单组分聚脲材料在寒冷地区某大坝溢流面防护中的应用

水利水电工程泄洪建筑物表面经常遭受高速含沙水流或携带推移质的冲刷,经过一段时间的运行,往往会出现不同程度的磨损及气蚀破坏,采用性能优越的水工混凝土抗冲耐磨材料修复和防护尤为重要。本文通过单组分聚脲材料性能试验揭示了材料的特点,介绍了其在新疆某大坝溢流面防护中的应用情况,其处理技术对类似工程具有良好的借鉴意义。     

Polyacrylonitrile/Nylon 6 Blends: Preparation and Characterization

Summary: Polyacrylonitrile (PAN) particles with micro‐size ranges (0.15–2 μm) were prepared by emulsion and dispersion polymerizationa and in supercritical carbon dioxide media. The PAN particles were blended with Nylon 6 (PA6) at 220 °C by using a miniature mixer; it was found that melt‐mixing was possible for PAN‐rich compositions as high as 70 wt.‐%. Blends were characterized by scanning electron microscopy, IR, viscosity measurements, differential scanning calorimetry, and dynamic mechanical thermal analysis (DMTA). The size and shape of original PAN particles were retained in PAN/PA6 blends. The useful range to blend PAN particles size was less than 1 μm in terms of shape retention of the PAN particles in blends. Blends with 40 wt.‐% PAN content were found to be melt‐processable. The elastic modulus was higher for PAN/PA6 blends than pure PA6.

SEM photograph of PAN‐SC/PA6 blend with a 40/60 weight ratio.     

低密度冷模塑聚氨酯软质泡沫塑料

介绍了低密度冷模塑聚氨酯软质泡沫塑料的配方体系，工艺特点及泡沫性能。指出该泡沫应用范围较广，发展前景甚好。     

可逆冷带轧机速度张力多变量耦合系统的建模及分散控制

针对具有多变量、非线性、强耦合和不确定性的可逆冷带轧机速度张力系统,提出了一种基于扩张状态观测器(extended state observer,ESO)的全局积分滑模自适应反步分散控制方法.首先,采用机理建模方法,建立了相对完备的可逆冷带轧机速度张力多变量耦合系统的数学模型.其次,将各子系统的耦合项和不确定项看成外扰,通过构造的ESO对其进行动态观测,并分别引入所设计的全局积分滑模自适应反步控制器中进行补偿,速度张力系统实现了有效的动态解耦和协调控制.理论分析表明,所提出的控制方法能够保证滑模面的渐近稳定和闭环系统的渐近跟踪性能.最后,基于某1422mm可逆冷带轧机速度张力系统的实际数据进行仿真,结果验证了所提方法的有效性.     

基于Simulation CFD平台四角切圆燃烧锅炉冷态空气动力场的仿真研究

采用基于CAD的新型计算流体力学软件Simulation CFD,对350MW切圆燃烧锅炉炉内的冷态空气动力场进行了数值模拟研究,分析结果表明,该方法不仅可以方便直观地立体三维显示炉膛内气流的流动情况,而且相比其它传统的计算流体软件如Fluent,Simulation CFD对计算机的要求低,计算速度快,能在较短的时间内完成锅炉炉内流动状态数值模拟,有利于实现锅炉炉内流动问题的快速诊断,为开发基于Simulation CFD平台锅炉在线监测系统奠定了基础。     

Adhesive Bonding of Oil-Contaminated Steel Substrates

Durability of adhesive bonds formed by curing epoxies against oil-contaminated steel substrates using amidoamine curing agents was determined during exposure to boiling water. The most durable bonds were obtained using amidoamine curing agents with relatively low amine numbers and by blending silane coupling agents such as γ-glycidoxypropyltrimethoxysilane (γ-GPS) and N-(2-aminoethyl)-3-aminopropyltrimethoxy silane (AAMS) into the adhesives. When X-ray photoelectron spectroscopy (XPS) was used to characterize the failure surfaces of the adhesive joints after exposure to boiling water, it was determined that adhesives prepared using amidoamine curing agents with low amine numbers were able to displace the oil from the steel surface but adhesives prepared with amidoamine curing agents with high amine numbers were not. Results obtained from XPS also showed that the amino groups on the substrate fracture surfaces of joints prepared using curing agents with low amine numbers were protonated whereas the amino groups in the bulk adhesive were not, indicating that there was a chemical interaction between the curing agent and the hydrated surface of the substrate. It was also shown using infrared spectroscopy that the amidoamine curing agents formed salts with calcium compounds in the oil.     

密炼机转子铜瓦椭圆的修复方法

简要介绍了一种XHM253/20密闭式炼胶机转子铜瓦椭圆的修复方法.该方法简便易行,修复工期短,修复质量高,在实际工作中具有一定参考价值.     

剖析F型、GK型密炼机结构特征

目前，以美国F型和德国GK型为代表的密炼机已在我国基本上实现了国产化。对这两类密炼机的结构特点和安装、使用上的利与弊，本文从密炼装置、转子密封装置、卸料装置、锁紧装置到主传动5个方面作了详细的剖析，并在此基础上，提出一个取长补短的新的密炼机设计方案。     

静态混合器气液两相流压降的数值模拟及实验研究

气泡流经过静态混合器的压降问题涉及到舰船动力系统性能的好坏。在分析了气泡平均驰豫时间的基础上,结合k ε湍流模型,利用平衡流模型模拟静态混合器内形成的稀疏湍流气泡流,得到了混合器内两相流流场。空气—水系统的压力降实验表明,计算流体力学模拟能够很好地预测SMV型静态混合器内气泡流的压降,是静态混合器设计的有效手段。     

Effect of low‐temperature plasma and chitosan treatment on wool dyeing with Acid Red 27

This study examines in detail the influence of low‐temperature plasma and biopolymer chitosan treatments on wool dyeability. Wool knitted fabrics were treated and characterized by whiteness and shrink‐resistance measurements. Surface modification was assessed by contact‐angle measurements of human hair fibers, which were used as a model to study the wetting properties of the treated wool knitted fabrics. The dyeing behavior was assessed from the diffusion mechanism point of view. The dyeing kinetics were measured at two different pHs (4.2 and 6.5) and three different temperatures (60, 85, and 100°C) to gain information about the contribution of the surface modification treatment to the dyeing mechanism. The exhaustion and reflectance data were compared, and the apparent diffusion coefficients were calculated. On the basis of the obtained results, a model for the dyeing mechanism of the chitosan treated wool was proposed. When treated with chitosan, the polymer sheath spread on the surface of the fibers acted as a predominant dyeing site in very short dyeing times, thus interacting with the dye and in later stages imparting the dye to the wool fiber. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2204–2214, 2005