合成煤中钠对煤燃烧及灰特性影响

准东煤中钠含量高，燃用时锅炉会出现严重结渣问题。通过向准东煤为原料制取的超纯煤中添加灰的模型化合物，得到合成煤。并在此基础上利用热重-差示扫描量热分析法（TG/DTG/DSC）、X射线衍射仪（XRD）和灰熔融温度测定分析手段，研究Na₂O含量对煤燃烧特性和灰熔融性的影响。结果表明：钠主要影响合成煤的着火温度（T_i）与焦炭燃烧阶段，钠含量增加使T_i升高，并且Na₂O在灰中质量分数由5%升高至8%后，钠含量增加使焦炭燃烧速率先减小后加快，并能够改善煤粉燃尽特性。钠能够降低灰熔融温度，并在Na₂O质量分数高于5%后，温度下降更加明显。在三元相图中钠对莫来石的助熔作用是造成灰熔融温度降低的重要原因。XRD分析表明Na₂O含量增加，充当骨架作用的石英在钠的助熔作用下与难熔矿物硅钙石、MgO等生成低熔点长石类矿物，这类矿物在高温下有助熔作用，能够降低灰熔融温度。同时还生成助熔性含钠矿物霞石，加剧了灰熔融。     

Experimental and theoretical investigation on unburned coal char burnout in a pilot-scale rotary kiln

Oxidation reactivity studies are imperative for improving carbon re-burn technologies and valuing the heat content of unburned carbon within coal combustion ashes. Non-isothermal, thermal gravimetric analysis (TGA) was used to examine the oxidation kinetics of unburned carbon in coal combustion fly ashes having different particle size distributions; TGA results were related to combustion efficiencies as measured in a bench-scale rotary kiln. The activation energy and pre-exponential factor were determined for the chemically-controlled reaction regime; the transition temperatures between chemically-controlled and partially diffusion-controlled combustion regimes were obtained for unburned carbon particles of different sizes. After the oxidation reaction rates were evaluated, the residence time distribution (RTD) of fly ashes in the rotary kiln were experimentally measured and the mean residence times related to process parameters, including the rotating velocity and kiln inclination. By comparing these results with an advective-dispersive model, the axial dispersion coefficient of fly ashes was determined. The reaction rates obtained by thermal analyses and the RTDs were used to predict combustion efficiencies within the kiln and oxidation conditions of unburned carbon using various processing options.     

循环灰条件下1-甲基萘催化裂解的实验研究

热解气化过程中 ,促进焦油的裂解使之转化为高热值煤气 ,对高挥发分劣质煤和生物质燃料的清洁高效利用具有重要的意义 .在固定床反应器上 ,以石英砂和两种烟煤在循环流化床锅炉上燃烧形成的循环灰为床料 ,实验研究了焦油中含量较高的 1 -甲基萘的裂解反应 ,测定了反应动力学参数 .结果表明 ,与石英砂条件下相比 ,循环灰促进了 1 -甲基萘的裂解 ,反应活化能降低 ,裂解气体的总产率提高     

高掺量增钙粉煤灰水泥的研制

本文研制的激活安定剂，能解决高掺量增钙粉煤灰水泥体积安定性不良的问题，提高该水泥的7天、28天强度，缩短凝结时间，使增钙灰掺量高达65%可以制备275砌筑水泥、掺42%的高钙粉煤灰的水泥达32.5级水泥。工业怀实验生产出65%增钙灰掺量的275砌筑水泥。     

Electrodialytic extraction of Cu,Pb and Cl from municipal solid waste incineration fly ash suspended in water

The possibility of using fly ash from municipal solid waste incineration (MSWI) in, for example, concrete is considered. MSWI fly ash, however, has too high a concentration of heavy metals, which may cause leaching problems during use or problems with waste handling at the end of the lifetime of the concrete. The Cl content in MSWI fly ash is also too high and will cause corrosion problems in reinforced concrete. The possibility of removing some of the unwanted heavy metals (Cu and Pb) together with Cl from an MSWI fly ash suspended in water using an electrodialytic separation method was investigated. The removal of Pb and Cu was found to be highly pH dependent and the highest contents removed were 41 and 90%, respectively. The Cu concentration of the ash decreased from 2200 to 860 mg kg^?1 but the Pb concentration increased from 8560 to 16 800 mg kg^?1, showing that Pb is mainly found in the ash fraction that is least soluble. Hence electrodialytic treatment of the ash suspended in water is not a solution to improve the ash quality in terms of Pb. The water‐soluble Cl content per unit weight of the original ash was 12.4%. The removal of water‐soluble Cl was efficient and >98% of Cl was removed (calculated on the basis of mean initial and final concentrations). This result indicates that electrodialytic extraction may be a method that can be used for the removal of Cl from ash prior to its utilization in concrete. Copyright © 2006 Society of Chemical Industry     

