not only reduces heat transfer performance significantly, but also causes considerable pressure drop, calling for higher pumping requirements. It would be much more desirable if surfaces with an inherently lower stickability for biofouling could be developed. In this paper, a cost-effective autocatalytic graded Ni-Cu-P-PTFE composite coating with corrosion-resistant properties was applied to reduce biofouling formation. The experimental results showed that the surface free energy of the Ni-Cu-P-PTFE coatings, which were altered by changing the PTFE content in the coatings, had a significant influence on the adhesion of microbial and mineral deposits. The Ni-Cu-P-PTFE coatings with defined surface free energy reduced the adhesion of these deposits significantly. The anti-bacterial mechanism of the composite coatings was explained with the extended DLVO theory.     

绿色节能脲醛树脂粘合剂的生产新方法

介绍了低游离甲醛含量的低醛/尿摩尔比脲醛树脂木材粘合剂的生产新方法。利用控制不同反应阶段不同工艺条件,使整个生产周期缩短20%,并充分利用反应热,使能耗降低。     

The role of the surface free energy in the selection of a suitable excipient in the course of a wet-granulation method

Pellets containing metronidazole were produced in a centrifugal granulator, with hydroxypropylcellulose (Klucel LF®) as binding agent, and corn starch, microcrystalline cellulose (Vivapur 101®) and lactose as excipients. The wettability of the pharmaceutical powders was assessed by means of contact angle measurements, and the dispersive and polar surface energies were determined. The spreading coefficients, the work of adhesion and the work of cohesion were calculated and correlated with the pellet properties (friability, bulk and tapped density, and porosity). The aim was to investigate the role of the surface free energy of one- and two-component powder compositions in pellet production. The interactions between the particles were found to be connected with the measured pellet parameters. It was concluded that, in the course of the growth of the pellets, the particle sizes of the pharmaceutical powders and the interactions between them are important. If the work of cohesion of the binder is lower than the work of cohesion of the substrate and the work of adhesion, then the optimal amount of the binding agent is that which coats the particles uniformly in minimal quantity and in continuous layer.     

A Semi‐Batch Process for Nitroxide Mediated Radical Polymerization

Summary: A semi‐batch process using nitroxide mediated polymerization, was explored for the design of low molecular weight solvent‐borne coatings, typical of those used in the automotive industry. While living radical polymerization (LRP) offers many advantages in the control of polymer chain microstructure that may confer important physical and chemical property benefits to coatings, adapting LRP to a semi‐batch process poses significant challenges in the design and operation of the process. Using styrene monomer, various two‐component initiating systems (free radical initiator, 4‐hydroxy‐TEMPO) were studied to understand the effects of different initiators on the course of polymerization. In addition, an alkoxyamine was synthesized and used as the initiating source. The initiators Luperox 7M75 and Luperox 231 give higher polymerization rates and reasonable control over polymerization, while benzoyl peroxide (BPO), Vazo 67, and the alkoxyamine are less effective. The number of polymer chains in the final product is always less than the theoretical value, reflecting poor initiation efficiency, probably resulting from undesirable termination reactions that become important due to the nature of the semi‐batch process. Adding camphorsulfonic acid (CSA) or charging initiator concurrently with monomer during semi‐batch feed, can increase the polymerization rate while maintaining the living character of the polymerization. The copolymerization of styrene and butyl acrylate is also shown to exhibit living character.

Schematic representation of the exchange reaction to produce N‐TEMPO capped polymer chains.     

Bulk free radical polymerizations of methyl methacrylateunder non-isothermal conditions and with intermediate additionof initiator: Experiments and modeling

Experimental data on the monomer conversion, x_m, and the weight average molecular weight, M_w, have been generated under several isothermal and non-isothermal conditions for the polymerization of methyl methacrylate in a rheometer-reactor assembly. The non-isothermal results, in particular, can be used to provide more stringent tests of kinetic models than isothermal data alone. A simple empirical model has been used to describe this system that accounts for the gel (Trommsdorff) and glass effects. The model involves only x_m and the temperature, and is quite general. The model parameters are tuned using only three sets of isothermal data. Good agreement is found between the experimental results and model predictions for a whole variety of experimental conditions, including non-isothermal operation and with intermediate addition of initiator. Because of its generality, this model is quite suitable for use for on-line optimizing control as well as for describing industrial reactors.