用除尘灰分离炭粉制备活性炭及其改性研究

以除尘灰分离炭粉为原料，确定了制备颗粒活性炭的最佳工艺，并对制备的颗粒活性炭进行不同的改性处理和对不同有机蒸气的吸附实验。利用X—光电子能谱仪分析了改性处理后的表面化学性质。吸附实验证明，活性炭的比表面积、表面化学性质和有机物的性质对吸附过程产生影响。     

Analysis of fly ash heavy metal content and disposal in three thermal power plants in India

The study investigates the heavy metal content of fly ash and bottom ash from three major power plants in North India, using flame atomic absorption spectrometry. It also studies the prevalent disposal methods used at these sites. The ashes were analysed for the presence of Cr, Mn, Pb, Zn, Cu, Ni and Co and detectable levels of all were found in both fly ash and bottom ash. The concentrations of Cr and Zn were highest while Co concentration was less. The wet disposal method is used in two of the power plants (site 1 and site 3). Neither of the sites uses ash pond lining in the construction of the ash ponds, hence leaching of the heavy metals is possible. Site 2 has adopted 100% dry disposal system which allows better utilization but incurs additional costs. Better management practices, increased utilization and proper disposal practices need to be undertaken to minimize the adverse environmental impact.     

Effect of vermicomposting on the transformation of some trace elements in fly ash

One major constraint of the agricultural uses of fly ash (FA) is the low availability of different plant nutrients despite their high occurrence in the total amount. However, degrading FA through increased microbial activity can improve the availability of these nutrients substantially. It has been found that intestines of epigeic earthworms contain a high concentration of different microorganisms. Therefore, in the present study we addressed the effects of vermicomposting technology on the solubility of some micronutrient cations (Fe, Mn, Cu, and Zn) and some heavy metals (Pb, Cd, and Cr) in different combinations of fly ash and organic matter, applied in the form of cow dung (CD). Various combinations of FA and CD were treated with and without an epigeic earthworm (Eisenia fetida) and the solubility of different trace elements in the treatments were estimated periodically. The results revealed that the inclusion of epigeic earthworm Eisenia fetida in different combinations of fly ash and cow dung converted a considerable amount of the micronutrients into bio-available forms. On the other hand, the solubility of heavy metals tended to be reduced by the microorganisms, presumably by formation of some organo-metallic complex. Application of these vermicomposted FA and CD combinations to a red lateritic soil was found to improve the soluble Fe, Mn, Cu, and Zn status of the soil. Furthermore, the use of vermicomposted FA and CD (1:1) in potato cultivation demonstrated that use of this mixture at 10 ton per hectare (t ha⁻¹; fresh weight) was able to compensate 80% of the recommended NPK fertiliser, along with farm yard manure application, without compromising the crop yield.     

Effect of porous structure and surface functionality on the mercury capacity of a fly ash carbon and its activated sample

The effect of porous structure and surface functionality on the mercury capacity of a fly ash carbon and its activated sample has been investigated. The samples were tested for mercury adsorption using a fixed‐bed with a simulated flue gas. The activated fly ash carbon sample has lower mercury capacity than its precursor fly ash carbon (0.23 vs. 1.85 mg/g), although its surface area is around 15 times larger, 863 vs. 53 m²/g. It was found that oxygen functionality and the presence of halogen species on the surface of fly ash carbons may promote mercury adsorption, while the surface area does not seem to have a significant effect on their mercury capacity.     

Influence of ash composition on heavy metal emissions in ash melting process

Two kinds of fly ash, discharged in the combustion of either refused derived fuel (RDF) or car shredder dust (SD), were examined for the emission of heavy metals in melting process under oxidizing and reducing conditions. The residual fractions of heavy metal in slag were experimentally estimated. As a result, it was confirmed that several volatile heavy metals were readily emitted during melting process. The type of atmosphere provided for the melting process was found to affect the emission of some volatile metals in RDF ash, but not in SD ash. The emission of volatile heavy metals in RDF ash under oxidizing conditions was lower than under any other conditions in this study. The emission behavior of iron and heavy metals in RDF ash under reducing conditions was similar to that in SD ash. These facts indicated that phosphorous in RDF ash had the property of fixing the volatile metals in the slag only under oxidizing conditions. Then the mixture of SD ash with phosphorous oxide powder was also tested in a melting process, and the result was consistent with the above inference of the effect of phosphorous.